Method of improving adhesion of carbon fibers with a polymeric matrix

Title: Method of improving adhesion of carbon fibers with a polymeric matrix

Abstract

A method of making a solid composite containing carbon fibers embedded in a polymeric matrix, the method comprising admixing carbon fibers with a polymer precursor resin, and curing the polymer precursor resin to form a cured polymeric matrix that contains said carbon fibers embedded therein, wherein said carbon fibers have covalently bonded on their surfaces a partially cured epoxy-containing or amine-containing sizing agent, wherein at least a portion of epoxide groups or amine groups in the sizing agent are available as uncrosslinked epoxide groups or amine groups, which corresponds to a curing degree of epoxide groups or amine groups of no more than about 0.6.

Inventors:: Vautard, Frederic; Ozcan, Soydan; Paulauskas, Felix Leonard

Issue Date:: 2019-10-29

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1600219

Patent Number(s):: 10457785

Application Number:: 15/158,053

Assignee:: UT-Battelle, LLC (Oak Ridge, TN)

Patent Classifications (CPCs):: C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08J - WORKING-UP

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

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C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08J - WORKING-UP
C08J2363/00 - Characterised by the use of epoxy resins

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/249948 - Fiber is precoated

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08J - WORKING-UP
C08J5/06 - using pretreated fibrous materials

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
C08L63/10 - Epoxy resins modified by unsaturated compounds

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08J - WORKING-UP
C08J5/24 - Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
C08J2333/04 - esters

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/2918 - including free carbon or carbide or therewith [not as steel]

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08J - WORKING-UP
C08J2463/00 - Characterised by the use of epoxy resins

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DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 05/18/2016

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Vautard, Frederic, Ozcan, Soydan, and Paulauskas, Felix Leonard. Method of improving adhesion of carbon fibers with a polymeric matrix.  United States: N. p., 2019. 
        Web.

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                    Vautard, Frederic, Ozcan, Soydan, & Paulauskas, Felix Leonard. Method of improving adhesion of carbon fibers with a polymeric matrix.  United States.

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                    Vautard, Frederic, Ozcan, Soydan, and Paulauskas, Felix Leonard. Tue .  
        "Method of improving adhesion of carbon fibers with a polymeric matrix".  United States.  https://www.osti.gov/servlets/purl/1600219.

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@article{osti_1600219,

  title        = {Method of improving adhesion of carbon fibers with a polymeric matrix},

  author       = {Vautard, Frederic and Ozcan, Soydan and Paulauskas, Felix Leonard},

  abstractNote = {A method of making a solid composite containing carbon fibers embedded in a polymeric matrix, the method comprising admixing carbon fibers with a polymer precursor resin, and curing the polymer precursor resin to form a cured polymeric matrix that contains said carbon fibers embedded therein, wherein said carbon fibers have covalently bonded on their surfaces a partially cured epoxy-containing or amine-containing sizing agent, wherein at least a portion of epoxide groups or amine groups in the sizing agent are available as uncrosslinked epoxide groups or amine groups, which corresponds to a curing degree of epoxide groups or amine groups of no more than about 0.6.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {10}

}

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Works referenced in this record:

Aqueous, radiation-curable coating compositions
patent, January 2000

Reich, Wolfgang; Enenkel, Peter; Keil, Edmund
US Patent Document 6,011,078
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=6011078

Sizing agent for carbon fibers
patent, November 1988

Saito, Makoto; Toki, Hiroshi; Miyazaki, Makoto
US Patent Document 4,781,947
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=4781947

At least trifunctional epoxy resin reacted with solid rubber mixed with epoxy resin and curing agent
patent, January 2000

McGrail, Patrick; Jenkins, Stephen D.; Carter, Jeffrey T.
US Patent Document 6,013,730
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=6013730

Carbon fiber multifilamentary tow which is particularly suited for weaving and/or resin impregnation
patent, December 1987

McAliley, J. Eugene; Daumit, Gene P.; Ethridge, Fredrick A.
US Patent Document 4,714,642
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=4714642

Fiber-reinforced polyphenylene ether molding compositions and process for their preparation
patent, August 1994

Grosse-Puppendahl, Thomas; Baron, Christian; Schmidt, Friedrich
US Patent Document 5,338,789
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5338789

Covalently compatible in-mold coating compositions for use with epoxy
patent, October 2008

Mack, Patrick E.; Smith, Mitchell D.
US Patent Document 7,431,789
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=7431789

Epoxy acrylate resins and their uses
patent, October 1997

Motoshima, Toshihiro; Karasawa, Akio; Takuma, Keisuke
US Patent Document 5,677,398
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5677398

Improving adhesion of acrylate resins
patent, December 2002

Reich, Wolfgang; Enenkel, Peter; Keil, Edmund
US Patent Document 6,500,878
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=6500878

Multifunctional curing agents and their use in improving strength of composites containing carbon fibers embedded in a polymeric matrix
patent, April 2017

Vautard, Frederic; Ozcan, Soydan
US Patent Document 9,617,398
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=9617398

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Title: Method of improving adhesion of carbon fibers with a polymeric matrix

Abstract

Citation Formats

Aqueous, radiation-curable coating compositions patent, January 2000

Sizing agent for carbon fibers patent, November 1988

At least trifunctional epoxy resin reacted with solid rubber mixed with epoxy resin and curing agent patent, January 2000

Carbon fiber multifilamentary tow which is particularly suited for weaving and/or resin impregnation patent, December 1987

Fiber-reinforced polyphenylene ether molding compositions and process for their preparation patent, August 1994

Covalently compatible in-mold coating compositions for use with epoxy patent, October 2008

Epoxy acrylate resins and their uses patent, October 1997

Improving adhesion of acrylate resins patent, December 2002

Multifunctional curing agents and their use in improving strength of composites containing carbon fibers embedded in a polymeric matrix patent, April 2017

Aqueous, radiation-curable coating compositions
patent, January 2000

Sizing agent for carbon fibers
patent, November 1988

At least trifunctional epoxy resin reacted with solid rubber mixed with epoxy resin and curing agent
patent, January 2000

Carbon fiber multifilamentary tow which is particularly suited for weaving and/or resin impregnation
patent, December 1987

Fiber-reinforced polyphenylene ether molding compositions and process for their preparation
patent, August 1994

Covalently compatible in-mold coating compositions for use with epoxy
patent, October 2008

Epoxy acrylate resins and their uses
patent, October 1997

Improving adhesion of acrylate resins
patent, December 2002

Multifunctional curing agents and their use in improving strength of composites containing carbon fibers embedded in a polymeric matrix
patent, April 2017