Electrolytes and metal hydride batteries
Abstract
Metal hydride batteries comprising an electrolyte composition which comprises an aqueous solution comprising potassium hydroxide (KOH) and one or more halide and/or oxyacid salts exhibit reduced degradation of the anode material during operation. The salts are for instance alkali metal salts. Anode materials exhibit for instance <100 % of the degradation of the same anode material in the same battery when replacing the electrolyte composition with 30 weight percent (wt %) aqueous KOH and the conductivity of the electrolyte composition is for instance ≥85 % of 30 wt % aqueous KOH. Anode materials are for example ABx high capacity hydrogen storage alloys comprising Mg where x is from about 0.5 to about 5 and which has a discharge capacity of ≥400 mAh/g.
- Inventors:
- Issue Date:
- Research Org.:
- BASF Corporation, Florham Park, NJ (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1568499
- Patent Number(s):
- 10333177
- Application Number:
- 14/540,174
- Assignee:
- ARPA-E
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AR0000386
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 11/13/2014
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Young, Kwo, Yan, Shuli, and Ng, Simon K. Y. Electrolytes and metal hydride batteries. United States: N. p., 2019.
Web.
Young, Kwo, Yan, Shuli, & Ng, Simon K. Y. Electrolytes and metal hydride batteries. United States.
Young, Kwo, Yan, Shuli, and Ng, Simon K. Y. Tue .
"Electrolytes and metal hydride batteries". United States. https://www.osti.gov/servlets/purl/1568499.
@article{osti_1568499,
title = {Electrolytes and metal hydride batteries},
author = {Young, Kwo and Yan, Shuli and Ng, Simon K. Y.},
abstractNote = {Metal hydride batteries comprising an electrolyte composition which comprises an aqueous solution comprising potassium hydroxide (KOH) and one or more halide and/or oxyacid salts exhibit reduced degradation of the anode material during operation. The salts are for instance alkali metal salts. Anode materials exhibit for instance <100 % of the degradation of the same anode material in the same battery when replacing the electrolyte composition with 30 weight percent (wt %) aqueous KOH and the conductivity of the electrolyte composition is for instance ≥85 % of 30 wt % aqueous KOH. Anode materials are for example ABx high capacity hydrogen storage alloys comprising Mg where x is from about 0.5 to about 5 and which has a discharge capacity of ≥400 mAh/g.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {6}
}
Works referenced in this record:
Electrochemical hydrogen storage alloys and batteries fabricated from Mg containing base alloys
patent, April 1997
- Ovshinsky, Stanford R.; Fetcenko, Michael A.; Reichman, Benjamin
- US Patent Document 5,616,432
Medium or large scale sealed metal oxide/metal hydride battery
patent, October 1995
- Matsumoto, Isao; Ikoma, Munehisa; Morishita, Nobuyasu
- US Patent Document 5,455,125
Method to make nickel positive electrodes and batteries using same
patent-application, August 2001
- Hong, Kuochih; Lin, Yee-Ming
- US Patent Document 09/776354; 20010012586
Nickel hydride secondary cell
patent, June 1997
- Edamoto, Toshiyuki; Wada, Shuichi
- US Patent Document 5,637,422
Alkali rechargeable batteries and process for the production of said rechargeable batteries
patent, November 2002
- Kawakami, Soichiro; Tani, Atsushi
- US Patent Document 6,475,664
Nickel/metal hydride storage battery
patent, June 2000
- Dansui, Yoshitaka; Kato, Fumio; Suzuki, Kenji
- US Patent Document 6,074,785