Acid, solvent, and thermal resistant metal-organic frameworks

Yaghi, Omar M.; Lee, Seungkyu; Jiang, Juncong; Zhang, Yuebiao

Title: Acid, solvent, and thermal resistant metal-organic frameworks

Abstract

The disclosure provides for thermal, solvent, and/or acid resistant metal organic frameworks and the use of these frameworks in devices and methods for gas separation, gas storage, and catalysis. The disclosure further provides for MOFs that are strong solid acids, and the use of these strong solid acid MOFs in catalytic devices and catalytic methods.

Inventors:: Yaghi, Omar M.; Lee, Seungkyu; Jiang, Juncong; Zhang, Yuebiao

Issue Date:: Tue May 14 00:00:00 EDT 2019

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1568320

Patent Number(s):: 10287304

Application Number:: 15/116,186

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2253/204 - Metal organic frameworks
B01D33/00 - Filters with filtering elements which move during the filtering operation
B01D53/047 - Pressure swing adsorption
B01D53/228 - {characterised by specific membranes}
B01D63/02 - Hollow fibre modules

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/226 - {Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
B01J20/3085 - {Chemical treatments not covered by groups B01J20/3007 - B01J20/3078}
B01J31/00 - Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/1691 - {Coordination polymers, e.g. metal-organic frameworks [MOF]
B01J37/04 - Mixing {

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F7/003 - {without C-Metal linkages}

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DOE Contract Number:: AC02-05CH11231; SC000105

Resource Type:: Patent

Resource Relation:: Patent File Date: 02/19/2015

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Yaghi, Omar M., Lee, Seungkyu, Jiang, Juncong, and Zhang, Yuebiao. Acid, solvent, and thermal resistant metal-organic frameworks.  United States: N. p., 2019. 
        Web.

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                    Yaghi, Omar M., Lee, Seungkyu, Jiang, Juncong, & Zhang, Yuebiao. Acid, solvent, and thermal resistant metal-organic frameworks.  United States.

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                    Yaghi, Omar M., Lee, Seungkyu, Jiang, Juncong, and Zhang, Yuebiao. Tue .  
        "Acid, solvent, and thermal resistant metal-organic frameworks".  United States.  https://www.osti.gov/servlets/purl/1568320.

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@article{osti_1568320,

  title        = {Acid, solvent, and thermal resistant metal-organic frameworks},

  author       = {Yaghi, Omar M. and Lee, Seungkyu and Jiang, Juncong and Zhang, Yuebiao},

  abstractNote = {The disclosure provides for thermal, solvent, and/or acid resistant metal organic frameworks and the use of these frameworks in devices and methods for gas separation, gas storage, and catalysis. The disclosure further provides for MOFs that are strong solid acids, and the use of these strong solid acid MOFs in catalytic devices and catalytic methods.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue May 14 00:00:00 EDT 2019},

  month        = {Tue May 14 00:00:00 EDT 2019}

}

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Title: Acid, solvent, and thermal resistant metal-organic frameworks

Abstract

Citation Formats

Process for Manufacture of Olefin Oxides patent, July 1954

Crystallisation facilitators for the synthesis of metal organic frameworks patent, September 2015

Crystalline metal-organic microporous materials patent, July 1997

Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent, April 2007

Adsorption process with on-line adsorbent removal patent-application, November 2006

Metal-organic frameworks with exceptionally large pore aperatures patent, July 2015

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent, March 2007

Polymerisation and oligomerisation catalysts patent, June 2007

Process for preparing an organometallic framework material patent-application, July 2005

Gas storage system patent-application, December 2004

Preparation of metal-containing zeolite catalysts of increased stability and activity patent, July 1985

Process for preparing hydrogen peroxide from the elements patent-application, March 2006

1,2,3-triazole based metal-organic framework as photo-active materials patent-application, November 2011

Covalently linked organic frameworks and polyhedra patent, September 2009

Mesh-Adjustable Molecular Sieve patent-application, August 2008

PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS patent-application, August 2007

Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO2 patent, July 2016

Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature patent, September 2010

Bone graft composition patent-application, October 2007

SHAPED BODIES CONTAINING METAL-ORGANIC FRAMEWORKS patent-application, June 2009

Covalent Organic Frameworks and Methods of Making Same patent-application, May 2014

Fluorinated metal-organic frameworks for gas storage patent, January 2013

Zeolite-like metal organic frameworks (ZMOFS): modular approach to the synthesis of organic-inorganic hybrid porous materials having a zeolite like topology patent-application, December 2006

