Collection, release, and detection of analytes with polymer composite sampling materials

Addleman, Raymond S.; Li, Xiaohong Shari; Chouyyok, Wilaiwan; Atkinson, David A.

Title: Collection, release, and detection of analytes with polymer composite sampling materials

Abstract

A unique fiber core sampler composition, related systems, and techniques for designing, making, and using the same are described. The sampler is used to interface with existing field instrumentation, such as Ion Mobility Spectrometer (IMS) equipment. Desired sampler characteristics include its: stiffness/flexibility; thermal mass and conductivity; specific heat; trace substance collection/release dependability, sensitivity and repeatability; thickness; reusability; durability; stability for thermal cleaning; and the like. In one form the sampler has a glass fiber core with a thickness less than 0.3 millimeter that is coated with a polymer including one or more of: polymeric organofluorine, polyimide, polyamide, PolyBenzlmidazole (PBI), PolyDiMethylSiloxane (PDMS), sulfonated tetrafluoroethylene (PFSA) and Poly(2,6-diphenyl-p-phenylene Oxide) (PPPO). Multiple polymer coatings with the same or different polymer types may be included, core/substrate surface functionalization utilized, and/or the core/substrate may be at partially filled with thermally conductive particles.

Inventors:: Addleman, Raymond S.; Li, Xiaohong Shari; Chouyyok, Wilaiwan; Atkinson, David A.

Issue Date:: 2019-10-22

Research Org.:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1600210

Patent Number(s):: 10453664

Application Number:: 14/692,371

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01J - ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS

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B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
B05D2506/10 - Fluorinated polymers
B05D3/0218 - {Pretreatment, e.g. heating the substrate}
B05D2518/10 - Silicon-containing polymers
B05D2505/50 - Polyimides
B05D2203/35 - Glass

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01J - ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
H01J49/0409 - {Sample holders or containers

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N1/02 - Devices for withdrawing samples
G01N2001/024 - {passengers or luggage}

B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
B05D2518/12 - Ceramic precursors

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N2001/022 - {sampling for security purposes, e.g. contraband, warfare agents}

B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
B05D2203/30 - Other inorganic substrates, e.g. ceramics, silicon

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N2001/028 - {Sampling from a surface, swabbing, vaporising}
G01N2001/027 - {field kits / quick test kits}

B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
B05D5/00 - Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
B05D3/0254 - {After-treatment}

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N2001/007 - {Devices specially adapted for forensic samples, e.g. tamper-proofing, sample tracking}
G01N1/405 - {by adsorption or absorption}

B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
B05D3/002 - {Pretreatement}

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DOE Contract Number:: AC05-76RL01830

Resource Type:: Patent

Resource Relation:: Patent File Date: 04/21/2015

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Addleman, Raymond S., Li, Xiaohong Shari, Chouyyok, Wilaiwan, and Atkinson, David A. Collection, release, and detection of analytes with polymer composite sampling materials.  United States: N. p., 2019. 
        Web.

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                    Addleman, Raymond S., Li, Xiaohong Shari, Chouyyok, Wilaiwan, & Atkinson, David A. Collection, release, and detection of analytes with polymer composite sampling materials.  United States.

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                    Addleman, Raymond S., Li, Xiaohong Shari, Chouyyok, Wilaiwan, and Atkinson, David A. Tue .  
        "Collection, release, and detection of analytes with polymer composite sampling materials".  United States.  https://www.osti.gov/servlets/purl/1600210.

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@article{osti_1600210,

  title        = {Collection, release, and detection of analytes with polymer composite sampling materials},

  author       = {Addleman, Raymond S. and Li, Xiaohong Shari and Chouyyok, Wilaiwan and Atkinson, David A.},

  abstractNote = {A unique fiber core sampler composition, related systems, and techniques for designing, making, and using the same are described. The sampler is used to interface with existing field instrumentation, such as Ion Mobility Spectrometer (IMS) equipment. Desired sampler characteristics include its: stiffness/flexibility; thermal mass and conductivity; specific heat; trace substance collection/release dependability, sensitivity and repeatability; thickness; reusability; durability; stability for thermal cleaning; and the like. In one form the sampler has a glass fiber core with a thickness less than 0.3 millimeter that is coated with a polymer including one or more of: polymeric organofluorine, polyimide, polyamide, PolyBenzlmidazole (PBI), PolyDiMethylSiloxane (PDMS), sulfonated tetrafluoroethylene (PFSA) and Poly(2,6-diphenyl-p-phenylene Oxide) (PPPO). Multiple polymer coatings with the same or different polymer types may be included, core/substrate surface functionalization utilized, and/or the core/substrate may be at partially filled with thermally conductive particles.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {10}

