Reagents and methods for fluorinating a substrate
Abstract
Described herein are perfluoroalkylated zinc compounds having the structure of Formula (I) or Formula (II), which can be used to perfluoroalkylate organic, inorganic and organometallic substrates. Methods of making and using these compounds by reacting zinc or a dialkylzinc compound with a perfluoroalkyl dihalide in a solvent such as tetrahydrofuran, dioxane or diglyme, are also described.
- Inventors:
- Issue Date:
- Research Org.:
- Lehigh Univ., Bethlehem, PA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1496631
- Patent Number(s):
- 10144747
- Application Number:
- 14/903,724
- Assignee:
- Lehigh University, Bethlehem, PA
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
- DOE Contract Number:
- FG02-13ER16369
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Jul 08
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Vicic, David. Reagents and methods for fluorinating a substrate. United States: N. p., 2018.
Web.
Vicic, David. Reagents and methods for fluorinating a substrate. United States.
Vicic, David. Tue .
"Reagents and methods for fluorinating a substrate". United States. https://www.osti.gov/servlets/purl/1496631.
@article{osti_1496631,
title = {Reagents and methods for fluorinating a substrate},
author = {Vicic, David},
abstractNote = {Described herein are perfluoroalkylated zinc compounds having the structure of Formula (I) or Formula (II), which can be used to perfluoroalkylate organic, inorganic and organometallic substrates. Methods of making and using these compounds by reacting zinc or a dialkylzinc compound with a perfluoroalkyl dihalide in a solvent such as tetrahydrofuran, dioxane or diglyme, are also described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {12}
}
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Works referenced in this record:
Method of storing active zero valent zinc metal
patent, October 1999
- Rieke, Reuben D.
- US Patent Document 5,964,919