Metal cyanometallates

Lu, Yuhao; Wang, Long; Vail, Sean; Lee, Jong-Jan

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Title: Metal cyanometallates

Abstract

Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q (CN)R.FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T.DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.

Inventors:: Lu, Yuhao; Wang, Long; Vail, Sean; Lee, Jong-Jan

Issue Date:: 2018-05-08

Research Org.:: Sharp Labs of America, Inc., Camas, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1532085

Patent Number(s):: 9966602

Application Number:: 15/279,588

Assignee:: Sharp Laboratories of America, Inc. (Camas, WA)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01C - AMMONIA

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01C - AMMONIA
C01C3/11 - Complex cyanides
C01C3/12 - Simple or complex iron cyanides

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/50 - Solid solutions
C01P2006/40 - Electric properties

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/58 - of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AR0000297

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016-09-29

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Lu, Yuhao, Wang, Long, Vail, Sean, and Lee, Jong-Jan. Metal cyanometallates.  United States: N. p., 2018. 
        Web.

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                    Lu, Yuhao, Wang, Long, Vail, Sean, & Lee, Jong-Jan. Metal cyanometallates.  United States.

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                    Lu, Yuhao, Wang, Long, Vail, Sean, and Lee, Jong-Jan. Tue .  
        "Metal cyanometallates".  United States.  https://www.osti.gov/servlets/purl/1532085.

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@article{osti_1532085,

  title        = {Metal cyanometallates},

  author       = {Lu, Yuhao and Wang, Long and Vail, Sean and Lee, Jong-Jan},

  abstractNote = {Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q (CN)R.FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T.DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {5}

}

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Works referenced in this record:

Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries
journal, December 2011

Wessells, Colin D.; Peddada, Sandeep V.; Huggins, Robert A.
Nano Letters, Vol. 11, Issue 12, p. 5421-5425
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Iron Hexacyanoferrate Nanoparticles as Cathode Materials for Lithium and Sodium Rechargeable Batteries
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Yu, S. -H.; Shokouhimehr, M.; Hyeon, T.
ECS Electrochemistry Letters, Vol. 2, Issue 4
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The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes
journal, January 2012

Wessells, Colin D.; Peddada, Sandeep V.; McDowell, Matthew T.
Journal of The Electrochemical Society, Vol. 159, Issue 2, p. A98-A103
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Potassium secondary cell based on Prussian blue cathode
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Eftekhari, Ali
Journal of Power Sources, Vol. 126, Issue 1-2, p. 221-228
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A Superior Low-Cost Cathode for a Na-Ion Battery
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Wang, Long; Lu, Yuhao; Liu, Jue
Angewandte Chemie International Edition, Vol. 52, Issue 7
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High Rate, Long Cycle Life Battery Electrode Materials With An Open Framework Structure
patent-application, December 2012

Wessells, Colin; Huggins, Robert; Cui, Yi
US Patent Application 13/482793; 20120328936
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120328936

Lithium intercalation behavior into iron cyanide complex as positive electrode of lithium secondary battery
journal, June 1999

Imanishi, N.; Morikawa, T.; Kondo, J.
Journal of Power Sources, Vol. 79, Issue 2
https://doi.org/10.1016/S0378-7753(99)00061-0

A sodium manganese ferrocyanide thin film for Na-ion batteries
journal, January 2013

Matsuda, Tomoyuki; Takachi, Masamitsu; Moritomo, Yutaka
Chemical Communications, Vol. 49, Issue 27
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Copper hexacyanoferrate battery electrodes with long cycle life and high power
journal, November 2011

Wessells, Colin D.; Huggins, Robert A.; Cui, Yi
Nature Communications, Vol. 2, Article No. 550
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Some Performance Characteristics of a Prussian Blue Battery
journal, January 1985

Neff, Vernon D.
Journal of The Electrochemical Society, Vol. 132, Issue 6, p. 1382-1384
https://doi.org/10.1149/1.2114121

Prussian blue: a new framework of electrode materials for sodium batteries
journal, January 2012

Lu, Yuhao; Wang, Long; Cheng, Jinguang
Chemical Communications, Vol. 48, Issue 52, p. 6544-6546
https://doi.org/10.1039/c2cc31777j

Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries
journal, January 2013

Wu, Xianyong; Deng, Wenwen; Qian, Jiangfeng
Journal of Materials Chemistry A, Vol. 1, Issue 35
https://doi.org/10.1039/c3ta12036h

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A method is provided for cycling power in a transition metal cyanometallate (TMCM) cathode battery. The method provides a battery with a TMCM cathode, an anode, and an electrolyte, where TMCM corresponds to the chemical formula of AXM1NM2M(CN)Y-d(H2O), where “A” is an alkali or alkaline earth metal, and where M1 and M2 are transition metals. The method charges the battery using a first charging current, or greater. In response to the charging current, a plating of “A” metal is formed overlying a plating surface of the anode. In response to discharging the battery, the “A” metal plating is removed frommore » « less
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Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q(CN)R.FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T. DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.
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Similar Records

Title: Metal cyanometallates

Abstract

Citation Formats

Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries journal, December 2011

Iron Hexacyanoferrate Nanoparticles as Cathode Materials for Lithium and Sodium Rechargeable Batteries journal, January 2013

The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes journal, January 2012

Potassium secondary cell based on Prussian blue cathode journal, February 2004

A Superior Low-Cost Cathode for a Na-Ion Battery journal, January 2013

High Rate, Long Cycle Life Battery Electrode Materials With An Open Framework Structure patent-application, December 2012

Lithium intercalation behavior into iron cyanide complex as positive electrode of lithium secondary battery journal, June 1999

A sodium manganese ferrocyanide thin film for Na-ion batteries journal, January 2013

Copper hexacyanoferrate battery electrodes with long cycle life and high power journal, November 2011

Some Performance Characteristics of a Prussian Blue Battery journal, January 1985

Prussian blue: a new framework of electrode materials for sodium batteries journal, January 2012

Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries journal, January 2013

Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries
journal, December 2011

Iron Hexacyanoferrate Nanoparticles as Cathode Materials for Lithium and Sodium Rechargeable Batteries
journal, January 2013

The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes
journal, January 2012

Potassium secondary cell based on Prussian blue cathode
journal, February 2004

A Superior Low-Cost Cathode for a Na-Ion Battery
journal, January 2013

High Rate, Long Cycle Life Battery Electrode Materials With An Open Framework Structure
patent-application, December 2012

Lithium intercalation behavior into iron cyanide complex as positive electrode of lithium secondary battery
journal, June 1999

A sodium manganese ferrocyanide thin film for Na-ion batteries
journal, January 2013

Copper hexacyanoferrate battery electrodes with long cycle life and high power
journal, November 2011

Some Performance Characteristics of a Prussian Blue Battery
journal, January 1985

Prussian blue: a new framework of electrode materials for sodium batteries
journal, January 2012

Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries
journal, January 2013