Electrochemical device having electrolyte including disiloxane

West, Robert C.; Amine, Khalil; Zhang, Zhengcheng; Wang, Qingzheng; Rossi, Nicholas Agostino Antonio; Vissers, Donald R.

Title: Electrochemical device having electrolyte including disiloxane

Abstract

One example of the disiloxanes include a backbone with a first silicon and a second silicon. The first silicon is linked to a first substituent selected from a group consisting of: a first side chain that includes a cyclic carbonate moiety; a first side chain that includes a poly(alkylene oxide) moiety; and a first cross link links the disiloxane to a second siloxane and that includes a poly(alkylene oxide) moiety. In some instance, the second silicon is linked to a second substituent selected from a group consisting of: a second side chain that includes a cyclic carbonate moiety, and a second side chain that includes a poly(alkylene oxide) moiety.

Inventors:: West, Robert C.; Amine, Khalil; Zhang, Zhengcheng; Wang, Qingzheng; Rossi, Nicholas Agostino Antonio; Vissers, Donald R.

Issue Date:: Tue Dec 13 00:00:00 EST 2011

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1531705

Patent Number(s):: 8076031

Application Number:: 11/056,866

Assignee:: West, Robert C., Madison, WI (United States)

Patent Classifications (CPCs):: C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

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C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G77/14 - containing silicon bound to oxygen-containing groups {
C08G77/46 - containing polyether sequences

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M10/0567 - characterised by the additives
H01M10/0568 - characterised by the solutes
H01M10/0569 - characterised by the solvents
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: W-31-109-ENG-38

Resource Type:: Patent

Resource Relation:: Patent File Date: 2005-02-10

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    West, Robert C., Amine, Khalil, Zhang, Zhengcheng, Wang, Qingzheng, Rossi, Nicholas Agostino Antonio, and Vissers, Donald R. Electrochemical device having electrolyte including disiloxane.  United States: N. p., 2011. 
        Web.

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                    West, Robert C., Amine, Khalil, Zhang, Zhengcheng, Wang, Qingzheng, Rossi, Nicholas Agostino Antonio, & Vissers, Donald R. Electrochemical device having electrolyte including disiloxane.  United States.

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                    West, Robert C., Amine, Khalil, Zhang, Zhengcheng, Wang, Qingzheng, Rossi, Nicholas Agostino Antonio, and Vissers, Donald R. Tue .  
        "Electrochemical device having electrolyte including disiloxane".  United States.  https://www.osti.gov/servlets/purl/1531705.

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@article{osti_1531705,

  title        = {Electrochemical device having electrolyte including disiloxane},

  author       = {West, Robert C. and Amine, Khalil and Zhang, Zhengcheng and Wang, Qingzheng and Rossi, Nicholas Agostino Antonio and Vissers, Donald R.},

  abstractNote = {One example of the disiloxanes include a backbone with a first silicon and a second silicon. The first silicon is linked to a first substituent selected from a group consisting of: a first side chain that includes a cyclic carbonate moiety; a first side chain that includes a poly(alkylene oxide) moiety; and a first cross link links the disiloxane to a second siloxane and that includes a poly(alkylene oxide) moiety. In some instance, the second silicon is linked to a second substituent selected from a group consisting of: a second side chain that includes a cyclic carbonate moiety, and a second side chain that includes a poly(alkylene oxide) moiety.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Dec 13 00:00:00 EST 2011},

