Low-temperature hydrogen production from oxygenated hydrocarbons

Cortright, Randy D.; Dumesic, James A.

Title: Low-temperature hydrogen production from oxygenated hydrocarbons

Abstract

Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIII transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.

Inventors:: Cortright, Randy D.; Dumesic, James A.

Issue Date:: 2005-11-15

Research Org.:: Wisconsin Alumni Research Foundation, Madison, WI (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1531497

Patent Number(s):: 6964758

Application Number:: 10/632,245

Assignee:: Wisconsin Alumni Research Foundation (Madison, WI)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/0233 - the reforming step being a steam reforming step
C01B2203/0277 - containing a catalytic decomposition step
C01B2203/0283 - containing a CO-shift step, i.e. a water gas shift step
C01B2203/0405 - Purification by membrane separation
C01B2203/0475 - the impurity being carbon dioxide
C01B2203/0495 - the impurity being water
C01B2203/1047 - Group VIII metal catalysts
C01B2203/1064 - Platinum group metal catalysts
C01B2203/107 - Platinum catalysts
C01B2203/1082 - Composition of support materials
C01B2203/1211 - Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
C01B3/22 - by decomposition of gaseous or liquid organic compounds
C01B3/326 - {characterised by the catalyst}
C01B3/501 - {by diffusion}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/52 - using catalysts, e.g. selective catalysts

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DOE Contract Number:: FG02-84ER13183

Resource Type:: Patent

Resource Relation:: Patent File Date: 2003-08-01

Country of Publication:: United States

Language:: English

Citation Formats


                    Cortright, Randy D., and Dumesic, James A. Low-temperature hydrogen production from oxygenated hydrocarbons.  United States: N. p., 2005. 
        Web.

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                    Cortright, Randy D., & Dumesic, James A. Low-temperature hydrogen production from oxygenated hydrocarbons.  United States.

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                    Cortright, Randy D., and Dumesic, James A. Tue .  
        "Low-temperature hydrogen production from oxygenated hydrocarbons".  United States.  https://www.osti.gov/servlets/purl/1531497.

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@article{osti_1531497,

  title        = {Low-temperature hydrogen production from oxygenated hydrocarbons},

  author       = {Cortright, Randy D. and Dumesic, James A.},

  abstractNote = {Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIII transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2005},

  month        = {11}

}

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Full Text Available
Low-temperature hydrogen production from oxygenated hydrocarbons

Patent Cortright, Randy D.; Dumesic, James A.

Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIII transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.
Full Text Available
Low-temperature hydrocarbon production from oxygenated hydrocarbons

Patent Cortright, Randy D.; Dumesic, James A.

Disclosed is a method of producing hydrocarbons from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase (preferably in the condensed liquid phase). The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. These metals are supported on supports that exhibit acidity or the reaction is conducted under liquid-phasemore » « less
Full Text Available
Method for low temperature catalytic production of hydrogen

Patent Mahajan, Devinder

The invention provides a process for the catalytic production of a hydrogen feed by exposing a hydrogen feed to a catalyst which promotes a base-catalyzed water-gas-shift reaction in a liquid phase. The hydrogen feed can be provided by any process known in the art of making hydrogen gas. It is preferably provided by a process that can produce a hydrogen feed for use in proton exchange membrane fuel cells. The step of exposing the hydrogen feed takes place preferably from about 80.degree. C. to about 150.degree. C.
Full Text Available
Method of carbon dioxide-free hydrogen production from hydrocarbon decomposition over metal salts

Patent Erlebacher, Jonah; Gaskey, Bernard

A process to decompose methane into carbon (graphitic powder) and hydrogen (H.sub.2 gas) without secondary production of carbon dioxide, employing a cycle in which a secondary chemical is recycled and reused, is disclosed.
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Title: Low-temperature hydrogen production from oxygenated hydrocarbons

Abstract

Citation Formats

Method for the catalytic conversion of organic materials into a product gas patent, April 1997

Steam reformer with internal hydrogen purification patent, January 1999

Conversion of hydrocarbons and alcohols for fuel cells journal, January 2001

Method of producing hydrogen from biomass patent, July 1997

Method for the treatment of a methanol reforming catalyst patent, August 2001

Hydrogen generation by steam reforming of methanol over copper-based catalysts for fuel cell applications journal, September 2001

Method for catalytic destruction of organic materials patent, May 1997

Catalyst for manufacturing hydrogen or synthesis gas and manufacturing method of hydrogen or synthesis gas patent, March 2002

Production of hydrogen from carbon monoxide and water patent, September 1980

Hydrogen Production from Wet Cellulose by Low Temperature Gasification Using a Reduced Nickel Catalyst journal, October 1995

Process for reforming hydrocarbon patent, June 2004

Conversion of carbohydrates patent, October 1985

Carbon-Halogen Bond Scission and Rearrangement of .beta.-Halohydrins on the Rh(111) Surface journal, December 1994

Conversion of biological material to liquid fuels patent, November 1981

Production of Hydrogen and Hydrocarbon from Cellulose and Water journal, August 1981

