Template-based methods of making and using ceramic solids

Title: Template-based methods of making and using ceramic solids

Abstract

Various embodiments relate to a method comprising forming a template from a template precursor, wherein the template contains an entrapped ceramic precursor, which can be further processed to form a ceramic solid, such as an oxide ceramic solid. In one embodiment, the template precursor is a hydrogel precursor and the template is a hydrogel template. The hydrogel template can include, for example, agarose, chitosan, alginate or a photo-initiating receptive hydrogel template such as a functionalized poly(ethylene glycol). Various devices, including electrolyte interfaces and energy storage devices, as well as thermoelectric devices are also provided. In one embodiment, the oxide ceramic solid is a cubic garnet having a nominal formula of Li7La3Zr2O12 (LLZO).

Inventors:: Sakamoto, Jeffrey; Thompson, Travis; Rangasamy, Ezhiyl; Lynam, Daniel A.

Issue Date:: 2019-08-20

Research Org.:: Michigan State Univ., East Lansing, MI (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1568757

Patent Number(s):: 10388975

Application Number:: 14/169,758

Assignee:: Board of Trustees of Michigan State University (East Lansing, MI)

Patent Classifications (CPCs):: C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F

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C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3244 - Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
C04B35/638 - Removal thereof
C04B2235/3217 - Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
C04B2235/3201 - Alkali metal oxides or oxide-forming salts thereof
C04B35/6365 - {Cellulose or derivatives thereof}
C04B35/50 - based on rare-earth compounds {

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G53/54 - {of the type [Mn2O4]-, e.g. Li
C01G51/68 - {containing rare earth, e.g. La0.3Sr0.7CoO3}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/624 - Sol-gel processing

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M2008/1293 - {Fuel cells with solid oxide electrolytes}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/495 - based on vanadium, niobium, tantalum, molybdenum or tungsten oxides or solid solutions thereof with other oxides, e.g. vanadates, niobates, tantalates, molybdates or tungstates

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/02 - obtained by optical microscopy
C01P2002/76 - by a space-group or by other symmetry indications

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3206 - Magnesium oxides or oxide-forming salts thereof

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3215 - Barium oxides or oxide-forming salts thereof

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/50 - Solid solutions

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0562 - Solid materials

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/505 - based on yttrium oxide
C04B2235/764 - Garnet structure A3B2

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2006/40 - Electric properties
C01P2002/72 - by d-values or two theta-values, e.g. as X-ray diagram

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G51/66 - {containing alkaline earth metals, e.g. SrCoO3}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3229 - Cerium oxides or oxide-forming salts thereof
C04B2235/3224 - Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/30 - Three-dimensional structures

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G23/005 - {Alkali titanates}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/50 - Fuel cells

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3286 - Gallium oxides, gallates, indium oxides, indates, thallium oxides, thallates or oxide forming salts thereof, e.g. zinc gallate
C04B35/01 - based on oxide ceramics
C04B2235/94 - Products characterised by their shape

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G51/42 - {containing alkali metals, e.g. LiCoO2}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/486 - Fine ceramics
C04B2235/3227 - Lanthanum oxide or oxide-forming salts thereof
C04B35/636 - Polysaccharides or derivatives thereof
C04B2235/3203 - Lithium oxide or oxide-forming salts thereof
C04B35/634 - Polymers

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M8/1253 - the electrolyte containing zirconium oxide
H01M2300/0077 - based on zirconium oxide

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G25/006 - {Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3251 - Niobium oxides, niobates, tantalum oxides, tantalates, or oxide-forming salts thereof

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P70/50 - Manufacturing or production processes characterised by the final manufactured product

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DOE Contract Number:: SC0001054; W911NF-10-2-0089

Resource Type:: Patent

Resource Relation:: Patent File Date: 01/31/2014

Country of Publication:: United States

Language:: English

Citation Formats


                    Sakamoto, Jeffrey, Thompson, Travis, Rangasamy, Ezhiyl, and Lynam, Daniel A. Template-based methods of making and using ceramic solids.  United States: N. p., 2019. 
        Web.

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                    Sakamoto, Jeffrey, Thompson, Travis, Rangasamy, Ezhiyl, & Lynam, Daniel A. Template-based methods of making and using ceramic solids.  United States.

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                    Sakamoto, Jeffrey, Thompson, Travis, Rangasamy, Ezhiyl, and Lynam, Daniel A. Tue .  
        "Template-based methods of making and using ceramic solids".  United States.  https://www.osti.gov/servlets/purl/1568757.

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@article{osti_1568757,

  title        = {Template-based methods of making and using ceramic solids},

  author       = {Sakamoto, Jeffrey and Thompson, Travis and Rangasamy, Ezhiyl and Lynam, Daniel A.},

  abstractNote = {Various embodiments relate to a method comprising forming a template from a template precursor, wherein the template contains an entrapped ceramic precursor, which can be further processed to form a ceramic solid, such as an oxide ceramic solid. In one embodiment, the template precursor is a hydrogel precursor and the template is a hydrogel template. The hydrogel template can include, for example, agarose, chitosan, alginate or a photo-initiating receptive hydrogel template such as a functionalized poly(ethylene glycol). Various devices, including electrolyte interfaces and energy storage devices, as well as thermoelectric devices are also provided. In one embodiment, the oxide ceramic solid is a cubic garnet having a nominal formula of Li7La3Zr2O12 (LLZO).},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {8}

}

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Works referenced in this record:

Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, October 2007

Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
US Patent Document 7,282,295
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=7282295

Methods of making and using oxide ceramic solids and products and devices related thereto
patent, July 2015

Sakamoto, Jeffrey S.; Rangasamy, Ezhiyl; Kim, Hyun-Joong
US Patent Document 9,093,717
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=9093717

High strength air-dried aerogels
patent-application, July 2007

Coronado, Paul R.; Satcher, JR., JOe H.
US Patent Application 11/335297; 20070167534
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220070167534%22.PGNR.&OS=DN/20070167534&RS=DN/20070167534

Ion Conductor Having a Garnet Structure
patent-application, August 2010

Weppner, Werner
US Patent Application 12/667400; 20100203383
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220100203383%22.PGNR.&OS=DN/20100203383&RS=DN/20100203383

CERAMIC MATERIAL AND PREPARATION METHOD THEREFOR
patent-application, March 2011

Yamamura, Yoshihiko; Hattori, Tatsuya; Yoshida, Toshihiro
US Patent Application 12/873393; 20110053002
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220110053002%22.PGNR.&OS=DN/20110053002&RS=DN/20110053002

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Similar Records

Title: Template-based methods of making and using ceramic solids

Abstract

Citation Formats

Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture patent, October 2007

Methods of making and using oxide ceramic solids and products and devices related thereto patent, July 2015

High strength air-dried aerogels patent-application, July 2007

Ion Conductor Having a Garnet Structure patent-application, August 2010

CERAMIC MATERIAL AND PREPARATION METHOD THEREFOR patent-application, March 2011

Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, October 2007

Methods of making and using oxide ceramic solids and products and devices related thereto
patent, July 2015

High strength air-dried aerogels
patent-application, July 2007

Ion Conductor Having a Garnet Structure
patent-application, August 2010

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patent-application, March 2011