Mixed metal iron oxides and uses thereof

Shen, Jian-ping; Lail, Marty; Turk, Brian; Mobley, Paul D.; Norman, Jason S.; Douglas, Laura; Peters, Jonathan

Title: Mixed metal iron oxides and uses thereof

Abstract

This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO2 and the selective reaction with organic compounds.

Inventors:: Shen, Jian-ping; Lail, Marty; Turk, Brian; Mobley, Paul D.; Norman, Jason S.; Douglas, Laura; Peters, Jonathan

Issue Date:: 2019-05-14

Research Org.:: Research Triangle Inst., Research Triangle Park, NC (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1568316

Patent Number(s):: 10286383

Application Number:: 15/808,514

Assignee:: Research Triangle Institute (Research Triangle Park, NC)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2523/80 - with zinc, cadmium or mercury

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2523/31 - Aluminium
B01J37/14 - with gases containing free oxygen
B01J2523/13 - Potassium
B01J2523/27 - Zinc

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/0238 - the reforming step being a carbon dioxide reforming step

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J37/03 - Precipitation
B01J2523/842 - Iron

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2400/30 - Aromatics

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/1088 - Non-supported catalysts

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J23/74 - Iron group metals

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2400/22 - Higher olefins

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J23/80 - with zinc, cadmium or mercury

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/0986 - Catalysts

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/1064 - Platinum group metal catalysts

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C31/04 - Methanol

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J23/8906 - {Iron and noble metals}
B01J23/83 - with rare earths or actinides

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C13/20 - with a cyclohexene ring

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2523/22 - Magnesium

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J3/725 - {Redox processes}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C29/156 - containing iron group metals, platinum group metals or compounds thereof
C07C2521/06 - Silicon, titanium, zirconium or hafnium
C07C2523/835 - with germanium, tin or lead
C07C2523/46 - Ruthenium, rhodium, osmium or iridium
C07C2521/04 - Alumina

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2523/00 - Constitutive chemical elements of heterogeneous catalysts

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J3/463 - {in stationary fluidised beds}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2521/08 - Silica

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/1235 - Hydrocarbons

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C1/041 - {Reactors}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/40 - characterised by the catalyst

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/1653 - integrated in a gasification combined cycle [IGCC]

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D301/03 - by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J35/002 - {Catalysts characterised by their physical properties}

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G27/00 - Refining of hydrocarbon oils in the absence of hydrogen, by oxidation

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C11/02 - Alkenes

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2523/72 - Manganese
B01J2523/821 - Ruthenium
B01J23/835 - with germanium, tin or lead
B01J2523/43 - Tin

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C11/06 - Propene

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E20/18 - Integrated gasification combined cycle [IGCC]

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C11/22 - containing carbon-to-carbon triple bonds

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/52 - using catalysts, e.g. selective catalysts

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C11/04 - Ethylene

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2523/3706 - Lanthanum

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/0969 - Carbon dioxide

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2523/78 - with alkali- or alkaline earth metals or beryllium

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J37/18 - with gases containing free hydrogen
B01J23/76 - combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
B01J2523/845 - Cobalt

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2523/889 - Manganese, technetium or rhenium
C07C2601/16 - the ring being unsaturated

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2523/24 - Strontium
B01J2523/17 - Copper

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C5/42 - by dehydrogenation with a hydrogen acceptor

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/40 - Carbon monoxide

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J23/8892 - {Manganese}
B01J23/002 - {Mixed oxides other than spinels, e.g. perovskite}
B01J21/02 - Boron or aluminium
B01J23/78 - with alkali- or alkaline earth metals

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C15/46 - Styrene
C07C9/06 - Ethane
C07C2/84 - catalytic
C07C2523/89 - combined with noble metals
C07C2523/83 - with rare earths or actinides
C07C2523/74 - Iron group metals

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/1047 - Group VIII metal catalysts

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DOE Contract Number:: FE0004329

Resource Type:: Patent

Resource Relation:: Patent File Date: 11/09/2017

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES

Citation Formats


                    Shen, Jian-ping, Lail, Marty, Turk, Brian, Mobley, Paul D., Norman, Jason S., Douglas, Laura, and Peters, Jonathan. Mixed metal iron oxides and uses thereof.  United States: N. p., 2019. 
        Web.

