Protective cathode coatings for lithium-ion batteries

Aykol, Muratahan; Kim, Soo; Hao, Shiqiang; Lu, Zhi; Hegde, Vinay Ishwar; Snydacker, David H.; Kirklin, Scott J.; Morgan, Dane; Wolverton, Christopher M.

Title: Protective cathode coatings for lithium-ion batteries

Abstract

Cathode coatings for lithium ion batteries, cathodes coated with the coatings, and lithium ion batteries incorporating the coated cathodes are provided. The coatings, which are composed of binary, ternary, and higher order metal oxides and/or metalloid oxides, can reduce the hydrofluoric acid (HF)-induced degradation of the electrolyte and/or cathodes, thereby improving the performance of lithium ion batteries, relative to lithium ion batteries that employ bare cathodes.

Inventors:: Aykol, Muratahan; Kim, Soo; Hao, Shiqiang; Lu, Zhi; Hegde, Vinay Ishwar; Snydacker, David H.; Kirklin, Scott J.; Morgan, Dane; Wolverton, Christopher M.

Issue Date:: 2019-08-06

Research Org.:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1568684

Patent Number(s):: 10374262

Application Number:: 15/427,295

Assignee:: Northwestern University (Evanston, IL)

Patent Classifications (CPCs):: Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

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Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M4/366 - {as layered products}
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx

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DOE Contract Number:: 4F-32002-M0001; AC02-06CH11357; DMR-1309957

Resource Type:: Patent

Resource Relation:: Patent File Date: 02/08/2017

Country of Publication:: United States

Language:: English

Citation Formats


                    Aykol, Muratahan, Kim, Soo, Hao, Shiqiang, Lu, Zhi, Hegde, Vinay Ishwar, Snydacker, David H., Kirklin, Scott J., Morgan, Dane, and Wolverton, Christopher M. Protective cathode coatings for lithium-ion batteries.  United States: N. p., 2019. 
        Web.

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                    Aykol, Muratahan, Kim, Soo, Hao, Shiqiang, Lu, Zhi, Hegde, Vinay Ishwar, Snydacker, David H., Kirklin, Scott J., Morgan, Dane, & Wolverton, Christopher M. Protective cathode coatings for lithium-ion batteries.  United States.

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                    Aykol, Muratahan, Kim, Soo, Hao, Shiqiang, Lu, Zhi, Hegde, Vinay Ishwar, Snydacker, David H., Kirklin, Scott J., Morgan, Dane, and Wolverton, Christopher M. Tue .  
        "Protective cathode coatings for lithium-ion batteries".  United States.  https://www.osti.gov/servlets/purl/1568684.

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@article{osti_1568684,

  title        = {Protective cathode coatings for lithium-ion batteries},

  author       = {Aykol, Muratahan and Kim, Soo and Hao, Shiqiang and Lu, Zhi and Hegde, Vinay Ishwar and Snydacker, David H. and Kirklin, Scott J. and Morgan, Dane and Wolverton, Christopher M.},

  abstractNote = {Cathode coatings for lithium ion batteries, cathodes coated with the coatings, and lithium ion batteries incorporating the coated cathodes are provided. The coatings, which are composed of binary, ternary, and higher order metal oxides and/or metalloid oxides, can reduce the hydrofluoric acid (HF)-induced degradation of the electrolyte and/or cathodes, thereby improving the performance of lithium ion batteries, relative to lithium ion batteries that employ bare cathodes.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {8}

}

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Works referenced in this record:

Surface modification agents for lithium batteries
patent-application, November 2009

Chen, Zonghai; Amine, Khalil; Belharouak, Ilias
US Patent Application 12/454173; 20090286157
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220090286157%22.PGNR.&OS=DN/20090286157&RS=DN/20090286157

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Title: Protective cathode coatings for lithium-ion batteries

Abstract

Citation Formats

Surface modification agents for lithium batteries patent-application, November 2009

Surface modification agents for lithium batteries
patent-application, November 2009