}

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Works referenced in this record:

Solid phase extraction medium
patent, January 1994

Markell, Craig G.; Hagen, Donald F.; Luedtke, James D.
US Patent Document 5,279,742
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5279742

Non-fouling polymeric surface modification and signal amplification method for biomolecular detection
patent, February 2013

Chilkoti, Ashutosh
US Patent Document 8,367,314
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=8367314

Ion mobility spectrometers
patent, April 1993

Jenkins, Anthony
US Patent Document 5,200,614
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5200614

Color coded swipe for portable explosive or drug detection system
patent, November 2013

Haas, Jeffrey S.; Haas, Jr., Douglas D.
US Patent Document 8,590,791
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=8590791

Carbonate-mediated hydrogen peroxide oxidation of 4-acylamino-2,2,6,6-tetramethylpiperidine
patent, July 1998

Pastor, Stephen D.; Smith, Andrea R.
US Patent Document 5,777,126
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5777126

Self-wettable solid phase extraction medium
patent, April 1997

Fritz, James S.; Hagen, Donald F.; Markell, Craig G.
US Patent Document 5,616,407
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5616407

Ion trap mobility spectrometer and method of operation for enhanced detection of narcotics
patent, February 1996

Jenkins, Anthony; McGann, William J.
US Patent Document 5,491,337
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5491337

Method for explosives detection
patent, July 2014

Haas, Jeffrey S.
US Patent Document 8,772,045
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=8772045

Devices and methods for the collection and detection of substances
patent, April 2013

Gold, Mark S.; Martin, David M.; Gold, Steven T.
US Patent Document 8,414,846
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=8414846

Apparatus and method for generating an ammonia gas
patent, February 2010

Reda, Ralph J.
US Patent Document 7,663,099
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=7663099

Compositions and methods for treating nuclear fuel
patent, January 2014

Soderquist, Chuck Z.; Johnsen, Amanda M.; McNamara, Bruce K.
US Patent Document 8,636,966
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=8636966

Materials and apparatus for the detection of contraband
patent, November 2004

Jenkins, Anthony; McGann, William J.; Napoli, Joseph D.
US Patent Document 6,815,670
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=6815670

High strength polymer of hydroquinone poly(iso-terephthalate) containing residues of p-hydroxybenzoic acid
patent, September 1992

Stern, Brian A.; Matzner, Markus; Layton, Richard G.
US Patent Document 5,147,967
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5147967

Method and device for identifying designated materials in the composition of an object
patent, June 1998

Maitrejean, Serge; Perion, Didier
US Patent Document 5,768,334
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5768334

High throughput methods for analysis of contamination in environmental samples
patent-application, April 2011

Agrawal, Anoop; Tonazzi, Juan Carlos L.; Adams, Lori L.
US Patent Application 12/969472; 20110092377
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220110092377%22.PGNR.&OS=DN/20110092377&RS=DN/20110092377

Compositions and methods for treating nuclear fuel
patent, August 2013

Soderquist, Chuck Z.; Johnsen, Amanda M.; McNamara, Bruce K.
US Patent Document 8,506,911
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=8506911

Quantitative organic vapor-particle sampler
patent, June 1998

Gundel, Lara A.; Daisey, Joan M.; Stevens, Robert K.
US Patent Document 5,763,360
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5763360

Materials and apparatus for the detection of contraband
patent, November 2003

Jenkins, Anthony; McGann, William J.; Napoli, Joseph D.
US Patent Document 6,642,513
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=6642513

Ion mobility spectrometer
patent, February 2004

Jenkins, Anthony; McGann, William J.
US Patent Document 6,690,005
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=6690005

Devices and methods for the collection and detection of substances
patent, March 2013

Gold, Mark S.; Martin, David M.; Gold, Steven T.
US Patent Document 8,388,907
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=8388907

Enhancements to ion mobility spectrometers
patent, July 2004

Jenkins, Anthony; McGann, William J.
US Patent Document 6,765,198
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=6765198

Analysis of volatile organic compounds
patent, January 1977

Fletcher, James; Zlatkis, Albert
US Patent Document 4,003,257
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=4003257

