Stepped gradient fuel electrode and method for making the same
Abstract
The present invention provides for a method of depositing a stepped-gradient fuel electrode onto a fuel cell support 2 and the resulting fuel cell, that comprises placing a solid oxide fuel cell support that has at least an air electrode layer 4 and an electrolyte layer 6 into an atmospheric plasma spraying chamber and measuring spray parameters of an atmospheric plasma spray to obtain reactive oxides, conductive metal and graphite phases. Then spraying the spray parameters onto the solid oxide fuel cell support to produce multiple sub-layers 8 on the solid oxide fuel cell support, and adjusting a hydrogen usage of the atmospheric plasma spray. The adjusting of the hydrogen usage comprises using high hydrogen levels for the initial spraying of the sub-layers producing a first gradient region, and a lower hydrogen level for subsequent spraying of the sub-layers, producing a second gradient region.
- Inventors:
- Issue Date:
- Research Org.:
- Siemens Energy, Inc., Orlando, FL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1531618
- Patent Number(s):
- 7637967
- Application Number:
- 11/298,321
- Assignee:
- Siemens Energy, Inc. (Orlando, FL)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- FC26-97FT34139
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2005-12-08
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Huang, Keqin, Harter, Harold D., and Turkal, Paul G. Stepped gradient fuel electrode and method for making the same. United States: N. p., 2009.
Web.
Huang, Keqin, Harter, Harold D., & Turkal, Paul G. Stepped gradient fuel electrode and method for making the same. United States.
Huang, Keqin, Harter, Harold D., and Turkal, Paul G. Tue .
"Stepped gradient fuel electrode and method for making the same". United States. https://www.osti.gov/servlets/purl/1531618.
@article{osti_1531618,
title = {Stepped gradient fuel electrode and method for making the same},
author = {Huang, Keqin and Harter, Harold D. and Turkal, Paul G.},
abstractNote = {The present invention provides for a method of depositing a stepped-gradient fuel electrode onto a fuel cell support 2 and the resulting fuel cell, that comprises placing a solid oxide fuel cell support that has at least an air electrode layer 4 and an electrolyte layer 6 into an atmospheric plasma spraying chamber and measuring spray parameters of an atmospheric plasma spray to obtain reactive oxides, conductive metal and graphite phases. Then spraying the spray parameters onto the solid oxide fuel cell support to produce multiple sub-layers 8 on the solid oxide fuel cell support, and adjusting a hydrogen usage of the atmospheric plasma spray. The adjusting of the hydrogen usage comprises using high hydrogen levels for the initial spraying of the sub-layers producing a first gradient region, and a lower hydrogen level for subsequent spraying of the sub-layers, producing a second gradient region.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2009},
month = {12}
}
Works referenced in this record:
Carrier substrate for an electrode layer of a fuel cell and method for the production thereof
patent-application, September 2005
- Hoefler, Thomas
- US Patent Application 11/134274; 20050208367
Method for manufacturing fuel cells, and articles made therewith
patent-application, December 2003
- Browall, Kenneth Walter; Wei, Chang
- US Patent Application 10/063939; 20030224232
Solid oxide fuel cell components and method of manufacture thereof
patent-application, January 2004
- Hui, Shiqiang; Ma, Xinqing; Zhang, Heng
- US Patent Application 10/377253; 20040018409
A study of Ni + 8YSZ/8YSZ/LaSrCoO ITSOFC fabricated by atmospheric plasma spraying
journal, February 2005
- Zheng, R.; Zhou, X.; Wang, S.
- Journal of Power Sources, Vol. 140, Issue 2
Multi-stage fuel cell arrangement
patent, January 1998
- Khandkar, Ashok C.; Elangovan, Singaravelu
- US Patent Document 5,712,055
Sealing structure for a fuel cell, as well as a method for producing it, and a fuel cell with the sealing structure
patent-application, October 2004
- Finkenwirth, Olav; Zerfass, Hans-Rainer
- US Patent Application 10/761124; 20040209147
Standard package design for both atmospheric and pressurized SOFC power generation system
patent, July 2004
- Gillett, James E.; Zafred, Paolo R.
- US Patent Document 6,764,784
Fuel cell
patent-application, October 2004
- Yoshikata, Kuniaki; Sakamoto, Hirotoshi; Mikami, Koichi
- US Patent Application 10/730013; 20040197628
High power density solid oxide fuel cell having a graded anode
patent, May 2001
- Kim, Jai-Woh; Fung, Kuan-Zong; Virkar, Anil V.
- US Patent Document 6,228,521
Low-cost atmospheric SOFC power generation system
patent, December 2003
- Holmes, Randall A.; Zafred, Paolo R.; Gillett, James E.
- US Patent Document 6,656,623
Method for operating a fuel cell assembly
patent, December 1998
- Chen, Tan-Ping
- US Patent Document 5,851,689
Method for modifying the surface of a thermal barrier coating by plasma-heating
patent, August 2000
- Gray, Dennis Michael; Hasz, Wayne Charles; Bethel, Timothy Francis
- US Patent Document 6,103,315