Aqueous pyridinium cation-based redox flow batteries

Zhang, Zhengcheng; Huang, Jinhua; Gallagher, Kevin

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Title: Aqueous pyridinium cation-based redox flow batteries

Abstract

The present invention provides an aqueous redox flow battery comprising a negative electrode immersed in an aqueous liquid negative electrolyte, a positive electrode immersed in an aqueous liquid positive electrolyte, and a cation-permeable separator (e.g., a porous membrane, film, sheet, or panel) between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise an electrolyte salt (e.g., a lithium or sodium salt), a redox reactant. The negative redox reactant comprises a pyridinium compound of Formula (I) as described in the specification.

Inventors:: Zhang, Zhengcheng; Huang, Jinhua; Gallagher, Kevin

Issue Date:: 2019-08-06

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1568682

Patent Number(s):: 10374239

Application Number:: 15/394,031

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Show more

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/90 - Selection of catalytic material
H01M8/04186 - of liquid-charged or electrolyte-charged reactants
H01M8/04201 - {Reactant storage and supply, e.g. means for feeding, pipes}
H01M8/188 - {by recharging of redox couples containing fluids

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/50 - Fuel cells

Show less

DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 12/29/2016

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 42 ENGINEERING; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Zhang, Zhengcheng, Huang, Jinhua, and Gallagher, Kevin. Aqueous pyridinium cation-based redox flow batteries.  United States: N. p., 2019. 
        Web.

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                    Zhang, Zhengcheng, Huang, Jinhua, & Gallagher, Kevin. Aqueous pyridinium cation-based redox flow batteries.  United States.

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                    Zhang, Zhengcheng, Huang, Jinhua, and Gallagher, Kevin. Tue .  
        "Aqueous pyridinium cation-based redox flow batteries".  United States.  https://www.osti.gov/servlets/purl/1568682.

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@article{osti_1568682,

  title        = {Aqueous pyridinium cation-based redox flow batteries},

  author       = {Zhang, Zhengcheng and Huang, Jinhua and Gallagher, Kevin},

  abstractNote = {The present invention provides an aqueous redox flow battery comprising a negative electrode immersed in an aqueous liquid negative electrolyte, a positive electrode immersed in an aqueous liquid positive electrolyte, and a cation-permeable separator (e.g., a porous membrane, film, sheet, or panel) between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise an electrolyte salt (e.g., a lithium or sodium salt), a redox reactant. The negative redox reactant comprises a pyridinium compound of Formula (I) as described in the specification.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {8}

}

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Similar Records

Title: Aqueous pyridinium cation-based redox flow batteries

Abstract

Citation Formats

Electrolyte for redox flow battery, and redox flow battery patent, August 2007

Electrically rechargeable REDOX flow cell patent, December 1976

New electrode materials derived from polyquinonic ionic compounds and their use in electrochemical generators patent-application, September 2010

Inhibitor of Reduction of Life Cycle of Redox Shuttle Additive and Non-Aqueous Electrolyte and Secondary Battery Comprising the Same patent-application, April 2007

Redox shuttles for lithium ion batteries patent-application, December 2011

Non-aqueous electrolyte secondary battery patent, January 1998

Organic Active Materials for Batteries patent-application, July 2013

Redox Flow Battery patent-application, January 2016

Redox Flow Cell for Storing Electrical Energy and Use Thereof patent-application, August 2018

Secondary Battery, Power Supply System Using Same and Usage of Power Supply System patent-application, January 2009

All-Vanadium Redox Flow Battery System Employing a V+4/V+5 Redox Couple and an Ancillary CE+3/CE+4 Redox Couple in the Positive Electrolyte Solution patent-application, December 2015

Vanadium Redox Battery Incorporating Multiple Electrolyte Reservoirs patent-application, October 2008

Polyether-functionalized redox shuttle additives for lithium ion batteries patent-application, December 2011

Non-aqueous Redox Flow Batteries Including 3,7-Perfluoroalkylated Phenothiazine Derivatives patent-application, December 2015

Lithium Rechargeable Electrochemical Cell patent-application, July 2009

Organic electrolyte solution and redox flow battery including the same patent-application, August 2011

Fuel System Using Redox Flow Battery patent-application, December 2010

Redox flow battery and method of operating it patent, February 2004

Organic non-aqueous cation-based redox flow batteries patent, March 2016

Redox battery patent, December 1982

High Energy Density Redox Flow Device patent-application, August 2011

Vanadium/polyhalide redox flow battery patent, January 2008

Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method patent, March 2005

Novel redox shuttles for overcharge protection of lithium batteries patent-application, September 2006

N-oxide redox shuttles for rechargeable lithium-ion cell patent-application, November 2006

High Energy Density Redox Flow Device patent-application, February 2010

Sodium Based Aqueous Electrolyte Electrochemical Secondary Energy Storage Device patent-application, March 2011

Redox Flow Battery patent-application, August 2011

Flow battery patent, November 1994

Redox Flow Battery patent-application, May 2012

Additives for non-aqueous electrolyte and secondary battery using the same patent-application, November 2010

Electrolyte for redox flow battery, and redox flow battery
patent, August 2007

Electrically rechargeable REDOX flow cell
patent, December 1976

New electrode materials derived from polyquinonic ionic compounds and their use in electrochemical generators
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Inhibitor of Reduction of Life Cycle of Redox Shuttle Additive and Non-Aqueous Electrolyte and Secondary Battery Comprising the Same
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Redox shuttles for lithium ion batteries
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Non-aqueous electrolyte secondary battery
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Organic Active Materials for Batteries
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Redox Flow Battery
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Redox Flow Cell for Storing Electrical Energy and Use Thereof
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Secondary Battery, Power Supply System Using Same and Usage of Power Supply System
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All-Vanadium Redox Flow Battery System Employing a V+4/V+5 Redox Couple and an Ancillary CE+3/CE+4 Redox Couple in the Positive Electrolyte Solution
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Vanadium Redox Battery Incorporating Multiple Electrolyte Reservoirs
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Polyether-functionalized redox shuttle additives for lithium ion batteries
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