System for hydrogen generation through steam reforming of hydrocarbons and integrated chemical reactor for hydrogen production from hydrocarbons patent, September 2003

Process for producing hydrocarbon fuels patent, May 1996

Process and preparation of hydrogen-rich gas patent, May 2000

Catalytic steam reforming of biomass-derived oxygenates: acetic acid and hydroxyacetaldehyde journal, August 1996

Process for converting carbohydrates to hydrocarbons patent, March 1985

Hydrogen producing fuel processing system patent, April 2001

Production of hydrogen from hydrocarbons and oxygenated hydrocarbons patent, August 2003

Ruthenium on rutile catalyst, catalytic system, and method for aqueous phase hydrogenations patent, May 2001

Two stage process for improving the catalyst life of zeolites in the synthesis of lower olefins from alcohols and their ether derivatives patent, November 1985

Treatment process for a methanol reforming catalyst therefor patent, January 2001

Process for the production of hydrogen and electrical energy from reforming of bio-ethanol with the use of fuel cells and with zero emission of pollutants patent, May 2002

Method for the catalytic conversion of lignocellulosic materials patent, May 1991

Process for producing high purity hydrogen patent, March 2001

Selective Hydrogen Production from Cellulose at Low Temperature Catalyzed by Supported Group 10 Metal journal, October 2000

Nickel/ruthenium catalyst and method for aqueous phase reactions patent, September 1998

Hydrogen Production from Cellulose in Hot Compressed Water Using Reduced Nickel Catalyst: Product Distribution at Different Reaction Temperatures. journal, January 1998

Method of using catalyst for steam reforming of alcohols patent, July 2002

Methods and systems for generating polyols patent, August 2010

Photo-electro-refining of bio-oil to biofuel and hydrogen patent, January 2012

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons patent, December 2015

Sugar mixtures and methods for production and use thereof patent, August 2016

Methods for treating lignocellulosic materials patent, May 2017

Method and device for hydrogen storage and delivery patent, June 2013

Nanocomposite particle and process of preparing the same patent, December 2011

Direct aqueous phase reforming and aldol condensation to form bio-based fuels patent, August 2016

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons patent, January 2015

Biofuels via hydrogenolysis-condensation patent, September 2016

Direct aqueous phase reforming of bio-based feedstocks patent, September 2016

Methods and systems for processing sugar mixtures and resultant compositions patent, May 2017

Biofuels via hydrogenolysis-condensation patent, November 2016

Methods for treating lignocellulosic materials patent, October 2017

Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils patent, June 2014

Process for producing a biofuel while minimizing fossil fuel derived carbon dioxide emissions patent, July 2014

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons patent, June 2013

Liquid fuel compositions patent, June 2013

Process for hydrogen gas production from carbohydrate feedstocks patent, August 2011

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons patent, September 2011

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons patent, February 2013

Sugar mixtures and methods for production and use thereof patent, May 2018

Liquid fuel compositions patent, September 2012

Production of hydrogen from non-cyclic organic substances having multiple alcohol functionality patent, February 2009

Methods and systems for generating polyols patent, August 2011

Process for producing a renewable hydrocarbon fuel patent, October 2014

Catalysts and methods for reforming oxygenated compounds patent, July 2012

Efficient production of fuels patent, September 2014

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons patent, January 2013

Base-facilitated reformation reactions of organic substances patent, January 2009

Methods and systems for processing a sucrose crop and sugar mixtures patent, October 2016

Methods and systems for generating polyols patent, June 2014

Biofuels via hydrogenolysis and dehydrogenation-condensation patent, July 2016

Methods and systems for generating polyols patent, June 2012

Production of aromatics from di- and polyoxygenates patent, September 2016

Methods for treating lignocellulosic materials patent, November 2016

Liquid fuel compositions patent, December 2015

Production of aromatics from di- and polyoxygenates patent, August 2016

Method of producing gaseous products using a downflow reactor patent, September 2014

Efficient production of hydrogen patent, April 2013

Direct aqueous phase reforming of bio-based feedstocks patent, April 2016

Method for hydrogen storage and delivery patent, March 2007

Production of hydrogen from oxygenated hydrocarbons patent, March 2014

Synthesis of liquid fuels from biomass patent, January 2013

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons patent, July 2011

Method for the catalytic conversion of organic materials into a product gas
patent, April 1997

Steam reformer with internal hydrogen purification
patent, January 1999

Conversion of hydrocarbons and alcohols for fuel cells
journal, January 2001

Method of producing hydrogen from biomass
patent, July 1997

Method for the treatment of a methanol reforming catalyst
patent, August 2001

Hydrogen generation by steam reforming of methanol over copper-based catalysts for fuel cell applications
journal, September 2001

Method for catalytic destruction of organic materials
patent, May 1997

Catalyst for manufacturing hydrogen or synthesis gas and manufacturing method of hydrogen or synthesis gas
patent, March 2002

Production of hydrogen from carbon monoxide and water
patent, September 1980

Hydrogen Production from Wet Cellulose by Low Temperature Gasification Using a Reduced Nickel Catalyst
journal, October 1995