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                    Shen, Jian-ping, Lail, Marty, Turk, Brian, Mobley, Paul D., Norman, Jason S., Douglas, Laura, & Peters, Jonathan. Mixed metal iron oxides and uses thereof.  United States.

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                    Shen, Jian-ping, Lail, Marty, Turk, Brian, Mobley, Paul D., Norman, Jason S., Douglas, Laura, and Peters, Jonathan. Tue .  
        "Mixed metal iron oxides and uses thereof".  United States.  https://www.osti.gov/servlets/purl/1568316.

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@article{osti_1568316,

  title        = {Mixed metal iron oxides and uses thereof},

  author       = {Shen, Jian-ping and Lail, Marty and Turk, Brian and Mobley, Paul D. and Norman, Jason S. and Douglas, Laura and Peters, Jonathan},

  abstractNote = {This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO2 and the selective reaction with organic compounds.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {5}

}

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Similar Records

Title: Mixed metal iron oxides and uses thereof

Abstract

Citation Formats

Process for the preparation of a new catalyst useful for producing alkylated aromatic amines patent, March 2000

Dehydrogenation catalyst patent, May 1979

Process for preparing acetonitrile patent, November 1977

Process using catalysts for selective catalytic reduction denox technology patent, December 1990

Process for producing ethanol from synthesis gas patent, November 1980

Method for producing carbon monoxide by reverse conversion with an adapted catalyst patent-application, June 2003

Process for the liquid phase hydrogenation of coal patent, April 1985

Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds patent, October 2000

Catalytic oxidation patent, January 1978

Preparation of vanadium antimony oxide based catalysts using nano-scale iron patent, March 2005

Process for converting a hydrocarbon to an oxygenate or a nitrile patent, November 2007

Catalysts for selective catalytic reduction DeNOx technology patent, May 1990

Vehicle exhaust gas catalysts patent, September 1991

Process for converting a hydrocarbon to an oxygenate or a nitrile patent, August 2015

Dehydrogenation process patent, March 1979

Process For Converting A Hydrocarbon To An Oxygenate Or A Nitrile patent-application, February 2008

Mixed Oxide Based Catalyst For The Conversion Of Carbon Dioxide To Syngas And Method Of Preparation And Use patent-application, June 2013

Solid mixed oxide composition containing molybdenum, cobalt and bismuth, which is suitable for the manufacture of acrolein from propylene by a redox reaction patent, June 2001

Process for the preparation of a new catalyst useful for producing alkylated aromatic amines
patent, March 2000

Dehydrogenation catalyst
patent, May 1979

Process for preparing acetonitrile
patent, November 1977

Process using catalysts for selective catalytic reduction denox technology
patent, December 1990

Process for producing ethanol from synthesis gas
patent, November 1980

Method for producing carbon monoxide by reverse conversion with an adapted catalyst
patent-application, June 2003

Process for the liquid phase hydrogenation of coal
patent, April 1985

Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds
patent, October 2000

Catalytic oxidation
patent, January 1978

Preparation of vanadium antimony oxide based catalysts using nano-scale iron
patent, March 2005

Process for converting a hydrocarbon to an oxygenate or a nitrile
patent, November 2007

Catalysts for selective catalytic reduction DeNOx technology
patent, May 1990

Vehicle exhaust gas catalysts
patent, September 1991

Process for converting a hydrocarbon to an oxygenate or a nitrile
patent, August 2015

Dehydrogenation process
patent, March 1979

Process For Converting A Hydrocarbon To An Oxygenate Or A Nitrile
patent-application, February 2008

Mixed Oxide Based Catalyst For The Conversion Of Carbon Dioxide To Syngas And Method Of Preparation And Use
patent-application, June 2013

Solid mixed oxide composition containing molybdenum, cobalt and bismuth, which is suitable for the manufacture of acrolein from propylene by a redox reaction
patent, June 2001