Manganese oxide composite electrodes for lithium batteries
Abstract
An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula x{zLi2MnO3.(1−z)LiM′O2}.(1−x)LiMn2−yMyO4 for 0 < x < 1; 0 ≦ y ≦ 0.5; and 0 < z < 1, comprised of layered zLi2MnO3.(1−z)LiM′O2 and spinel LiMn2−yMyO4 components, physically mixed or blended with one another or separated from one another in a compartmentalized electrode, in which M is one or more metal ions, and in which M′ is selected from one or more first-row transition metal ions, The electrode is activated by removing lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1531649
- Patent Number(s):
- 7790308
- Application Number:
- 12/590,392
- Assignee:
- UChicago Argonne, LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- DOE Contract Number:
- AC02-06CH11357; W-31-109-ENG-38
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2009-11-05
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Johnson, Christopher S., Kang, Sun-Ho, and Thackeray, Michael M. Manganese oxide composite electrodes for lithium batteries. United States: N. p., 2010.
Web.
Johnson, Christopher S., Kang, Sun-Ho, & Thackeray, Michael M. Manganese oxide composite electrodes for lithium batteries. United States.
Johnson, Christopher S., Kang, Sun-Ho, and Thackeray, Michael M. Tue .
"Manganese oxide composite electrodes for lithium batteries". United States. https://www.osti.gov/servlets/purl/1531649.
@article{osti_1531649,
title = {Manganese oxide composite electrodes for lithium batteries},
author = {Johnson, Christopher S. and Kang, Sun-Ho and Thackeray, Michael M.},
abstractNote = {An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula x{zLi2MnO3.(1−z)LiM′O2}.(1−x)LiMn2−yMyO4 for 0 < x < 1; 0 ≦ y ≦ 0.5; and 0 < z < 1, comprised of layered zLi2MnO3.(1−z)LiM′O2 and spinel LiMn2−yMyO4 components, physically mixed or blended with one another or separated from one another in a compartmentalized electrode, in which M is one or more metal ions, and in which M′ is selected from one or more first-row transition metal ions, The electrode is activated by removing lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2010},
month = {9}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Lithium metal oxide electrodes for lithium cells and batteries
patent, January 2004
- Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil
- US Patent Document 6,680,143
Lithium manganese oxide compound
patent, October 1992
- Thackeray, Michael M.; Rossouw, Margaretha H.
- US Patent Document 5,153,081
Works referencing / citing this record:
Cathode material and battery
patent, July 2016
- Liu, Jun; Roelofs, Mark Gerrit
- US Patent Document 9,391,322
Fluorinated electrolyte compositions
patent, May 2018
- Holstein, William L.; Chen, Xudong; Liu, Jun
- US Patent Document 9,979,050
Particle, electrode, power storage device, electronic device, and method for manufacturing electrode
patent, September 2018
- Kawakami, Takahiro; Ochiai, Teruaki; Yoshitomi, Shuhei
- US Patent Document 10,084,186
Lithium manganese oxide composite, secondary battery, and manufacturing method thereof
patent, May 2017
- Kawakami, Takahiro; Yoshitomi, Shuhei; Ochiai, Teruaki
- US Patent Document 9,666,326
Lithium—manganese composite oxide, secondary battery, and electric device
patent, March 2016
- Kawakami, Takahiro; Yoshitomi, Shuhei; Ochiai, Teruaki
- US Patent Document 9,293,236
Fluorinated electrolyte compositions
patent, August 2018
- Dubois, Charles J.; Kodokian, George K.; Nyland, Barbara S.
- US Patent Document 10,044,066
Cobalt-stabilized lithium metal oxide electrodes for lithium batteries
patent, September 2018
- Thackeray, Michael M.; Croy, Jason R.; Long, Brandon R.
- US Patent Document 10,069,143
Manganese oxide composite electrodes for lithium batteries
patent, December 2011
- Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S.
- US Patent Document 8,080,340
Composite positive electrode active material positive electrode including the same, and lithium battery including the positive electrode
patent, August 2018
- Choi, Byungjin; Kang, Yoonsok; Park, Junho
- US Patent Document 10,044,030
Additives to improve electrolyte performance in lithium ion batteries
patent, September 2018
- Dubois, Charles J.; Petrov, Viacheslav A.; Roelofs, Mark Gerrit
- US Patent Document 10,074,874
Lithium ion battery
patent, June 2017
- Chen, Xudong; Liu, Jun; Roelofs, Mark Gerrit
- US Patent Document 9,673,450
Lithium manganese composite oxide, secondary battery, and electrical device
patent, January 2018
- Kawakami, Takahiro; Ikenuma, Tatsuya; Seo, Satoshi
- US Patent Document 9,865,867