Materials with extremely durable intercalation of lithium and manufacturing methods thereof

Title: Materials with extremely durable intercalation of lithium and manufacturing methods thereof

Abstract

Composites of silicon and various porous scaffold materials, such as carbon material comprising micro-, meso- and/or macropores, and methods for manufacturing the same are provided. The compositions find utility in various applications, including electrical energy storage electrodes and devices comprising the same.

Inventors:: Sakshaug, Avery; Costantino, Henry R.; Feaver, Aaron M.; Thompkins, Leah A.; Geramita, Katharine; Kron, Benjamin E.; Fredrick, Sarah; Afkhami, Farshid; Strong, Adam

Issue Date:: 2018-12-04

Research Org.:: Group 14 Technologies, Inc., Seattle, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1496212

Patent Number(s):: 10,147,950

Application Number:: 15/248,830

Assignee:: Group 14 Technologies, Inc. (Seattle, WA) DOEEE

DOE Contract Number:: EE0007312

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Aug 26

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Sakshaug, Avery, Costantino, Henry R., Feaver, Aaron M., Thompkins, Leah A., Geramita, Katharine, Kron, Benjamin E., Fredrick, Sarah, Afkhami, Farshid, and Strong, Adam. Materials with extremely durable intercalation of lithium and manufacturing methods thereof.  United States: N. p., 2018. 
        Web.

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                    Sakshaug, Avery, Costantino, Henry R., Feaver, Aaron M., Thompkins, Leah A., Geramita, Katharine, Kron, Benjamin E., Fredrick, Sarah, Afkhami, Farshid, & Strong, Adam. Materials with extremely durable intercalation of lithium and manufacturing methods thereof.  United States.

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                    Sakshaug, Avery, Costantino, Henry R., Feaver, Aaron M., Thompkins, Leah A., Geramita, Katharine, Kron, Benjamin E., Fredrick, Sarah, Afkhami, Farshid, and Strong, Adam. Tue .  
        "Materials with extremely durable intercalation of lithium and manufacturing methods thereof".  United States.  https://www.osti.gov/servlets/purl/1496212.

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@article{osti_1496212,

  title        = {Materials with extremely durable intercalation of lithium and manufacturing methods thereof},

  author       = {Sakshaug, Avery and Costantino, Henry R. and Feaver, Aaron M. and Thompkins, Leah A. and Geramita, Katharine and Kron, Benjamin E. and Fredrick, Sarah and Afkhami, Farshid and Strong, Adam},

  abstractNote = {Composites of silicon and various porous scaffold materials, such as carbon material comprising micro-, meso- and/or macropores, and methods for manufacturing the same are provided. The compositions find utility in various applications, including electrical energy storage electrodes and devices comprising the same.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {12}

}

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Systems, components, and methods relating to subterranean containment barriers. Laterally adjacent tubular casings having male interlock structures and multiple female interlock structures defining recesses for receiving a male interlock structure are used to create subterranean barriers for containing and treating buried waste and its effluents. The multiple female interlock structures enable the barriers to be varied around subsurface objects and to form barrier sidewalls. The barrier may be used for treating and monitoring a zone of interest.
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Methods and systems for electrophoretic deposition of energetic materials and compositions thereof

Patent Sullivan, Kyle T. ; Gash, Alexander E. ; Kuntz, Joshua D. ; ...

A product includes: a part including at least one component characterized as an energetic material, where the at least one component is at least partially characterized by physical characteristics of being deposited by an electrophoretic deposition process. A method includes: providing a plurality of particles of an energetic material suspended in a dispersion liquid to an EPD chamber or configuration; applying a voltage difference across a first pair of electrodes to generate a first electric field in the EPD chamber; and depositing at least some of the particles of the energetic material on at least one surface of a substrate,more »« less
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Thermoelectric materials and methods for synthesis thereof

Patent Ren, Zhifeng ; Zhang, Qinyong ; Zhang, Qian ; ...

