Production of 1,5-pentanediol via upgrading of tetrahydrofufuryl alcohol
Abstract
A method of making 1,5-pentanediol from tetrahydrofurfural alcohol. The method includes the steps of dehydrating tetrahydrofurfural alcohol (THFA) to dihydropyran (DHP); hydrating at least a portion of the DHP to 2-hydroxy-tetrahydropyran (2-HY-THP) in the absence of homogeneous acid; and hydrogenating at least a portion of the 2-HY-THP to 1,5-pentanediol. The method can be conducted entirely in the absence of noble metal catalysts.
- Inventors:
- Issue Date:
- Research Org.:
- Wisconsin Alumni Research Foundation, Madison, WI (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1498705
- Patent Number(s):
- 10183904
- Application Number:
- 15/004,091
- Assignee:
- Wisconsin Alumni Research Foundation (Madison, WI)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- EE0006878
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2016 Jan 22
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Huber, George Willis, Dumesic, James A., Barnett, Kevin J., and Brentzel, Zach J. Production of 1,5-pentanediol via upgrading of tetrahydrofufuryl alcohol. United States: N. p., 2019.
Web.
Huber, George Willis, Dumesic, James A., Barnett, Kevin J., & Brentzel, Zach J. Production of 1,5-pentanediol via upgrading of tetrahydrofufuryl alcohol. United States.
Huber, George Willis, Dumesic, James A., Barnett, Kevin J., and Brentzel, Zach J. Tue .
"Production of 1,5-pentanediol via upgrading of tetrahydrofufuryl alcohol". United States. https://www.osti.gov/servlets/purl/1498705.
@article{osti_1498705,
title = {Production of 1,5-pentanediol via upgrading of tetrahydrofufuryl alcohol},
author = {Huber, George Willis and Dumesic, James A. and Barnett, Kevin J. and Brentzel, Zach J.},
abstractNote = {A method of making 1,5-pentanediol from tetrahydrofurfural alcohol. The method includes the steps of dehydrating tetrahydrofurfural alcohol (THFA) to dihydropyran (DHP); hydrating at least a portion of the DHP to 2-hydroxy-tetrahydropyran (2-HY-THP) in the absence of homogeneous acid; and hydrogenating at least a portion of the 2-HY-THP to 1,5-pentanediol. The method can be conducted entirely in the absence of noble metal catalysts.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}
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Works referenced in this record:
Preparation of Dihydropyran, δ-Hydroxyvaleraldehyde and 1,5-Pentanediol from Tetrahydrofurfuryl Alcohol
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Reaction of Allenic Hydrocarbon with Formaldehyde Under Non-Acidic Conditions to Produce an Unsaturated Alcohol
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