Battery anode with preloaded metals

Wang, Long; Lu, Yuhao; Lee, Jong-Jan

Title: Battery anode with preloaded metals

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Abstract

A method is presented for fabricating an anode preloaded with consumable metals. The method provides a material (X), which may be one of the following materials: carbon, metals able to be electrochemically alloyed with a metal (Me), intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. The method loads the metal (Me) into the material (X). Typically, Me is an alkali metal, alkaline earth metal, or a combination of the two. As a result, the method forms a preloaded anode comprising Me/X for use in a battery comprising a M1YM2Z(CN)N.MH2O cathode, where M1 and M2 are transition metals. The method loads the metal (Me) into the material (X) using physical (mechanical) mixing, a chemical reaction, or an electrochemical reaction. Also provided is preloaded anode, preloaded with consumable metals.

Inventors:: Wang, Long; Lu, Yuhao; Lee, Jong-Jan

Issue Date:: 2017-01-03

Research Org.:: Sharp Laboratories of America, Inc., Camas, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1531967

Patent Number(s):: 9537131

Application Number:: 14/198,663

Assignee:: Sharp Laboratories of America, Inc. (Camas, WA)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B19/02 - Elemental selenium or tellurium

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T29/49108 - Electric battery cell making

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B17/02 - Preparation of sulfur

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/0416 - {involving impregnation with a solution, dispersion, paste or dry powder
H01M4/0404 - {by coating on electrode collectors}
H01M4/0452 - {from solutions}
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/0471 - {involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B33/021 - Preparation

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/58 - of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/1391 - of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/623 - {fluorinated polymers}
H01M10/052 - Li-accumulators

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01D - COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
C01D1/02 - Oxides

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/88 - by thermal analysis data, e.g. TGA, DTA, DSC

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/134 - Electrodes based on metals, Si or alloys

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/72 - by d-values or two theta-values, e.g. as X-ray diagram

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M4/387 - {Tin or alloys based on tin}
H01M2004/027 - {Negative electrodes}
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M4/587 - for inserting or intercalating light metals
H01M4/5825 - {Oxygenated metallic slats or polyanionic structures, e.g. borates, phosphates, silicates, olivines}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/00 - Carbon

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M4/56 - of lead
H01M4/628 - {Inhibitors, e.g. gassing inhibitors, corrosion inhibitors}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B25/003 - {Phosphorus}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/77 - by unit-cell parameters, atom positions or structure diagrams

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/0495 - {Chemical alloying}
H01M4/049 - {Manufacturing of an active layer by chemical means}
H01M4/1397 - of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01D - COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
C01D15/02 - Oxides

H - ELECTRICITY H02 - GENERATION H02J - CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER
H02J7/0042 - {characterised by the mechanical construction}

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/5815 - {Sulfides}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J6/008 - {Pyrolysis reactions

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/1395 - of electrodes based on metals, Si or alloys
H01M4/04 - Processes of manufacture in general
H01M4/60 - of organic compounds
H01M10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M4/366 - {as layered products}
H01M4/133 - Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M4/0497 - {Chemical precipitation}
H01M4/382 - {Lithium
H01M4/381 - {Alkaline or alkaline earth metals elements
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/38 - of elements or alloys

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01C - AMMONIA
C01C3/12 - Simple or complex iron cyanides

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DOE Contract Number:: AR0000297

Resource Type:: Patent

Resource Relation:: Patent File Date: 2014-03-06

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Wang, Long, Lu, Yuhao, and Lee, Jong-Jan. Battery anode with preloaded metals.  United States: N. p., 2017. 
        Web.

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                    Wang, Long, Lu, Yuhao, & Lee, Jong-Jan. Battery anode with preloaded metals.  United States.

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                    Wang, Long, Lu, Yuhao, and Lee, Jong-Jan. Tue .  
        "Battery anode with preloaded metals".  United States.  https://www.osti.gov/servlets/purl/1531967.

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@article{osti_1531967,

  title        = {Battery anode with preloaded metals},

  author       = {Wang, Long and Lu, Yuhao and Lee, Jong-Jan},

  abstractNote = {A method is presented for fabricating an anode preloaded with consumable metals. The method provides a material (X), which may be one of the following materials: carbon, metals able to be electrochemically alloyed with a metal (Me), intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. The method loads the metal (Me) into the material (X). Typically, Me is an alkali metal, alkaline earth metal, or a combination of the two. As a result, the method forms a preloaded anode comprising Me/X for use in a battery comprising a M1YM2Z(CN)N.MH2O cathode, where M1 and M2 are transition metals. The method loads the metal (Me) into the material (X) using physical (mechanical) mixing, a chemical reaction, or an electrochemical reaction. Also provided is preloaded anode, preloaded with consumable metals.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2017},

  month        = {1}

}

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