Air Collector with Functionalized Ion Exchange Membrane for Capturing Ambient CO2 patent-application, September 2007

Bleaching composition for dry cleaning containing transition metal bleach catalyst patent, November 2002

Covalently linked organic frameworks and polyhedra patent-application, July 2006

Gas Sensor Incorporating a Porous Framework patent-application, February 2012

Reversible ethylene oxide capture in porous frameworks patent, April 2014

Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature patent-application, March 2007

CHEMICAL FRAMEWORK COMPOSITIONS AND METHODS OF USE patent-application, June 2011

Synthesis of inorganic membranes on supports patent, July 1998

Process for preparing porous metal-organic frameworks based on aluminum fumarate patent, September 2013

Substituted benzazoloporphyrazines for polymerization and surface attachment and articles formed therefrom patent-application, January 2011

Gas sensor incorporating a porous framework patent, May 2014

Reversible oxygen sorbent compositions patent, May 1993

System and method for generating and/or screening potential metal-organic frameworks patent, December 2014

Zeolite synthesis using an alcohol or like molecules patent, November 1992

Metal oxides from metal-organic framework materials patent, August 2013

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application, September 2005

Metal-organic framework materials for gaseous hydrocarbon storage patent, March 2008

Metal organic framework—polymer mixed matrix membranes patent, December 2009

Adsorbing Agent, Dust Collection Chamber And Method For Adsorbing Odours patent-application, January 2008

Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application, December 2004

Mixed metal framework compositions for monoalkylene glycol production patent, November 1991

Gas storage system patent, December 2007

Porous Metal Organic Framework Based On Pyrroles And Pyridinones patent-application, July 2009

Non-regenerating carbon monoxide sensor patent, March 1998

EDIBLE AND BIOCOMPATIBLE METAL-ORGANIC FRAMEWORKS patent-application, November 2010

Method of using a metal organic frameworks based on aluminum fumarate patent, August 2013

Late transition metal catalyst complexes and oligomers therefrom patent, December 2002

Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials patent-application, August 2009

Communication system for connection to a base station of a multi-cellular wireless telephone system patent, April 1997

Gas Odorous Substance Separation patent-application, August 2008

Gas Adsorption on Metal-Organic Frameworks patent-application, March 2010

Crystalline membranes patent-application, January 2005

Shaped bodies containing metal-organic frameworks patent, May 2005

Method of storing, uptaking, releasing of gases by novel framework materials patent-application, August 2003

Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals patent, January 2010

Method of storing, uptaking, releasing of gases by novel framework materials patent, August 2005

Polymeric Foams with Nanocellular Morphology and Methods for Making Them patent-application, October 2009

Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene patent-application, November 2011

Reversible Ethylene Oxide Capture in Porous Frameworks patent-application, February 2012

Carbon Dioxide Capture and Storage Using Open Frameworks patent-application, May 2012

Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent-application, January 2005

Porous organo-metallic skeleton material containing an additional polymer patent, October 2010

Process for preparing and organometallic framework material patent, August 2008

Shaped bodies containing metal-organic frameworks patent-application, December 2003

ADSORPTIVE GAS SEPARATION OF MULTI-COMPONENT GASES patent-application, June 2010

Process for the alkoxylation of organic compounds in the presence of novel framework materials patent, October 2007

Organic Porous Materials Comprising Shape-Persistent Three-Dimensional Molecular Cage Building Blocks patent-application, February 2013

High gas adsorption metal-organic framework patent, February 2010

Process for preparing hydrogen peroxide from the elements patent-application, April 2004

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application, January 2003

Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals patent-application, November 2004

Metal-organic polyhedra patent-application, June 2005

Shaped bodies containing metal-organic frameworks patent, April 2009

Process for producing polyalkylene carbonates patent, September 2003

Process for Manufacture of Olefin Oxides
patent, July 1954

Crystallisation facilitators for the synthesis of metal organic frameworks
patent, September 2015

Crystalline metal-organic microporous materials
patent, July 1997

Process for the alkoxylation of monools in the presence of metallo-organic framework materials
patent, April 2007

Adsorption process with on-line adsorbent removal
patent-application, November 2006

Metal-organic frameworks with exceptionally large pore aperatures
patent, July 2015

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
patent, March 2007

Polymerisation and oligomerisation catalysts
patent, June 2007

Process for preparing an organometallic framework material
patent-application, July 2005

Gas storage system
patent-application, December 2004

Preparation of metal-containing zeolite catalysts of increased stability and activity
patent, July 1985

