Low-temperature hydrogen production from oxygenated hydrocarbons
Abstract
Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIII transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.
- Inventors:
- Issue Date:
- Research Org.:
- Wisconsin Alumni Research Foundation, Madison, WI (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1531497
- Patent Number(s):
- 6964758
- Application Number:
- 10/632,245
- Assignee:
- Wisconsin Alumni Research Foundation (Madison, WI)
- Patent Classifications (CPCs):
-
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- FG02-84ER13183
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2003-08-01
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Cortright, Randy D., and Dumesic, James A. Low-temperature hydrogen production from oxygenated hydrocarbons. United States: N. p., 2005.
Web.
Cortright, Randy D., & Dumesic, James A. Low-temperature hydrogen production from oxygenated hydrocarbons. United States.
Cortright, Randy D., and Dumesic, James A. Tue .
"Low-temperature hydrogen production from oxygenated hydrocarbons". United States. https://www.osti.gov/servlets/purl/1531497.
@article{osti_1531497,
title = {Low-temperature hydrogen production from oxygenated hydrocarbons},
author = {Cortright, Randy D. and Dumesic, James A.},
abstractNote = {Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIII transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2005},
month = {11}
}
Works referenced in this record:
Conversion of hydrocarbons and alcohols for fuel cells
journal, January 2001
- Rostrup-Nielsen, Jens R.
- Physical Chemistry Chemical Physics, Vol. 3, Issue 3
Hydrogen generation by steam reforming of methanol over copper-based catalysts for fuel cell applications
journal, September 2001
- Lindström, B.
- International Journal of Hydrogen Energy, Vol. 26, Issue 9
Hydrogen Production from Wet Cellulose by Low Temperature Gasification Using a Reduced Nickel Catalyst
journal, October 1995
- Minowa, Tomoaki; Ogi, Tomoko; Yokoyama, Shin-ya
- Chemistry Letters, Vol. 24, Issue 10
Carbon-Halogen Bond Scission and Rearrangement of .beta.-Halohydrins on the Rh(111) Surface
journal, December 1994
- Brown, Nicole F.; Barteau, Mark A.
- The Journal of Physical Chemistry, Vol. 98, Issue 48
Production of Hydrogen and Hydrocarbon from Cellulose and Water
journal, August 1981
- Kawai, Maki; Kawai, Tomoji; Tamaru, Kenzi
- Chemistry Letters, Vol. 10, Issue 8
Catalytic steam reforming of biomass-derived oxygenates: acetic acid and hydroxyacetaldehyde
journal, August 1996
- Wang, D.; Montané, D.; Chornet, E.
- Applied Catalysis A: General, Vol. 143, Issue 2, p. 245-270
Selective Hydrogen Production from Cellulose at Low Temperature Catalyzed by Supported Group 10 Metal
journal, October 2000
- Usui, Yoko; Minowa, Tomoaki; Inoue, Seiichi
- Chemistry Letters, Vol. 29, Issue 10
Hydrogen Production from Cellulose in Hot Compressed Water Using Reduced Nickel Catalyst: Product Distribution at Different Reaction Temperatures.
journal, January 1998
- Minowa, Tomoaki; Fang, Zhen
- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 31, Issue 3