Metal cyanometallate synthesis method
Abstract
A method is provided for synthesizing metal cyanometallate (MCM). The method provides a solution of AXM1Y(CN)Z; where “A” is selected from a first group of metals and M1 is selected from a second group of metals. The method adds a material including M2 to the solution to form a liquid phase material that may be either a suspension or a solution. M2 is selected from the second group of metals. The method adds acid to the liquid phase material. The addition of acid to the liquid phase material decomposes the M2 material into M2-ions. Simultaneous with the addition of the acid, a precipitate of ANM1PM2Q(CN)R.FH2O is formed, where N is in a range of 1 to 2. A variation of the above-described synthesis method is also provided.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of Texas, Austin, TX (United States); Sharp Labs. of America, Inc., Camas, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1532012
- Patent Number(s):
- 9745202
- Application Number:
- 14/731,607
- Assignee:
- Board of Regents, The University of Texas System (Austin, TX); Sharp Laboratories of America, Inc. (Camas, WA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01C - AMMONIA
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- DOE Contract Number:
- AR0000297
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015-06-05
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Song, Jie, Lu, Yuhao, and Wang, Long. Metal cyanometallate synthesis method. United States: N. p., 2017.
Web.
Song, Jie, Lu, Yuhao, & Wang, Long. Metal cyanometallate synthesis method. United States.
Song, Jie, Lu, Yuhao, and Wang, Long. Tue .
"Metal cyanometallate synthesis method". United States. https://www.osti.gov/servlets/purl/1532012.
@article{osti_1532012,
title = {Metal cyanometallate synthesis method},
author = {Song, Jie and Lu, Yuhao and Wang, Long},
abstractNote = {A method is provided for synthesizing metal cyanometallate (MCM). The method provides a solution of AXM1Y(CN)Z; where “A” is selected from a first group of metals and M1 is selected from a second group of metals. The method adds a material including M2 to the solution to form a liquid phase material that may be either a suspension or a solution. M2 is selected from the second group of metals. The method adds acid to the liquid phase material. The addition of acid to the liquid phase material decomposes the M2 material into M2-ions. Simultaneous with the addition of the acid, a precipitate of ANM1PM2Q(CN)R.FH2O is formed, where N is in a range of 1 to 2. A variation of the above-described synthesis method is also provided.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {8}
}
Works referenced in this record:
Methods for the preparation of metallic alloy nanoparticles and compositions thereof
patent-application, December 2005
- Bocarsly, Andrew B.; Zhu, Shu
- US Patent Application 11/208948; 20050274225