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Title: Porous polymer network materials

Abstract

Functionalized Porous Polymer Networks (PPNs) exhibiting favourable characteristics such as high surface area′ and gas uptake properties are disclosed, including methods of making such networks. A method of preparing a porous polymer network, comprising: (a) a step of homo-coupling a monomer in the presence of 2,2′-bipyridyl, 1,5-cycloocta-1,5-diene, a mixed solvent of DMF/THF and a compound or mixture selected from the group consisting of bis(1,5-cydoocta-1,5-diene)nickel(0), Ni(PPH3) 4, and Zn/NiCI2/NaBr/PPH3 at a temperature in the range of 20 to 40° C. These stable PPNs may be useful in the context of carbon capture, gas storage and separation, and as supports for catalysts.

Inventors:
; ;
Issue Date:
Research Org.:
Texas A&M Univ., College Station, TX (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1531926
Patent Number(s):
9,409,116
Application Number:
14/405,653
Assignee:
The Texas A&M University System (College Station, TX)
DOE Contract Number:  
AR0000073
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012-12-13
Country of Publication:
United States
Language:
English

Citation Formats

Zhou, Hong -Cai, Sculley, Julian, and Lu, Weigang. Porous polymer network materials. United States: N. p., 2016. Web.
Zhou, Hong -Cai, Sculley, Julian, & Lu, Weigang. Porous polymer network materials. United States.
Zhou, Hong -Cai, Sculley, Julian, and Lu, Weigang. Tue . "Porous polymer network materials". United States. https://www.osti.gov/servlets/purl/1531926.
@article{osti_1531926,
title = {Porous polymer network materials},
author = {Zhou, Hong -Cai and Sculley, Julian and Lu, Weigang},
abstractNote = {Functionalized Porous Polymer Networks (PPNs) exhibiting favourable characteristics such as high surface area′ and gas uptake properties are disclosed, including methods of making such networks. A method of preparing a porous polymer network, comprising: (a) a step of homo-coupling a monomer in the presence of 2,2′-bipyridyl, 1,5-cycloocta-1,5-diene, a mixed solvent of DMF/THF and a compound or mixture selected from the group consisting of bis(1,5-cydoocta-1,5-diene)nickel(0), Ni(PPH3) 4, and Zn/NiCI2/NaBr/PPH3 at a temperature in the range of 20 to 40° C. These stable PPNs may be useful in the context of carbon capture, gas storage and separation, and as supports for catalysts.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {8}
}

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Works referenced in this record:

Porous polymer networks and ion-exchange media and metal-polymer composites made therefrom
patent, March 2015


Carbon dioxide capture and storage using open frameworks
patent, November 2014