Process for reforming hydrocarbon
patent, June 2004

Conversion of carbohydrates
patent, October 1985

Carbon-Halogen Bond Scission and Rearrangement of .beta.-Halohydrins on the Rh(111) Surface
journal, December 1994

Conversion of biological material to liquid fuels
patent, November 1981

Production of Hydrogen and Hydrocarbon from Cellulose and Water
journal, August 1981

System for hydrogen generation through steam reforming of hydrocarbons and integrated chemical reactor for hydrogen production from hydrocarbons
patent, September 2003

Process for producing hydrocarbon fuels
patent, May 1996

Process and preparation of hydrogen-rich gas
patent, May 2000

Catalytic steam reforming of biomass-derived oxygenates: acetic acid and hydroxyacetaldehyde
journal, August 1996

Process for converting carbohydrates to hydrocarbons
patent, March 1985

Hydrogen producing fuel processing system
patent, April 2001

Production of hydrogen from hydrocarbons and oxygenated hydrocarbons
patent, August 2003

Ruthenium on rutile catalyst, catalytic system, and method for aqueous phase hydrogenations
patent, May 2001

Two stage process for improving the catalyst life of zeolites in the synthesis of lower olefins from alcohols and their ether derivatives
patent, November 1985

Treatment process for a methanol reforming catalyst therefor
patent, January 2001

Process for the production of hydrogen and electrical energy from reforming of bio-ethanol with the use of fuel cells and with zero emission of pollutants
patent, May 2002

Method for the catalytic conversion of lignocellulosic materials
patent, May 1991

Process for producing high purity hydrogen
patent, March 2001

Selective Hydrogen Production from Cellulose at Low Temperature Catalyzed by Supported Group 10 Metal
journal, October 2000

Nickel/ruthenium catalyst and method for aqueous phase reactions
patent, September 1998

Hydrogen Production from Cellulose in Hot Compressed Water Using Reduced Nickel Catalyst: Product Distribution at Different Reaction Temperatures.
journal, January 1998

Method of using catalyst for steam reforming of alcohols
patent, July 2002

Methods and systems for generating polyols
patent, August 2010

Photo-electro-refining of bio-oil to biofuel and hydrogen
patent, January 2012

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
patent, December 2015

Sugar mixtures and methods for production and use thereof
patent, August 2016

Methods for treating lignocellulosic materials
patent, May 2017

Method and device for hydrogen storage and delivery
patent, June 2013

Nanocomposite particle and process of preparing the same
patent, December 2011

Direct aqueous phase reforming and aldol condensation to form bio-based fuels
patent, August 2016

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
patent, January 2015

Biofuels via hydrogenolysis-condensation
patent, September 2016

Direct aqueous phase reforming of bio-based feedstocks
patent, September 2016

Methods and systems for processing sugar mixtures and resultant compositions
patent, May 2017

Biofuels via hydrogenolysis-condensation
patent, November 2016

Methods for treating lignocellulosic materials
patent, October 2017

Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils
patent, June 2014

Process for producing a biofuel while minimizing fossil fuel derived carbon dioxide emissions
patent, July 2014

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
patent, June 2013

Liquid fuel compositions
patent, June 2013

Process for hydrogen gas production from carbohydrate feedstocks
patent, August 2011

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
patent, September 2011

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
patent, February 2013

Sugar mixtures and methods for production and use thereof
patent, May 2018

Liquid fuel compositions
patent, September 2012

Production of hydrogen from non-cyclic organic substances having multiple alcohol functionality
patent, February 2009

Methods and systems for generating polyols
patent, August 2011

Process for producing a renewable hydrocarbon fuel
patent, October 2014

Catalysts and methods for reforming oxygenated compounds
patent, July 2012

Efficient production of fuels
patent, September 2014

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
patent, January 2013

Base-facilitated reformation reactions of organic substances
patent, January 2009

Methods and systems for processing a sucrose crop and sugar mixtures
patent, October 2016

Methods and systems for generating polyols
patent, June 2014

Biofuels via hydrogenolysis and dehydrogenation-condensation
patent, July 2016

Methods and systems for generating polyols
patent, June 2012

Production of aromatics from di- and polyoxygenates
patent, September 2016

Methods for treating lignocellulosic materials
patent, November 2016

Liquid fuel compositions
patent, December 2015

Production of aromatics from di- and polyoxygenates
patent, August 2016

Method of producing gaseous products using a downflow reactor
patent, September 2014

Efficient production of hydrogen
patent, April 2013

Direct aqueous phase reforming of bio-based feedstocks
patent, April 2016

Method for hydrogen storage and delivery
patent, March 2007

Production of hydrogen from oxygenated hydrocarbons
patent, March 2014

Synthesis of liquid fuels from biomass
patent, January 2013

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
patent, July 2011

Catalyst for aqueous phase reforming of biomass-derived polyols and preparation method thereof
patent, August 2015

Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
patent, November 2011

Hydrogen production from biomass
patent, July 2011