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Title: Metal cyanometallates

Abstract

Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q (CN)R.FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T.DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.

Inventors:
; ; ;
Issue Date:
Research Org.:
Sharp Labs of America, Inc., Camas, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1532085
Patent Number(s):
9966602
Application Number:
15/279,588
Assignee:
Sharp Laboratories of America, Inc. (Camas, WA)
Patent Classifications (CPCs):
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01C - AMMONIA
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AR0000297
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016-09-29
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats

Lu, Yuhao, Wang, Long, Vail, Sean, and Lee, Jong-Jan. Metal cyanometallates. United States: N. p., 2018. Web.
Lu, Yuhao, Wang, Long, Vail, Sean, & Lee, Jong-Jan. Metal cyanometallates. United States.
Lu, Yuhao, Wang, Long, Vail, Sean, and Lee, Jong-Jan. Tue . "Metal cyanometallates". United States. https://www.osti.gov/servlets/purl/1532085.
@article{osti_1532085,
title = {Metal cyanometallates},
author = {Lu, Yuhao and Wang, Long and Vail, Sean and Lee, Jong-Jan},
abstractNote = {Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q (CN)R.FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T.DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {5}
}

Works referenced in this record:

Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries
journal, December 2011


Iron Hexacyanoferrate Nanoparticles as Cathode Materials for Lithium and Sodium Rechargeable Batteries
journal, January 2013


The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes
journal, January 2012


Potassium secondary cell based on Prussian blue cathode
journal, February 2004


A Superior Low-Cost Cathode for a Na-Ion Battery
journal, January 2013


Lithium intercalation behavior into iron cyanide complex as positive electrode of lithium secondary battery
journal, June 1999


A sodium manganese ferrocyanide thin film for Na-ion batteries
journal, January 2013


Copper hexacyanoferrate battery electrodes with long cycle life and high power
journal, November 2011


Some Performance Characteristics of a Prussian Blue Battery
journal, January 1985


Prussian blue: a new framework of electrode materials for sodium batteries
journal, January 2012


Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries
journal, January 2013