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Title: Metal cyanometallates

Abstract

Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q (CN)R.FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T.DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.

Inventors:
; ; ;
Issue Date:
Research Org.:
Sharp Labs of America, Inc., Camas, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1532085
Patent Number(s):
9,966,602
Application Number:
15/279,588
Assignee:
Sharp Laboratories of America, Inc. (Camas, WA)
DOE Contract Number:  
AR0000297
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016-09-29
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats

Lu, Yuhao, Wang, Long, Vail, Sean, and Lee, Jong-Jan. Metal cyanometallates. United States: N. p., 2018. Web.
Lu, Yuhao, Wang, Long, Vail, Sean, & Lee, Jong-Jan. Metal cyanometallates. United States.
Lu, Yuhao, Wang, Long, Vail, Sean, and Lee, Jong-Jan. Tue . "Metal cyanometallates". United States. https://www.osti.gov/servlets/purl/1532085.
@article{osti_1532085,
title = {Metal cyanometallates},
author = {Lu, Yuhao and Wang, Long and Vail, Sean and Lee, Jong-Jan},
abstractNote = {Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q (CN)R.FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T.DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {5}
}

Patent:

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