Catalytic conversion of bio-mass derivable aliphatic alcohols to valuable alkenes or oxygenates

Lin, Manhua; Eng, Wai-Si

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Title: Catalytic conversion of bio-mass derivable aliphatic alcohols to valuable alkenes or oxygenates

Abstract

Disclosed is a method for producing, among others, alkenes and/or saturated or unsaturated oxygenates and, which include at least one of an aldehyde and an acid, comprising subjecting the corresponding C3 to C5 aliphatic alcohols that are derivable from biomass, to a vapor phase process over the catalytic system in the presence of a gas mixture of oxygen, air or nitrogen and/or other suitable diluting gas. The catalyst system comprises multi-catalytic zones, in each of which the composition of the co-feed and other reaction parameter can be independently controlled.

Inventors:: Lin, Manhua; Eng, Wai-Si

Issue Date:: 2019-05-28

Research Org.:: EverNu Technology, LLC, Warwick, PA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1568389

Patent Number(s):: 10300464

Application Number:: 14/649,929

Assignee:: EverNu Technology, LLC (Warwick, PA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J23/002 - {Mixed oxides other than spinels, e.g. perovskite}
B01J23/28 - Molybdenum
B01J23/30 - Tungsten
B01J23/687 - {with tungsten}
B01J23/888 - Tungsten
B01J23/8885 - {containing also molybdenum}
B01J2523/00 - Constitutive chemical elements of heterogeneous catalysts
B01J2523/53 - Antimony
B01J2523/55 - Vanadium
B01J2523/68 - Molybdenum
B01J35/023 - {Catalysts characterised by dimensions, e.g. grain size}
B01J37/0036 - {Grinding}
B01J37/08 - Heat treatment {

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C1/24 - by elimination of water
C07C11/06 - Propene
C07C11/09 - Isobutene
C07C2523/10 - of rare earths
C07C2523/18 - Arsenic, antimony or bismuth
C07C2523/22 - Vanadium
C07C2523/28 - Molybdenum
C07C2523/30 - Tungsten
C07C2523/745 - Iron
C07C2523/887 - containing in addition other metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
C07C2523/888 - Tungsten
C07C45/38 - being a primary hydroxyl group
C07C47/02 - Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
C07C47/22 - Acryaldehyde
C07C51/235 - of —CHO groups or primary alcohol groups
C07C57/04 - Acrylic acid
C07C67/40 - by oxidation of primary alcohols

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/52 - using catalysts, e.g. selective catalysts

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DOE Contract Number:: SC0007695

Resource Type:: Patent

Resource Relation:: Patent File Date: 12/06/2013

Country of Publication:: United States

Language:: English

Citation Formats


                    Lin, Manhua, and Eng, Wai-Si. Catalytic conversion of bio-mass derivable aliphatic alcohols to valuable alkenes or oxygenates.  United States: N. p., 2019. 
        Web.

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                    Lin, Manhua, & Eng, Wai-Si. Catalytic conversion of bio-mass derivable aliphatic alcohols to valuable alkenes or oxygenates.  United States.

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                    Lin, Manhua, and Eng, Wai-Si. Tue .  
        "Catalytic conversion of bio-mass derivable aliphatic alcohols to valuable alkenes or oxygenates".  United States.  https://www.osti.gov/servlets/purl/1568389.

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@article{osti_1568389,

  title        = {Catalytic conversion of bio-mass derivable aliphatic alcohols to valuable alkenes or oxygenates},

  author       = {Lin, Manhua and Eng, Wai-Si},

  abstractNote = {Disclosed is a method for producing, among others, alkenes and/or saturated or unsaturated oxygenates and, which include at least one of an aldehyde and an acid, comprising subjecting the corresponding C3 to C5 aliphatic alcohols that are derivable from biomass, to a vapor phase process over the catalytic system in the presence of a gas mixture of oxygen, air or nitrogen and/or other suitable diluting gas. The catalyst system comprises multi-catalytic zones, in each of which the composition of the co-feed and other reaction parameter can be independently controlled.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {5}

}

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Works referenced in this record:

Oxidation of alkanes to unsaturated aldehydes and carboxylic acids using a catalyst containing Mo, V, Te and Nb
patent, January 2001

Lin, Manhua; Linsen, Michael
US Patent Document 6,180,825
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6180825

Zn and/or Ga promoted multi-metal oxide catalyst
patent, July 2003

Chaturvedi, Sanjay; Gaffney, Anne Mae; Han, Scott
US Patent Document 6,589,907
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6589907

Fermentive production of isobutanol using highly active ketol-acid reductoisomerase enzymes
patent-application, October 2008

Liao, Der-Ing; Nelson, Mark J.; Bramucci, Michael G.
US Patent Application 12/103844; 20080261230
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080261230

Process for preparing a catalyst
patent, February 2003

Lin, Manhua; Linsen, Michael
US Patent Document 6,514,903
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6514903