Materials having improved thermoelectric properties are disclosed. In some embodiments, lead telluride/selenide based materials with improved figure of merit and mechanical properties are disclosed. In some embodiments, the lead telluride/selenide based materials of the present disclosure are p-type thermoelectric materials formed by adding sodium (Na), silicon (Si) or both to thallium doped lead telluride materials. In some embodiments, the lead telluride/selenide based materials are formed by doping lead telluride/selenides with potassium.
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Title: Materials with extremely durable intercalation of lithium and manufacturing methods thereof

Abstract

Citation Formats

Method for molding precured high temperature resins patent, September 1988

Low density, resorcinol-formaldehyde aerogels patent, October 1989

High-density adsorbent and method of producing same patent, March 1991

Supercapacitors based on carbon foams patent, November 1993

Production of highly microporous activated carbon products patent, May 1995

Carbon foams for energy storage devices patent, June 1996

Microporous carbons for fuel gas storage patent, March 1997

Process for producing carbon foams for energy storage devices patent, August 1998

Highly microporous carbons and process of manufacture patent, October 1999

Carbon material for electric double layer capacitor, method of producing same, electric double layer capacitor and method of fabricating same patent, October 2001

Metal oxide electrode for supercapacitor and manufacturing method thereof patent, January 2002

Activated carbon for use in electric double layer capacitor and method of producing the same patent, July 2003

Carbonaceous material, its production process and electric double layer capacitor employing it patent, March 2005

Lithium-alloying-material/carbon composite patent, January 2013

Porous carbon for electrochemical double layer capacitors patent, July 2013

Porous Anode Active Material, Method Of Preparing The Same, And Anode And Lithium Battery Employing The Same patent-application, June 2008

Hybrid anode compositions for lithium ion batteries patent-application, May 2009

Composite electrode comprising a carbon structure coated with a thin film of mixed metal oxides for electrochemical energy storage patent-application, July 2009

High Energy Lithium Ion Batteries With Particular Negative Electrode Compositions patent-application, December 2009

High Energy Density Redox Flow Device patent-application, February 2010

A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery journal, January 1996

Methane storage in activated carbon fibres journal, January 1997

Grading Aggregates - II. - The Application of Mathematical Formulas to Mortars journal, September 1931

Carbon cryogel as support of platinum nano-sized electrocatalyst for the hydrogen oxidation reaction journal, May 2006

Characterization of carbon cryogel synthesized by sol–gel polycondensation and freeze-drying journal, January 2004

Tailored Porous Materials journal, October 1999

Structural Investigation of Resorcinol Formaldehyde and Carbon Aerogels Using SAXS and BET journal, January 1997

Li-ion capacitors with carbon cathode and hard carbon/stabilized lithium metal powder anode electrodes journal, September 2012

Influence of drying on the morphology of resorcinol–formaldehyde-based carbon gels journal, November 2005

Morphology and organic EDLC applications of chemically activated AR-resin-based carbons journal, January 2002

Preparation of carbon gel microspheres containing silicon powder for lithium ion battery anodes journal, January 2004

Are carbon nanostructures an efficient hydrogen storage medium? journal, August 2003

Synthesis of mesoporous carbon composite and its electric double-layer formation behavior journal, July 2006

Effects of electrolytes and electrochemical pretreatments on the capacitive characteristics of activated carbon fabrics for supercapacitors journal, January 2004

Natural gas storage in activated carbon pellets without a binder journal, January 2002

Highly dispersed platinum catalysts prepared by impregnation of texture-tailored carbon xerogels journal, June 2006

Synthesis of transition metal-doped carbon xerogels by solubilization of metal salts in resorcinol–formaldehyde aqueous solution journal, January 2004

High-voltage asymmetric supercapacitors operating in aqueous electrolyte journal, November 2005

Correlation between the capacitor performance and pore structure journal, January 2006

Adsorption of phenol and reactive dyes from aqueous solution on carbon cryogel microspheres with controlled porous structure journal, November 2006

Texture control of freeze-dried resorcinol–formaldehyde gels journal, April 1998

Estimation of the pore-size distribution function from the nitrogen adsorption isotherm. Comparison of density functional theory and the method of Do and co-workers journal, January 2003

Influence of pore structure and surface chemistry on electric double layer capacitance in non-aqueous electrolyte journal, January 2003

Preparation of resorcinol–formaldehyde carbon cryogel microhoneycombs journal, January 2004