Process for preparing hydrogen peroxide from the elements
patent-application, March 2006

1,2,3-triazole based metal-organic framework as photo-active materials
patent-application, November 2011

Covalently linked organic frameworks and polyhedra
patent, September 2009

Mesh-Adjustable Molecular Sieve
patent-application, August 2008

PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS
patent-application, August 2007

Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO2
patent, July 2016

Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature
patent, September 2010

Bone graft composition
patent-application, October 2007

SHAPED BODIES CONTAINING METAL-ORGANIC FRAMEWORKS
patent-application, June 2009

Covalent Organic Frameworks and Methods of Making Same
patent-application, May 2014

Fluorinated metal-organic frameworks for gas storage
patent, January 2013

Zeolite-like metal organic frameworks (ZMOFS): modular approach to the synthesis of organic-inorganic hybrid porous materials having a zeolite like topology
patent-application, December 2006

Air Collector with Functionalized Ion Exchange Membrane for Capturing Ambient CO₂
patent-application, September 2007

Bleaching composition for dry cleaning containing transition metal bleach catalyst
patent, November 2002

Covalently linked organic frameworks and polyhedra
patent-application, July 2006

Gas Sensor Incorporating a Porous Framework
patent-application, February 2012

Reversible ethylene oxide capture in porous frameworks
patent, April 2014

Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature
patent-application, March 2007

CHEMICAL FRAMEWORK COMPOSITIONS AND METHODS OF USE
patent-application, June 2011

Synthesis of inorganic membranes on supports
patent, July 1998

Process for preparing porous metal-organic frameworks based on aluminum fumarate
patent, September 2013

Substituted benzazoloporphyrazines for polymerization and surface attachment and articles formed therefrom
patent-application, January 2011

Gas sensor incorporating a porous framework
patent, May 2014

Reversible oxygen sorbent compositions
patent, May 1993

System and method for generating and/or screening potential metal-organic frameworks
patent, December 2014

Zeolite synthesis using an alcohol or like molecules
patent, November 1992

Metal oxides from metal-organic framework materials
patent, August 2013

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
patent-application, September 2005

Metal-organic framework materials for gaseous hydrocarbon storage
patent, March 2008

Metal organic framework—polymer mixed matrix membranes
patent, December 2009

Adsorbing Agent, Dust Collection Chamber And Method For Adsorbing Odours
patent-application, January 2008

Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent-application, December 2004

Mixed metal framework compositions for monoalkylene glycol production
patent, November 1991

Gas storage system
patent, December 2007

Porous Metal Organic Framework Based On Pyrroles And Pyridinones
patent-application, July 2009

Non-regenerating carbon monoxide sensor
patent, March 1998

EDIBLE AND BIOCOMPATIBLE METAL-ORGANIC FRAMEWORKS
patent-application, November 2010

Method of using a metal organic frameworks based on aluminum fumarate
patent, August 2013

Late transition metal catalyst complexes and oligomers therefrom
patent, December 2002

Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials
patent-application, August 2009

Communication system for connection to a base station of a multi-cellular wireless telephone system
patent, April 1997

Gas Odorous Substance Separation
patent-application, August 2008

Gas Adsorption on Metal-Organic Frameworks
patent-application, March 2010

Crystalline membranes
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Shaped bodies containing metal-organic frameworks
patent, May 2005

Method of storing, uptaking, releasing of gases by novel framework materials
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Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals
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Method of storing, uptaking, releasing of gases by novel framework materials
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Polymeric Foams with Nanocellular Morphology and Methods for Making Them
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Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene
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Reversible Ethylene Oxide Capture in Porous Frameworks
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Carbon Dioxide Capture and Storage Using Open Frameworks
patent-application, May 2012

Process for the alkoxylation of monools in the presence of metallo-organic framework materials
patent-application, January 2005

Porous organo-metallic skeleton material containing an additional polymer
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Process for preparing and organometallic framework material
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patent-application, December 2003

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patent-application, June 2010

Process for the alkoxylation of organic compounds in the presence of novel framework materials
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High gas adsorption metal-organic framework
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Process for preparing hydrogen peroxide from the elements
patent-application, April 2004

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Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals
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Metal-organic polyhedra
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Process for producing polyalkylene carbonates
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High gas adsorption in a microporous metal-organic framework with open-metal sites
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Metal-organic framework materials for gaseous hydrocarbon storage
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Process for the alkoxylation of monools in the presence of metallo-organic framework materials
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