Method for preparing acrolein or methacrolein
patent, September 1992

Honda, Tadatoshi; Nagayama, Tokio; Horiuchi, Nobuhiko
US Patent Document 5,144,090
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5144090

Promoted multi-metal oxide catalyst
patent, June 2002

Chaturvedi, Sanjay; Gaffney, Anne Mae; Han, Scott
US Patent Document 6,403,525
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6403525

Process for producing unsaturated aldehydes and unsaturated carboxylic acids
patent, July 1977

Okada, Kazuya; Matsuzawa, Hideo; Ishii, Hiromichi
US Patent Document 4,035,418
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4035418

Catalyst useful for oxidation reactions
patent, November 2004

Lin, Manhua
US Patent Document 6,812,366
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6812366

Promoted multi-metal oxide catalyst
patent, June 2002

Chaturvedi, Sanjay; Gaffney, Anne Mae; Han, Scott
US Patent Document 6,407,280
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6407280

Method for producing methacrylic acid from isobutane
patent, August 2005

Berndt, Silke; Müller-Engel, Klaus Joachim; Schindler, Gotz-Peter
US Patent Document 6,933,407
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6933407

Recycle process
patent, May 2006

Bogan, Jr., Leonard Edward; Bors, Daniel A.; Cavalcanti, Fernando Antonio Pessoa
US Patent Document 7,049,466
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7049466

Method for production of methacrylic acid
patent, September 1990

Abe, Tadashi; Manabe, Mitsuyoshi; Deguchi, Koji
US Patent Document 4,954,650
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4954650

Promoted multi-metal oxide catalyst
patent, May 2002

Bogan, Jr., Leonard Edward
US Patent Document 6,383,978
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6383978

Catalyst useful for oxidation of alkanes
patent, February 2003

Han, Scott; Le, Dominique Hung Nhu; McNeal, Nneka Namono
US Patent Document 6,518,216
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6518216

Catalyst useful for oxidation reactions
patent, November 2003

Lin, Manhua
US Patent Document 6,653,253
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6653253

Process for producing carboxylic esters
patent, February 1981

Tamura, Nobuhiro; Fukuoka, Yohei; Yamamatsu, Setsuo
US Patent Document 4,249,019
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4249019

Method for producing an unsaturated carboxylic acid
patent, January 1995

Ushikubo, Takashi; Nakamura, Hiroya; Koyasu, Yukio
US Patent Document 5,380,933
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5380933

Selective oxidation of alkanes and/or alkenes to valuable oxygenates
patent, February 2011

Lin, Manhua; Pillai, Krishnan S.
US Patent Document 7,888,281
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7888281

Selective Oxidation of Alkanes and/or Alkenes to Valuable Oxygenates
patent-application, July 2008

Lin, Manjua; Pillai, Krishnan S.
US Patent Application 12/016264; 20080177106
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080177106

Process for preparing a catalyst
patent, February 2003

Lin, Manhua; Linsen, Michael
US Patent Document 6,514,901
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6514901

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Similar Records

Title: Catalytic conversion of bio-mass derivable aliphatic alcohols to valuable alkenes or oxygenates

Abstract

Citation Formats

Oxidation of alkanes to unsaturated aldehydes and carboxylic acids using a catalyst containing Mo, V, Te and Nb patent, January 2001

Zn and/or Ga promoted multi-metal oxide catalyst patent, July 2003

Fermentive production of isobutanol using highly active ketol-acid reductoisomerase enzymes patent-application, October 2008

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Method for preparing acrolein or methacrolein patent, September 1992

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Catalyst useful for oxidation reactions patent, November 2004

Promoted multi-metal oxide catalyst patent, June 2002

Method for producing methacrylic acid from isobutane patent, August 2005

Recycle process patent, May 2006

Method for production of methacrylic acid patent, September 1990

Promoted multi-metal oxide catalyst patent, May 2002

Catalyst useful for oxidation of alkanes patent, February 2003

Catalyst useful for oxidation reactions patent, November 2003

Process for producing carboxylic esters patent, February 1981

Method for producing an unsaturated carboxylic acid patent, January 1995

Selective oxidation of alkanes and/or alkenes to valuable oxygenates patent, February 2011

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Oxidation of alkanes to unsaturated aldehydes and carboxylic acids using a catalyst containing Mo, V, Te and Nb
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Zn and/or Ga promoted multi-metal oxide catalyst
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Fermentive production of isobutanol using highly active ketol-acid reductoisomerase enzymes
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Process for preparing a catalyst
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Method for preparing acrolein or methacrolein
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Promoted multi-metal oxide catalyst
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Process for producing unsaturated aldehydes and unsaturated carboxylic acids
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Catalyst useful for oxidation reactions
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Promoted multi-metal oxide catalyst
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Method for producing methacrylic acid from isobutane
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Catalyst useful for oxidation reactions
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