Aerogels derived from multifunctional organic monomers journal, January 1992

Structure of organic aerogels. 1. Morphology and scaling journal, September 1993

Methane Storage within Dry and Wet Active Carbons: A Comparative Study journal, September 2003

Prevulcanized natural rubber latex/clay aerogel nanocomposites journal, July 2008

Studies of activated carbons used in double-layer capacitors journal, July 1998

Characterization of the Lithium/Oxygen Organic Electrolyte Battery journal, January 2002

Ether-Based Electrolytes for the Lithium/Oxygen Organic Electrolyte Battery journal, January 2006

Microporosity in carbon aerogels journal, April 1998

Simulation study on the relationship between a high resolution αs-plot and the pore size distribution for activated carbon journal, October 1998

Evaluation of lithium-ion capacitors assembled with pre-lithiated graphite anode and activated carbon cathode journal, March 2012

Removal of single component chlorinated hydrocarbon vapor by activated carbon of very high surface area journal, January 1999

Influence of freeze-drying conditions on the mesoporosity of organic gels as carbon precursors journal, January 2000

Preparation of mesoporous carbon by freeze drying journal, January 1999

Influence of surfactants on porous properties of carbon cryogels prepared by sol–gel polycondensation of resorcinol and formaldehyde journal, January 2003

A novel electrode material for electric double-layer capacitors journal, March 2005

Air electrode design for sustained high power operation of Li/air batteries journal, December 2009

Fabrication and nano-structure control of carbon aerogels via a microemulsion-templated sol–gel polymerization method journal, April 2006

RETRACTED: Pore size control of Pitch-based activated carbon fibers by pyrolytic deposition of propylene journal, August 2005

Synthesis of mesoporous carbon and its adsorption property to biomolecules journal, November 2008

Control of mesoporosity of carbon gels prepared by sol–gel polycondensation and freeze drying journal, August 2001

Porous properties of carbon gel microspheres as adsorbents for gas separation journal, January 2004

Preparation and characterization of carbon cryogel microspheres journal, July 2002

Preparation of highly microporous and mesoporous carbon from the mesophase pitch and its carbon foams with KOH journal, January 2004

Method for molding precured high temperature resins
patent, September 1988

Low density, resorcinol-formaldehyde aerogels
patent, October 1989

High-density adsorbent and method of producing same
patent, March 1991

Supercapacitors based on carbon foams
patent, November 1993

Production of highly microporous activated carbon products
patent, May 1995

Carbon foams for energy storage devices
patent, June 1996

Microporous carbons for fuel gas storage
patent, March 1997

Process for producing carbon foams for energy storage devices
patent, August 1998

Highly microporous carbons and process of manufacture
patent, October 1999

Carbon material for electric double layer capacitor, method of producing same, electric double layer capacitor and method of fabricating same
patent, October 2001

Metal oxide electrode for supercapacitor and manufacturing method thereof
patent, January 2002

Activated carbon for use in electric double layer capacitor and method of producing the same
patent, July 2003

Carbonaceous material, its production process and electric double layer capacitor employing it
patent, March 2005

Lithium-alloying-material/carbon composite
patent, January 2013

Porous carbon for electrochemical double layer capacitors
patent, July 2013

Porous Anode Active Material, Method Of Preparing The Same, And Anode And Lithium Battery Employing The Same
patent-application, June 2008

Hybrid anode compositions for lithium ion batteries
patent-application, May 2009

Composite electrode comprising a carbon structure coated with a thin film of mixed metal oxides for electrochemical energy storage
patent-application, July 2009

High Energy Lithium Ion Batteries With Particular Negative Electrode Compositions
patent-application, December 2009

High Energy Density Redox Flow Device
patent-application, February 2010

A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery
journal, January 1996

Methane storage in activated carbon fibres
journal, January 1997

Grading Aggregates - II. - The Application of Mathematical Formulas to Mortars
journal, September 1931

Carbon cryogel as support of platinum nano-sized electrocatalyst for the hydrogen oxidation reaction
journal, May 2006

Characterization of carbon cryogel synthesized by sol–gel polycondensation and freeze-drying
journal, January 2004

Tailored Porous Materials
journal, October 1999

Structural Investigation of Resorcinol Formaldehyde and Carbon Aerogels Using SAXS and BET
journal, January 1997

Li-ion capacitors with carbon cathode and hard carbon/stabilized lithium metal powder anode electrodes
journal, September 2012

Influence of drying on the morphology of resorcinol–formaldehyde-based carbon gels
journal, November 2005

Morphology and organic EDLC applications of chemically activated AR-resin-based carbons
journal, January 2002

Preparation of carbon gel microspheres containing silicon powder for lithium ion battery anodes
journal, January 2004

Are carbon nanostructures an efficient hydrogen storage medium?
journal, August 2003

Synthesis of mesoporous carbon composite and its electric double-layer formation behavior
journal, July 2006

Effects of electrolytes and electrochemical pretreatments on the capacitive characteristics of activated carbon fabrics for supercapacitors
journal, January 2004

Natural gas storage in activated carbon pellets without a binder
journal, January 2002

Highly dispersed platinum catalysts prepared by impregnation of texture-tailored carbon xerogels
journal, June 2006

Synthesis of transition metal-doped carbon xerogels by solubilization of metal salts in resorcinol–formaldehyde aqueous solution
journal, January 2004

High-voltage asymmetric supercapacitors operating in aqueous electrolyte
journal, November 2005

Correlation between the capacitor performance and pore structure
journal, January 2006

Adsorption of phenol and reactive dyes from aqueous solution on carbon cryogel microspheres with controlled porous structure
journal, November 2006

Texture control of freeze-dried resorcinol–formaldehyde gels
journal, April 1998

Estimation of the pore-size distribution function from the nitrogen adsorption isotherm. Comparison of density functional theory and the method of Do and co-workers
journal, January 2003

Influence of pore structure and surface chemistry on electric double layer capacitance in non-aqueous electrolyte
journal, January 2003

Preparation of resorcinol–formaldehyde carbon cryogel microhoneycombs
journal, January 2004

Aerogels derived from multifunctional organic monomers
journal, January 1992

Structure of organic aerogels. 1. Morphology and scaling
journal, September 1993

Methane Storage within Dry and Wet Active Carbons: A Comparative Study
journal, September 2003

Prevulcanized natural rubber latex/clay aerogel nanocomposites
journal, July 2008

Studies of activated carbons used in double-layer capacitors
journal, July 1998

Characterization of the Lithium/Oxygen Organic Electrolyte Battery
journal, January 2002

Ether-Based Electrolytes for the Lithium/Oxygen Organic Electrolyte Battery
journal, January 2006

Microporosity in carbon aerogels
journal, April 1998

Simulation study on the relationship between a high resolution αs-plot and the pore size distribution for activated carbon
journal, October 1998

Evaluation of lithium-ion capacitors assembled with pre-lithiated graphite anode and activated carbon cathode
journal, March 2012

Removal of single component chlorinated hydrocarbon vapor by activated carbon of very high surface area
journal, January 1999

Influence of freeze-drying conditions on the mesoporosity of organic gels as carbon precursors
journal, January 2000

Preparation of mesoporous carbon by freeze drying
journal, January 1999

Influence of surfactants on porous properties of carbon cryogels prepared by sol–gel polycondensation of resorcinol and formaldehyde
journal, January 2003

A novel electrode material for electric double-layer capacitors
journal, March 2005

Air electrode design for sustained high power operation of Li/air batteries
journal, December 2009

Fabrication and nano-structure control of carbon aerogels via a microemulsion-templated sol–gel polymerization method
journal, April 2006

RETRACTED: Pore size control of Pitch-based activated carbon fibers by pyrolytic deposition of propylene
journal, August 2005

Synthesis of mesoporous carbon and its adsorption property to biomolecules
journal, November 2008

Control of mesoporosity of carbon gels prepared by sol–gel polycondensation and freeze drying
journal, August 2001

Porous properties of carbon gel microspheres as adsorbents for gas separation
journal, January 2004

Preparation and characterization of carbon cryogel microspheres
journal, July 2002

Preparation of highly microporous and mesoporous carbon from the mesophase pitch and its carbon foams with KOH
journal, January 2004