Title: Catalyst and sorbent material for the production of hydrogen

Abstract

A catalyst and sorbent is disclosed which comprises pellets with an absorbent core and a protective shell with a catalyst in the shell. Such material is especially well suited for steam reforming of hydrocarbons to produce hydrogen since a reforming catalyst can be incorporated in the shell and a sorbent for the by-product carbon dioxide can be used for the core. It is also well suited for producing hydrogen from carbon monoxide by means of the water gas shift reaction. The shell can be made sufficiently strong and durable for moving bed applications as well as fixed bed applications.

Inventors:

Wheelock, Thomas D.; Shanks, Brent H.

Issue Date:

2007-02-13

Research Org.:

Iowa State Univ., Ames, IA (United States)

Sponsoring Org.:

USDOE

OSTI Identifier:

1531523

Patent Number(s):

7176159

Application Number:

10/218,803

Assignee:

Iowa State University Research Foundation, Inc. (Ames, IA)

Patent Classifications (CPCs):

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C01B3/56 - by contacting with solids
C01B2203/1241 - Natural gas or methane

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

B01J20/28014 - {characterised by their form}
B01J2220/4887 - Residues, wastes, e.g. garbage, municipal or industrial sludges, compost, animal manure
B01J37/16 - Reducing
B01J37/0205 - {in several steps}
B01J35/008 - {egg-shell like}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C01B2203/0283 - containing a CO-shift step, i.e. a water gas shift step
C01B3/16 - using catalysts

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

B01J20/3293 - {Coatings on a core, the core being particle or fiber shaped, e.g. encapsulated particles, coated fibers}
B01J20/041 - {Oxides or hydroxides}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C01B3/38 - using catalysts

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

B01J20/08 - comprising aluminium oxide or hydroxide
B01J23/78 - with alkali- or alkaline earth metals

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C01B2203/0233 - the reforming step being a steam reforming step

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

B01J20/3078 - {Thermal treatment, e.g. calcining or pyrolizing}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

Y02P20/52 - using catalysts, e.g. selective catalysts

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C01B2203/0475 - the impurity being carbon dioxide

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

B01J20/3204 - {Inorganic carriers, supports or substrates}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C01B2203/0425 - In-situ adsorption process during hydrogen production

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

B01J37/0203 - {the impregnation liquid containing organic compounds}

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DOE Contract Number:  

FG26-02NT41549

Resource Type:

Patent

Resource Relation:

Patent File Date: 2002-08-14

Country of Publication:

United States

Language:

English

Subject:

36 MATERIALS SCIENCE; 08 HYDROGEN; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY