skip to main content
DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Process for making carbon-based nano-rods from switchable ionic liquids and devices and processes incorporating same

Abstract

A method of making carbon-based nano-rods from switchable ionic liquids (SWIL) that incorporates the SWIL is disclosed. Resulting nano-rods provide adsorption and spontaneous desorption of water at selected relative humidity values that find use in selected applications and devices.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1496813
Patent Number(s):
10,179,320
Application Number:
15/078,807
Assignee:
BATTELLE MEMORIAL INSTITUTE (Richland, WA)
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Mar 23
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING

Citation Formats

Nune, Satish K., Heldebrant, David J., Lao, David B., Liu, Jian, and Whyatt, Greg A. Process for making carbon-based nano-rods from switchable ionic liquids and devices and processes incorporating same. United States: N. p., 2019. Web.
Nune, Satish K., Heldebrant, David J., Lao, David B., Liu, Jian, & Whyatt, Greg A. Process for making carbon-based nano-rods from switchable ionic liquids and devices and processes incorporating same. United States.
Nune, Satish K., Heldebrant, David J., Lao, David B., Liu, Jian, and Whyatt, Greg A. Tue . "Process for making carbon-based nano-rods from switchable ionic liquids and devices and processes incorporating same". United States. https://www.osti.gov/servlets/purl/1496813.
@article{osti_1496813,
title = {Process for making carbon-based nano-rods from switchable ionic liquids and devices and processes incorporating same},
author = {Nune, Satish K. and Heldebrant, David J. and Lao, David B. and Liu, Jian and Whyatt, Greg A.},
abstractNote = {A method of making carbon-based nano-rods from switchable ionic liquids (SWIL) that incorporates the SWIL is disclosed. Resulting nano-rods provide adsorption and spontaneous desorption of water at selected relative humidity values that find use in selected applications and devices.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}

Patent:

Save / Share:

Works referenced in this record:

Pertechnetate (TcO4−) reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Hanford Site, USA
journal, September 2012

  • Peretyazhko, T. S.; Zachara, J. M.; Kukkadapu, R. K.
  • Geochimica et Cosmochimica Acta, Vol. 92
  • DOI: 10.1016/j.gca.2012.05.041

Phase Transitions of Single Salt Particles Studied Using a Transmission Electron Microscope with an Environmental Cell
journal, September 2005

  • Wise, Matthew E.; Biskos, George; Martin, Scot T.
  • Aerosol Science and Technology, Vol. 39, Issue 9
  • DOI: 10.1080/02786820500295263

Review of the vapour pressures of ice and supercooled water for atmospheric applications
journal, April 2005

  • Murphy, D. M.; Koop, T.
  • Quarterly Journal of the Royal Meteorological Society, Vol. 131, Issue 608
  • DOI: 10.1256/qj.04.94

Unimpeded Permeation of Water Through Helium-Leak-Tight Graphene-Based Membranes
journal, January 2012


Water adsorption on carbons — Critical review of the most popular analytical approaches
journal, March 2008

  • Furmaniak, Sylwester; Gauden, Piotr A.; Terzyk, Artur P.
  • Advances in Colloid and Interface Science, Vol. 137, Issue 2
  • DOI: 10.1016/j.cis.2007.08.001

Water adsorption in MOFs: fundamentals and applications
journal, January 2014

  • Canivet, Jérôme; Fateeva, Alexandra; Guo, Youmin
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00078A

The role of water co-adsorption on the modification of ZnO nanowires using acetic acid
journal, January 2014

  • Domínguez, Adriel; grosse Holthaus, Svea; Köppen, Susan
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 18
  • DOI: 10.1039/C4CP00667D

Shape Matters: Anisotropy of the Morphology of Inorganic Colloidal Particles - Synthesis and Function
journal, August 2011


Synthesis and Characterization of Magnetic Iron Sulfide Nanowires
journal, December 2003


Switchable Ionic liquids (SILs) based on glycerol and acid gases
journal, January 2011

  • Anugwom, Ikenna; Mäki-Arvela, Päivi; Virtanen, Pasi
  • RSC Advances, Vol. 1, Issue 3
  • DOI: 10.1039/c1ra00154j

Electrically Switchable Capillarity of Ionic Liquids
journal, January 2012

  • Hu, Xiaodong; Zhang, Shiguo; Qu, Chao
  • Journal of Adhesion Science and Technology, Vol. ahead-of-print, Issue ahead-of-print
  • DOI: 10.1163/156856111X600442

Green chemistry: Reversible nonpolar-to-polar solvent
journal, August 2005

  • Jessop, Philip G.; Heldebrant, David J.; Li, Xiaowang
  • Nature, Vol. 436, Issue 7054, p. 1102-1102
  • DOI: 10.1038/4361102a

Reversible Uptake of COS, CS2, and SO2: Ionic Liquids with O-Alkylxanthate, O-Alkylthiocarbonyl, and O-Alkylsulfite Anions
journal, August 2009

  • Heldebrant, David J.; Yonker, Clement R.; Jessop, Philip G.
  • Chemistry - A European Journal, Vol. 15, Issue 31, p. 7619-7627
  • DOI: 10.1002/chem.200802602

A Molecular Model for Adsorption of Water on Activated Carbon:  Comparison of Simulation and Experiment
journal, January 1999

  • McCallum, C. L.; Bandosz, T. J.; McGrother, S. C.
  • Langmuir, Vol. 15, Issue 2
  • DOI: 10.1021/la9805950

Water sorption and time-dependent crystallization behaviour of freeze-dried lactose–salt mixtures
journal, April 2007


The dry oxidation of tetragonal FeS 1- x mackinawite
journal, October 2001

  • Boursiquot, S.; Mullet, M.; Abdelmoula, M.
  • Physics and Chemistry of Minerals, Vol. 28, Issue 9
  • DOI: 10.1007/s002690100193

Origin of the Large N 1s Binding Energy in X-ray Photoelectron Spectra of Calcined Carbonaceous Materials
journal, January 1996

  • Casanovas, Jordi; Ricart, Josep Manel; Rubio, Jaime
  • Journal of the American Chemical Society, Vol. 118, Issue 34
  • DOI: 10.1021/ja960338m

In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High-Performance Supercapacitors
journal, May 2014

  • Jeon, Ju-Won; Sharma, Ronish; Meduri, Praveen
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 10
  • DOI: 10.1021/am500339x

Powders with superparamagnetic Fe 3 C particles studied with Mössbauer spectrometry
journal, March 2010


Micro and mesoporous metal–organic frameworks for catalysis applications
journal, January 2010

  • Thallapally, Praveen K.; Fernandez, Carlos A.; Motkuri, Radha Kishan
  • Dalton Trans., Vol. 39, Issue 7
  • DOI: 10.1039/B921118G

Voigt-based methods for arbitrary-shape static hyperfine parameter distributions in Mössbauer spectroscopy
journal, May 1991

  • Rancourt, D. G.; Ping, J. Y.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 58, Issue 1
  • DOI: 10.1016/0168-583X(91)95681-3

Adsorption of water molecules on partially oxidized graphite surfaces: a molecular dynamics study of the competition between OH and COOH sites,
journal, January 2008

  • Picaud, Sylvain; Collignon, Barbara; Hoang, Paul N. M.
  • Physical Chemistry Chemical Physics, Vol. 10, Issue 46
  • DOI: 10.1039/b811126j

Water adsorption on a NaCl (001) surface: A density functional theory study
journal, December 2006


Structure and stability of thin water films on quartz surfaces
journal, October 2010

  • Chen, Yun-Wen; Cheng, Hai-Ping
  • Applied Physics Letters, Vol. 97, Issue 16
  • DOI: 10.1063/1.3504710

Kinetics of Capillary Condensation of Water in Mesoporous Carbon: Nucleation and Meniscus Growth
journal, July 2015

  • Morishige, Kunimitsu; Kittaka, Shigeharu
  • The Journal of Physical Chemistry C, Vol. 119, Issue 32
  • DOI: 10.1021/acs.jpcc.5b04596

Evaporation rate of water in hydrophobic confinement
journal, March 2012

  • Sharma, S.; Debenedetti, P. G.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 12
  • DOI: 10.1073/pnas.1116167109

Hydrophobicity at Small and Large Length Scales
journal, June 1999

  • Lum, Ka; Chandler, David; Weeks, John D.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 22
  • DOI: 10.1021/jp984327m

Evaporation Length Scales of Confined Water and Some Common Organic Liquids
journal, April 2011

  • Cerdeiriña, Claudio A.; Debenedetti, Pablo G.; Rossky, Peter J.
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 9
  • DOI: 10.1021/jz200319g

Water conduction through the hydrophobic channel of a carbon nanotube
journal, November 2001