  month        = {Tue Dec 13 00:00:00 EST 2011}

}

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Polyphosphazene solid electrolytes
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Structures of Orthoborate Anions and Physical Properties of Their Lithium Salt Nonaqueous Solutions
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Xu, Wu; Shusterman, Alan J.; Videa, Marcelo
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Kohama, Shigemi; Umeki, Yoshihisa
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Convenient and Efficient Tosylation of Oligoethylene Glycols and the Related Alcohols in Tetrahydrofuran–Water in the Presence of Sodium Hydroxide
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Ouchi, Mikio; Inoue, Yoshihisa; Liu, Yu
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Asai, Hiroyuki; Matsuda, Yoshiharu; Nakamura, Takashi
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Non-aqueous electrolyte solvents for secondary cells
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Angell, Charles Austen; Xu, Kang; Kovalev, Igor P.
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Large lithium polymer battery development The immobile solvent concept
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Gauthier, M.; Bélanger, A.; Bouchard, P.
Journal of Power Sources, Vol. 54, Issue 1
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A Highly Conductive Solid-State Polymer Electrolyte Based on a Double-Comb Polysiloxane Polymer with Oligo(ethylene oxide) Side Chains
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Hooper, Richard; Lyons, Leslie J.; Moline, David A.
Organometallics, Vol. 18, Issue 17
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Solvent-free cation-conducting polysiloxane electrolytes with pendant oligo(oxyethylene) and sulfonate groups
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Zhou, Guang Bin; Khan, Ishrat M.; Smid, Johannes
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Amatucci, Glenn G.; DuPasquier, Aurelien L.; Tarascon, Jean-Marie
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Mukherjee, Shyama P.; Skotheim, Terje A.
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Works referencing / citing this record:

Fast cure gel polymer electrolytes
patent, July 2013

Amine, Khalil; Zhang, Zhengcheng
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Gelated ionic liquid film-coated surfaces and uses thereof
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Maschmeyer, Thomas; Easton, Max; Ward, Antony
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Electrolyte for lithium battery and lithium battery including the same
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Park, Insun; Kang, Yoonsok; Park, Minsik
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Organosilicon-containing electrolyte compositions having enhanced electrochemical and thermal stability
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Johnson, Tobias; Pollina, Michael; Zhou, Liu
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Organosilicon—containing electrolyte compositions having enhanced electrochemical and thermal stability
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Johnson, Tobias; Pollina, Michael; Zhou, Liu
US Patent Document 9,799,918
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Title: Electrochemical device having electrolyte including disiloxane

Abstract

Citation Formats

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Cross-linked polysiloxanes patent-application, October 2003

Cross-Linked Network Polymer Electrolytes Based on a Polysiloxane Backbone with Oligo(oxyethylene) Side Chains: Synthesis and Conductivity journal, December 2003

Ionic conductive polymer gel and lithium-ion battery using the same patent, January 2000

Synthesis and Ionic Conductivity of Cyclosiloxanes with Ethyleneoxy-Containing Substituents journal, November 2005

Chloride ion conductivity in a plasticized quaternary ammonium polymer journal, July 1984

Nonaqueous electrolytic solution and nonaqueous secondary battery patent-application, June 2002

Method of making electroactive high storage capacity polycarbon-sulfide materials and electrolytic cells containing same patent, November 1997

Preparation of ion conductive solid electrolyte patent, March 1990

Thermal stability of propylene carbonate and ethylene carbonate–propylene carbonate-based electrolytes for use in Li cells journal, July 2002

Solid electrolytes containing polysiloxane acrylates patent, May 1995

Overcharge protection systems for rechargeable batteries patent, March 1999

LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation journal, January 2002

Organosilyl and organosiloxanyl derivatives of glycerin ethers and their use patent, December 1995

Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions journal, January 2001

Solid polymer electrolytes based on cross-linked polysiloxane-g-oligo(ethylene oxide): ionic conductivity and electrochemical properties journal, June 2003

Stabilized anode for lithium-polymer batteries patent, October 1999

Cross-Linked Polyalkylene Oxide patent, May 1973

Lithium ion secondary battery patent, November 2003

Polymer electrolyte complexes of LiCIO4 and comb polymers of siloxane with oligo-oxyethylene side chains journal, January 1988