Variable stiffness structure
patent, February 2011

McKnight, Geoffrey P.; Barvosa-Carter, William B.
US Patent Document 7,892,630
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=7892630

Annealed linear high density polyethylene and preparation thereof
patent, November 1995

Howard, Jr., Edward G.
US Patent Document 5,468,842
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=5468842

Enhanced surface sampler and process for collection and release of analytes
patent, February 2015

Addleman, Raymond S.; Atkinson, David A.; Bays, John T.
US Patent Document 8,943,910
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=8943910

Calibration and verification tool and method for calibrating a detection apparatus
patent, December 2010

Carey, Loucinda; Bistany, Kurt
US Patent Document 7,856,898
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=7856898

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Title: Collection, release, and detection of analytes with polymer composite sampling materials

Abstract

Citation Formats

Solid phase extraction medium patent, January 1994

Non-fouling polymeric surface modification and signal amplification method for biomolecular detection patent, February 2013

Ion mobility spectrometers patent, April 1993

Color coded swipe for portable explosive or drug detection system patent, November 2013

Carbonate-mediated hydrogen peroxide oxidation of 4-acylamino-2,2,6,6-tetramethylpiperidine patent, July 1998

Self-wettable solid phase extraction medium patent, April 1997

Ion trap mobility spectrometer and method of operation for enhanced detection of narcotics patent, February 1996

Method for explosives detection patent, July 2014

Devices and methods for the collection and detection of substances patent, April 2013

Apparatus and method for generating an ammonia gas patent, February 2010

Compositions and methods for treating nuclear fuel patent, January 2014

Materials and apparatus for the detection of contraband patent, November 2004

High strength polymer of hydroquinone poly(iso-terephthalate) containing residues of p-hydroxybenzoic acid patent, September 1992

Method and device for identifying designated materials in the composition of an object patent, June 1998

High throughput methods for analysis of contamination in environmental samples patent-application, April 2011

Compositions and methods for treating nuclear fuel patent, August 2013

Quantitative organic vapor-particle sampler patent, June 1998

Materials and apparatus for the detection of contraband patent, November 2003

Ion mobility spectrometer patent, February 2004

Devices and methods for the collection and detection of substances patent, March 2013

Enhancements to ion mobility spectrometers patent, July 2004

Analysis of volatile organic compounds patent, January 1977

Variable stiffness structure patent, February 2011

Annealed linear high density polyethylene and preparation thereof patent, November 1995

Enhanced surface sampler and process for collection and release of analytes patent, February 2015

Calibration and verification tool and method for calibrating a detection apparatus patent, December 2010

Solid phase extraction medium
patent, January 1994

Non-fouling polymeric surface modification and signal amplification method for biomolecular detection
patent, February 2013

Ion mobility spectrometers
patent, April 1993

Color coded swipe for portable explosive or drug detection system
patent, November 2013

Carbonate-mediated hydrogen peroxide oxidation of 4-acylamino-2,2,6,6-tetramethylpiperidine
patent, July 1998

Self-wettable solid phase extraction medium
patent, April 1997

Ion trap mobility spectrometer and method of operation for enhanced detection of narcotics
patent, February 1996

Method for explosives detection
patent, July 2014

Devices and methods for the collection and detection of substances
patent, April 2013

Apparatus and method for generating an ammonia gas
patent, February 2010

Compositions and methods for treating nuclear fuel
patent, January 2014

Materials and apparatus for the detection of contraband
patent, November 2004

High strength polymer of hydroquinone poly(iso-terephthalate) containing residues of p-hydroxybenzoic acid
patent, September 1992

Method and device for identifying designated materials in the composition of an object
patent, June 1998

High throughput methods for analysis of contamination in environmental samples
patent-application, April 2011

Compositions and methods for treating nuclear fuel
patent, August 2013

Quantitative organic vapor-particle sampler
patent, June 1998

Materials and apparatus for the detection of contraband
patent, November 2003

Ion mobility spectrometer
patent, February 2004

Devices and methods for the collection and detection of substances
patent, March 2013

Enhancements to ion mobility spectrometers
patent, July 2004

Analysis of volatile organic compounds
patent, January 1977

Variable stiffness structure
patent, February 2011

Annealed linear high density polyethylene and preparation thereof
patent, November 1995

Enhanced surface sampler and process for collection and release of analytes
patent, February 2015

Calibration and verification tool and method for calibrating a detection apparatus
patent, December 2010