Method to stabilize base metal catalysts by overcoating via atomic layer deposition and resulting product

Dumesic, James A.; O'Neill, Brandon J.

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Title: Method to stabilize base metal catalysts by overcoating via atomic layer deposition and resulting product

Abstract

A method for stabilizing a metal or metal-containing particle supported on a surface is described, along with the resulting composition of matter. The method includes the steps of depositing upon the surface a protective thin film of a material of sufficient thickness to overcoat the metal or metal-containing particle and the surface, thereby yielding an armored surface; and then calcining the armored surface for a time and at a temperature sufficient to form channels in the protective thin film, wherein the channels so formed expose a portion of the metal- or metal-containing particle to the surrounding environment. Also described is a method of performing a heterogeneous catalytic reaction using the stabilized, supported catalyst.

Inventors:: Dumesic, James A.; O'Neill, Brandon J.

Issue Date:: 2018-11-27

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1495370

Patent Number(s):: 10137434

Application Number:: 15/232,910

Assignee:: Wisconsin Alumni Research Foundation (Madison, WI)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J21/04 - Alumina
B01J21/063 - {Titanium
B01J23/72 - Copper
B01J23/94 - of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
B01J33/00 - Protection of catalysts, e.g. by coating
B01J35/0006 - {Catalysts containing parts with different compositions}
B01J35/02 - Solids
B01J37/0221 - {of particles}
B01J37/08 - Heat treatment {

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D307/44 - Furfuryl alcohol

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/584 - of catalysts

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Aug 10

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Dumesic, James A., and O'Neill, Brandon J. Method to stabilize base metal catalysts by overcoating via atomic layer deposition and resulting product.  United States: N. p., 2018. 
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                    Dumesic, James A., & O'Neill, Brandon J. Method to stabilize base metal catalysts by overcoating via atomic layer deposition and resulting product.  United States.

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                    Dumesic, James A., and O'Neill, Brandon J. Tue .  
        "Method to stabilize base metal catalysts by overcoating via atomic layer deposition and resulting product".  United States.  https://www.osti.gov/servlets/purl/1495370.

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@article{osti_1495370,

  title        = {Method to stabilize base metal catalysts by overcoating via atomic layer deposition and resulting product},

  author       = {Dumesic, James A. and O'Neill, Brandon J.},

  abstractNote = {A method for stabilizing a metal or metal-containing particle supported on a surface is described, along with the resulting composition of matter. The method includes the steps of depositing upon the surface a protective thin film of a material of sufficient thickness to overcoat the metal or metal-containing particle and the surface, thereby yielding an armored surface; and then calcining the armored surface for a time and at a temperature sufficient to form channels in the protective thin film, wherein the channels so formed expose a portion of the metal- or metal-containing particle to the surrounding environment. Also described is a method of performing a heterogeneous catalytic reaction using the stabilized, supported catalyst.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {11}

}

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Works referenced in this record:

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Lu, Junling; Liu, Bin; Greeley, Jeffrey P.
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Stabilization of Supported Metal Nanoparticles Using an Ultrathin Porous Shell
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Similar Records

Title: Method to stabilize base metal catalysts by overcoating via atomic layer deposition and resulting product

Abstract

Citation Formats

Porous Alumina Protective Coatings on Palladium Nanoparticles by Self-Poisoned Atomic Layer Deposition journal, May 2012

Core-Satellite Nanocomposite Catalysts Protected by a Porous Silica Shell: Controllable Reactivity, High Stability, and Magnetic Recyclability journal, November 2008

Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process journal, June 2005

Chemisorption of hydrogen on stepped (410) surfaces of Ni and Cu journal, September 1995

FTIR study of CO interaction with Cu/TiO2 journal, April 2003

Method of forming metal layer using atomic layer deposition and semiconductor device having the metal layer as barrier metal layer or upper or lower electrode of capacitor patent, September 2001

Al 2 O 3 and TiO 2 Atomic Layer Deposition on Copper for Water Corrosion Resistance journal, November 2011

Surface alumina species on modified titanium dioxide: A solid-state 27Al MAS and 3QMAS NMR investigation of catalyst supports journal, May 2010

Foldamers with Heterogeneous Backbones journal, October 2008

Stabilization of Supported Metal Nanoparticles Using an Ultrathin Porous Shell journal, August 2011

Deactivation of supported copper metal catalysts for hydrogenation reactions journal, April 2001

Metal Catalyst Composition patent-application, April 2014

Deactivation of metal catalysts in liquid phase organic reactions journal, July 2003

Joint diffraction and modeling approach to the structure of liquid alumina journal, January 2013

Structural effects on trends in the deposition and dissolution of metal-supported metal adstructures journal, August 2010

Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition journal, March 2012

Method for manufacturing thin film using atomic layer deposition patent, August 2001

The measurement of copper surface areas by reactive frontal chromatography*1 journal, January 1987

Atomic Layer Deposition: An Overview journal, January 2010

Crystallinity of inorganic films grown by atomic layer deposition: Overview and general trends journal, January 2013

CO−NO and CO−O2 Interactions on Cu(100) between 25 and 200 K Studied with Infrared Reflection Absorption Spectroscopy journal, February 2005

Porous Alumina Protective Coatings on Palladium Nanoparticles by Self-Poisoned Atomic Layer Deposition
journal, May 2012

Core-Satellite Nanocomposite Catalysts Protected by a Porous Silica Shell: Controllable Reactivity, High Stability, and Magnetic Recyclability
journal, November 2008

Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process
journal, June 2005

Chemisorption of hydrogen on stepped (410) surfaces of Ni and Cu
journal, September 1995

FTIR study of CO interaction with Cu/TiO₂
journal, April 2003

Method of forming metal layer using atomic layer deposition and semiconductor device having the metal layer as barrier metal layer or upper or lower electrode of capacitor
patent, September 2001

Al ₂ O ₃ and TiO ₂ Atomic Layer Deposition on Copper for Water Corrosion Resistance
journal, November 2011

Surface alumina species on modified titanium dioxide: A solid-state ²⁷Al MAS and 3QMAS NMR investigation of catalyst supports
journal, May 2010

Foldamers with Heterogeneous Backbones
journal, October 2008

Stabilization of Supported Metal Nanoparticles Using an Ultrathin Porous Shell
journal, August 2011

Deactivation of supported copper metal catalysts for hydrogenation reactions
journal, April 2001

Metal Catalyst Composition
patent-application, April 2014

Deactivation of metal catalysts in liquid phase organic reactions
journal, July 2003

Joint diffraction and modeling approach to the structure of liquid alumina
journal, January 2013

Structural effects on trends in the deposition and dissolution of metal-supported metal adstructures
journal, August 2010

Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition
journal, March 2012

Method for manufacturing thin film using atomic layer deposition
patent, August 2001

The measurement of copper surface areas by reactive frontal chromatography*1
journal, January 1987

Atomic Layer Deposition: An Overview
journal, January 2010

Crystallinity of inorganic films grown by atomic layer deposition: Overview and general trends
journal, January 2013

CO−NO and CO−O₂ Interactions on Cu(100) between 25 and 200 K Studied with Infrared Reflection Absorption Spectroscopy
journal, February 2005