  • Hummer, G.; Rasaiah, J. C.; Noworyta, J. P.
  • Nature, Vol. 414, Issue 6860
  • DOI: 10.1038/35102535

Liquid−Vapor Oscillations of Water Nanoconfined between Hydrophobic Disks: Thermodynamics and Kinetics
journal, June 2010

  • Xu, Limei; Molinero, Valeria
  • The Journal of Physical Chemistry B, Vol. 114, Issue 21
  • DOI: 10.1021/jp102443m

A Monte Carlo simulation of the hydrophobic interaction
journal, January 1979

  • Pangali, C.; Rao, M.; Berne, B. J.
  • The Journal of Chemical Physics, Vol. 71, Issue 7
  • DOI: 10.1063/1.438701

Activation Barrier Scaling for the Spontaneous Evaporation of Confined Water
journal, December 2004

  • Luzar, Alenka
  • The Journal of Physical Chemistry B, Vol. 108, Issue 51
  • DOI: 10.1021/jp0470703

Computer Simulation of Hydrophobic Hydration Forces on Stacked Plates at Short Range
journal, March 1995

  • Wallqvist, A.; Berne, B. J.
  • The Journal of Physical Chemistry, Vol. 99, Issue 9
  • DOI: 10.1021/j100009a053

Direct measurements of long-range surface forces in gas and liquid media
journal, July 1982

  • Rabinovich, Ya. I.; Derjaguin, B. V.; Churaev, N. V.
  • Advances in Colloid and Interface Science, Vol. 16, Issue 1
  • DOI: 10.1016/0001-8686(82)85007-0

The hydrophobic interaction is long range, decaying exponentially with distance
journal, November 1982

  • Israelachvili, Jacob; Pashley, Richard
  • Nature, Vol. 300, Issue 5890
  • DOI: 10.1038/300341a0

Interplay between Hydrodynamics and the Free Energy Surface in the Assembly of Nanoscale Hydrophobes
journal, December 2011

  • Morrone, Joseph A.; Li, Jingyuan; Berne, B. J.
  • The Journal of Physical Chemistry B, Vol. 116, Issue 1
  • DOI: 10.1021/jp209568n

Free Energy Barriers to Evaporation of Water in Hydrophobic Confinement
journal, October 2012

  • Sharma, Sumit; Debenedetti, Pablo G.
  • The Journal of Physical Chemistry B, Vol. 116, Issue 44
  • DOI: 10.1021/jp308362h

Experimental and numerical study on water sorption over modified mesoporous silica
journal, January 2015


Water adsorption in metal-organic frameworks with open-metal sites
journal, December 2014

  • Peng, Xuan; Lin, Li-Chiang; Sun, Weizhen
  • AIChE Journal, Vol. 61, Issue 2
  • DOI: 10.1002/aic.14707

Anisotropic nanomaterials: structure, growth, assembly, and functions
journal, January 2011

  • Sajanlal, Panikkanvalappil R.; Sreeprasad, Theruvakkattil S.; Samal, Akshaya K.
  • Nano Reviews, Vol. 2, Issue 1
  • DOI: 10.3402/nano.v2i0.5883

Synthesis of CoPt Nanorods in Ionic Liquids
journal, April 2005

  • Wang, Yong; Yang, Hong
  • Journal of the American Chemical Society, Vol. 127, Issue 15
  • DOI: 10.1021/ja043625w

Organized 3D-alkyl imidazolium ionic liquids could be used to control the size of in situ generated ruthenium nanoparticles?
journal, January 2009

  • Gutel, Thibaut; Santini, Catherine C.; Philippot, Karine
  • Journal of Materials Chemistry, Vol. 19, Issue 22
  • DOI: 10.1039/b821659b

Ionic-Liquid-Assisted Formation of Silver Nanowires
journal, May 2009

  • Kim, Tae Young; Kim, Won Jung; Hong, Seung Hyun
  • Angewandte Chemie International Edition, Vol. 48, Issue 21
  • DOI: 10.1002/anie.200806379

Vapor-liquid-solid growth of Si nanowires: A kinetic analysis
journal, July 2012

  • Shakthivel, Dhayalan; Raghavan, Srinivasan
  • Journal of Applied Physics, Vol. 112, Issue 2
  • DOI: 10.1063/1.4737597

Solvent cavitation under solvophobic confinement
journal, August 2013

  • Ashbaugh, Henry S.
  • The Journal of Chemical Physics, Vol. 139, Issue 6
  • DOI: 10.1063/1.4817661