Gel polymer electrolyte of vinyl acetate patent, July 2001

Investigations of a siloxane-based polymer electrolyte employing carbon-13, silicon-29, lithium-7, and sodium-23 solid-state NMR spectroscopy journal, May 1988

Process to produce lithium-polymer batteries patent, June 1998

Acrylic alkoxy silane monomer and solid electrolyte derived by the polymerization thereof patent, April 1994

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Electrolyte materials containing highly dissociated metal ion salts patent, July 1996

Triblock copolymers and networks incorporating oligo (oxyethylene) chains journal, March 1993

Solid polymer electrolyte and method of preparation patent-application, September 2003

Organic carbonate additives for nonaqueous electrolyte in alkali metal electrochemical cells patent, May 1998

Organosilicon compounds containing (meth) acryloxy groups, their preparation and their use patent, January 1997

BATTERIES: The Battery: Not Yet a Terminal Case journal, May 2002

Method of manufacturing lithium secondary cell patent, August 2003

Solid polymer electrolyte of an organopolysiloxane crosslinked with polyalkylene oxide patent, May 1992

Modification of polymethylhydrosiloxane by dehydrocoupling reactions catalyzed by transition metal complexes: Evidence for the preservation of linear siloxane structures journal, May 2005

Overcharge protection systems for rechargeable batteries patent, June 2001

Poly(ethylene oxide) electrolytes for operation at near room temperature journal, January 1985

Nonflammable/self-extinguishing electrolytes for batteries patent, November 1998

Fabrication of electrodes and devices containing electrodes patent, January 2001

Conduction of lithium ions in polyvinylidene fluoride and its derivatives—I journal, May 1983

Synthesis, characterization, and electrical response of phosphazene polyelectrolytes journal, May 1989

Electrolyte containing a crosslinked compound having ether linkages and a high-molecular compound patent, June 2003

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Batteries containing single-ion conducting solid polymer electrolytes patent, May 1997

Rechargeable hybrid battery/supercapacitor system patent, June 2001

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Time resolved luminescence and vibrational spectroscopic studies on complexes of poly(ethylene oxide) oligomers and EuTFSI3 salt journal, December 1998

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journal, January 2002

Lithium secondary battery
patent-application, December 2002

Radiation cured solid electrolytes and electrochemical devices employing the same
patent, May 1989

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journal, February 2001

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journal, June 2005

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patent, March 1997

Electrolyte for rechargeable lithium battery and rechargeable lithium battery comprising same
patent-application, October 2004

Batteries, conductive compositions, and conductive films containing organic liquid electrolytes and plasticizers
patent, January 2000

In situ thermal polymerization method for making gel polymer lithium ion rechargeable electrochemical cells
patent-application, June 2003

Electrochemical cell having a pre-passivated electrode and associated fabrication process
patent, December 2002

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patent, September 2000

Complexes of alkali metal ions with poly(ethylene oxide)
journal, November 1973

Curable composition for polymer electrolyte
patent-application, May 2002

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journal, June 1999

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patent-application, May 2003

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patent, September 1970

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journal, June 1999

Highly Conductive PEO-like Polymer Electrolytes
journal, September 1997

Lithium battery
patent-application, March 2002

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journal, September 1985

Preparation of redox polymer cathodes for thin film rechargeable batteries
patent, November 1994

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patent-application, October 2003

Cross-Linked Network Polymer Electrolytes Based on a Polysiloxane Backbone with Oligo(oxyethylene) Side Chains: Synthesis and Conductivity
journal, December 2003

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patent, January 2000

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journal, November 2005

Chloride ion conductivity in a plasticized quaternary ammonium polymer
journal, July 1984

Nonaqueous electrolytic solution and nonaqueous secondary battery
patent-application, June 2002

Method of making electroactive high storage capacity polycarbon-sulfide materials and electrolytic cells containing same
patent, November 1997

Preparation of ion conductive solid electrolyte
patent, March 1990

Thermal stability of propylene carbonate and ethylene carbonate–propylene carbonate-based electrolytes for use in Li cells
journal, July 2002

