Solid catalysts for producing alcohols and methods of making the same

Title: Solid catalysts for producing alcohols and methods of making the same

Abstract

An aspect of the present disclosure is a catalyst that includes a solid support, a first metal that includes at least one of ruthenium (Ru), platinum (Pt), palladium (Pd) deposited on the solid support, and a second metal comprising at least one of tin (Sn), rhenium (Re), cobalt (Co), molybdenum (Mo), or tungsten (W) deposited on the solid support, where the first metal and the second metal are present at a first metal to second metal mass ratio between about 1.0:2.0 and about 1.0:0.5.

Inventors:: Vardon, Derek R.; Eaton, Todd R.; Settle, Amy

Issue Date:: 2019-11-26

Research Org.:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1600315

Patent Number(s):: 10486141

Application Number:: 15/828,658

Assignee:: U.S. Department of Energy (Washington, DC)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J35/0013 - {Colloids}
B01J35/1019 - {100-500 m2/g}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C31/08 - Ethanol

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J23/626 - {with tin}
B01J23/6567 - {Rhenium}
B01J35/002 - {Catalysts characterised by their physical properties}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C31/205 - {1,3-Propanediol

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J23/8913 - {Cobalt and noble metals}
B01J35/1023 - {500-1000 m2/g}
B01J35/006 - {metal crystallite size}
B01J23/462 - {Ruthenium}
B01J23/6527 - {Tungsten}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C29/149 - with hydrogen or hydrogen-containing gases
C07C31/10 - containing three carbon atoms
C07C31/207 - {1,4-Butanediol

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J27/20 - Carbon compounds
B01J23/6525 - {Molybdenum}
B01J35/1014 - {10-100 m2/g}

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DOE Contract Number:: AC36-08GO28308

Resource Type:: Patent

Resource Relation:: Patent File Date: 12/01/2017

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Vardon, Derek R., Eaton, Todd R., and Settle, Amy. Solid catalysts for producing alcohols and methods of making the same.  United States: N. p., 2019. 
        Web.

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                    Vardon, Derek R., Eaton, Todd R., & Settle, Amy. Solid catalysts for producing alcohols and methods of making the same.  United States.

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                    Vardon, Derek R., Eaton, Todd R., and Settle, Amy. Tue .  
        "Solid catalysts for producing alcohols and methods of making the same".  United States.  https://www.osti.gov/servlets/purl/1600315.

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@article{osti_1600315,

  title        = {Solid catalysts for producing alcohols and methods of making the same},

  author       = {Vardon, Derek R. and Eaton, Todd R. and Settle, Amy},

  abstractNote = {An aspect of the present disclosure is a catalyst that includes a solid support, a first metal that includes at least one of ruthenium (Ru), platinum (Pt), palladium (Pd) deposited on the solid support, and a second metal comprising at least one of tin (Sn), rhenium (Re), cobalt (Co), molybdenum (Mo), or tungsten (W) deposited on the solid support, where the first metal and the second metal are present at a first metal to second metal mass ratio between about 1.0:2.0 and about 1.0:0.5.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {11}

}

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Works referenced in this record:

Ru,Re/carbon catalyst for hydrogenation in aqueous solution
patent, December 1995

Schwartz, Jo-Ann Theresa
US Patent Document 5,478,952
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5478952

Method and Ru,Re,Sn/carbon catalyst for hydrogenation in aqueous solution
patent, December 1999

Bockrath, Richard E.; Campos, Daniel; Schwartz, Jo-Ann Theresa
US Patent Document 6,008,384
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=6008384

Catalysts for hydrogenation of carboxylic acid
patent, December 2002

Konishi, Mitsuo; Ueno, Eizaburou
US Patent Document 6,495,730
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=6495730

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Title: Solid catalysts for producing alcohols and methods of making the same

Abstract

Citation Formats

Ru,Re/carbon catalyst for hydrogenation in aqueous solution patent, December 1995

Method and Ru,Re,Sn/carbon catalyst for hydrogenation in aqueous solution patent, December 1999

Catalysts for hydrogenation of carboxylic acid patent, December 2002

Ru,Re/carbon catalyst for hydrogenation in aqueous solution
patent, December 1995

Method and Ru,Re,Sn/carbon catalyst for hydrogenation in aqueous solution
patent, December 1999

Catalysts for hydrogenation of carboxylic acid
patent, December 2002