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Title: Highly durable nanoscale electrocatalyst based on core shell particles

Abstract

A multimetallic nanoscale catalyst having a sore portion enveloped by a shell portion and exhibiting high catalytic activity and improved catalytic durability. In various embodiments, the core/shell nanoparticles comprise a gold particle coated with a catalytically active platinum bimetallic material. The shape of the nanoparticles is substantially defined by the particle shape of the core portion. The nanoparticles may be dispersed on a high surface area substrate for use as a catalyst and is characterized by no significant loss in surface area and specific activity following extended potential cycling.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1531735
Patent Number(s):
8178463
Application Number:
12/754,323
Assignee:
UChicago Argonne, LLC (Chicago, IL)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC02-06CH11357; W-31-109-ENG-38
Resource Type:
Patent
Resource Relation:
Patent File Date: 2010-04-05
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats

Stamenkovic, Vojislav, Markovic, Nenad M., Wang, Chao, Daimon, Hideo, and Sun, Shouheng. Highly durable nanoscale electrocatalyst based on core shell particles. United States: N. p., 2012. Web.
Stamenkovic, Vojislav, Markovic, Nenad M., Wang, Chao, Daimon, Hideo, & Sun, Shouheng. Highly durable nanoscale electrocatalyst based on core shell particles. United States.
Stamenkovic, Vojislav, Markovic, Nenad M., Wang, Chao, Daimon, Hideo, and Sun, Shouheng. Tue . "Highly durable nanoscale electrocatalyst based on core shell particles". United States. https://www.osti.gov/servlets/purl/1531735.
@article{osti_1531735,
title = {Highly durable nanoscale electrocatalyst based on core shell particles},
author = {Stamenkovic, Vojislav and Markovic, Nenad M. and Wang, Chao and Daimon, Hideo and Sun, Shouheng},
abstractNote = {A multimetallic nanoscale catalyst having a sore portion enveloped by a shell portion and exhibiting high catalytic activity and improved catalytic durability. In various embodiments, the core/shell nanoparticles comprise a gold particle coated with a catalytically active platinum bimetallic material. The shape of the nanoparticles is substantially defined by the particle shape of the core portion. The nanoparticles may be dispersed on a high surface area substrate for use as a catalyst and is characterized by no significant loss in surface area and specific activity following extended potential cycling.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 15 00:00:00 EDT 2012},
month = {Tue May 15 00:00:00 EDT 2012}
}

Works referenced in this record:

Gold-based alloy nanoparticles for use in fuel cell catalysts
patent, April 2007


Core-shell synthesis of carbon-supported alloy nanoparticle catalysts
patent, May 2006


Hydrogen storage material based on platelets and/or a multilayered core/shell structure
patent, October 2007


Catalyst material
patent, June 1998


Hydrogen storage material based on platelets and/or a multilayered core/shell structure
patent-application, April 2005


    Works referencing / citing this record:

    Multimetallic core/interlayer/shell nanoparticles
    patent, October 2018


    Fuel cell electrodes
    patent, June 2015


    Exhaust gas purification catalyst and production method thereof
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    Bimetallic catalyst
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    Supported bimetallic nanocomposite catalyst and the preparation method thereof
    patent, February 2016