Solid electrolytes containing polysiloxane acrylates
patent, May 1995

Overcharge protection systems for rechargeable batteries
patent, March 1999

LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation
journal, January 2002

Organosilyl and organosiloxanyl derivatives of glycerin ethers and their use
patent, December 1995

Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions
journal, January 2001

Solid polymer electrolytes based on cross-linked polysiloxane-g-oligo(ethylene oxide): ionic conductivity and electrochemical properties
journal, June 2003

Stabilized anode for lithium-polymer batteries
patent, October 1999

Cross-Linked Polyalkylene Oxide
patent, May 1973

Lithium ion secondary battery
patent, November 2003

Polymer electrolyte complexes of LiCIO4 and comb polymers of siloxane with oligo-oxyethylene side chains
journal, January 1988

Gel polymer electrolyte of vinyl acetate
patent, July 2001

Investigations of a siloxane-based polymer electrolyte employing carbon-13, silicon-29, lithium-7, and sodium-23 solid-state NMR spectroscopy
journal, May 1988

Process to produce lithium-polymer batteries
patent, June 1998

Acrylic alkoxy silane monomer and solid electrolyte derived by the polymerization thereof
patent, April 1994

Batteries, conductive compositions, and conductive films containing organic liquid electrolytes and plasticizers
patent, March 1998

Electrolyte materials containing highly dissociated metal ion salts
patent, July 1996

Triblock copolymers and networks incorporating oligo (oxyethylene) chains
journal, March 1993

Solid polymer electrolyte and method of preparation
patent-application, September 2003

Organic carbonate additives for nonaqueous electrolyte in alkali metal electrochemical cells
patent, May 1998

Organosilicon compounds containing (meth) acryloxy groups, their preparation and their use
patent, January 1997

BATTERIES: The Battery: Not Yet a Terminal Case
journal, May 2002

Method of manufacturing lithium secondary cell
patent, August 2003

Solid polymer electrolyte of an organopolysiloxane crosslinked with polyalkylene oxide
patent, May 1992

Modification of polymethylhydrosiloxane by dehydrocoupling reactions catalyzed by transition metal complexes: Evidence for the preservation of linear siloxane structures
journal, May 2005

Overcharge protection systems for rechargeable batteries
patent, June 2001

Poly(ethylene oxide) electrolytes for operation at near room temperature
journal, January 1985

Nonflammable/self-extinguishing electrolytes for batteries
patent, November 1998

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patent, January 2001

Conduction of lithium ions in polyvinylidene fluoride and its derivatives—I
journal, May 1983

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journal, May 1989

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patent, June 2003

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journal, July 1988

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patent, May 1997

Rechargeable hybrid battery/supercapacitor system
patent, June 2001

Polymer electrolytes
patent, September 2002

Nonaqueous liquid electrolyte
patent-application, September 2003

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patent, January 2002

Method of preparing aminofunctional alkoxy polysiloxanes
patent, November 2002

Hydrophilic contact lens made from polysiloxanes containing hydrophilic sidechains
patent, March 1981

Organosilanes and Organosiloxanes Containing Polyoxyalkylene
patent, March 1965

Time resolved luminescence and vibrational spectroscopic studies on complexes of poly(ethylene oxide) oligomers and EuTFSI3 salt
journal, December 1998

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journal, April 2001

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patent, August 1991

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journal, May 1988

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patent-application, February 2003

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journal, January 1992

Electronic package with improved heat sink
patent, July 1989

Gel electrolytes on the basis of oligo(ethylene glycol)n dimethacrylates—thermal, mechanical and electrochemical properties in relationship to the network structure
journal, May 2000

Polyphosphazenes Bearing Branched and Linear Oligoethyleneoxy Side Groups as Solid Solvents for Ionic Conduction
journal, January 1996

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patent, March 1999