Low-temperature hydrocarbon production from oxygenated hydrocarbons
Abstract
Disclosed is a method of producing hydrocarbons from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase (preferably in the condensed liquid phase). The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. These metals are supported on supports that exhibit acidity or the reaction is conducted under liquid-phase conditions at acidic pHs. The disclosed method allows the production of hydrocarbon by the liquid-phase reaction of water with biomass-derived oxygenated compounds.
- Inventors:
- Issue Date:
- Research Org.:
- Wisconsin Alumni Research Foundation, Madison, WI (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1531496
- Patent Number(s):
- 6953873
- Application Number:
- 10/435,208
- Assignee:
- Wisconsin Alumni Research Foundation (Madison, WI)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
- DOE Contract Number:
- FG02-84ER13183
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2003-05-09
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 08 HYDROGEN; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 09 BIOMASS FUELS
Citation Formats
Cortright, Randy D., and Dumesic, James A. Low-temperature hydrocarbon production from oxygenated hydrocarbons. United States: N. p., 2005.
Web.
Cortright, Randy D., & Dumesic, James A. Low-temperature hydrocarbon production from oxygenated hydrocarbons. United States.
Cortright, Randy D., and Dumesic, James A. Tue .
"Low-temperature hydrocarbon production from oxygenated hydrocarbons". United States. https://www.osti.gov/servlets/purl/1531496.
@article{osti_1531496,
title = {Low-temperature hydrocarbon production from oxygenated hydrocarbons},
author = {Cortright, Randy D. and Dumesic, James A.},
abstractNote = {Disclosed is a method of producing hydrocarbons from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase (preferably in the condensed liquid phase). The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. These metals are supported on supports that exhibit acidity or the reaction is conducted under liquid-phase conditions at acidic pHs. The disclosed method allows the production of hydrocarbon by the liquid-phase reaction of water with biomass-derived oxygenated compounds.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2005},
month = {10}
}
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