Capture and release of acid gasses using tunable organic solvents with aminopyridine
Abstract
A class of water lean, organic solvents that can bind with various acid gasses to form acid gas bound molecules having a high degree of intramolecular hydrogen bonding which enables their use as regenerable solvents for acid gas capture. Unlike the other devices described in the prior art, the present invention takes advantage of shortened distances between the portions of the molecule that form hydrogen bonds within the structures when loaded with an acid gas so as to create a molecule with a higher internal bonding affinity and a reduced proclivity for agglomeration with other molecules.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1495039
- Patent Number(s):
- 10130907
- Application Number:
- 15/410,523
- Assignee:
- BATTELLE MEMORIAL INSTITUTE (Richland, WA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
- DOE Contract Number:
- AC0576RL01830
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2017 Jan 19
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Koech, Phillip K., Malhotra, Deepika, Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Rober J., and Cantu, David C.. Capture and release of acid gasses using tunable organic solvents with aminopyridine. United States: N. p., 2018.
Web.
Koech, Phillip K., Malhotra, Deepika, Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Rober J., & Cantu, David C.. Capture and release of acid gasses using tunable organic solvents with aminopyridine. United States.
Koech, Phillip K., Malhotra, Deepika, Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Rober J., and Cantu, David C.. Tue .
"Capture and release of acid gasses using tunable organic solvents with aminopyridine". United States. https://www.osti.gov/servlets/purl/1495039.
@article{osti_1495039,
title = {Capture and release of acid gasses using tunable organic solvents with aminopyridine},
author = {Koech, Phillip K. and Malhotra, Deepika and Heldebrant, David J. and Glezakou, Vassiliki-Alexandra and Rousseau, Rober J. and Cantu, David C.},
abstractNote = {A class of water lean, organic solvents that can bind with various acid gasses to form acid gas bound molecules having a high degree of intramolecular hydrogen bonding which enables their use as regenerable solvents for acid gas capture. Unlike the other devices described in the prior art, the present invention takes advantage of shortened distances between the portions of the molecule that form hydrogen bonds within the structures when loaded with an acid gas so as to create a molecule with a higher internal bonding affinity and a reduced proclivity for agglomeration with other molecules.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {11}
}
Works referenced in this record:
Liquid absorbent for acidic gases and process of deacidification of a gas
patent, November 1994
- Peytavy, Jean-Louis; Le Coz, Philippe; Oliveau, Olivier
- US Patent Document 5,366,709
The reaction of trimethylamine in liquid hydrogen sulphide: an electrical conductivity study
journal, June 1983
- Halliday, James; Bindner, Patrick
- Canadian Journal of Chemistry, Vol. 61, Issue 6, p. 1142-1145
Equimolar CO2 Absorption by Anion-Functionalized Ionic Liquids
journal, February 2010
- Gurkan, Burcu E.; de la Fuente, Juan C.; Mindrup, Elaine M.
- Journal of the American Chemical Society, Vol. 132, Issue 7, p. 2116-2117
Single component, reversible ionic liquids for energy applications
journal, June 2010
- Blasucci, Vittoria; Hart, Ryan; Mestre, Veronica Llopis
- Fuel, Vol. 89, Issue 6, p. 1315-1319
Reversible Uptake of COS, CS2, and SO2: Ionic Liquids with O-Alkylxanthate, O-Alkylthiocarbonyl, and O-Alkylsulfite Anions
journal, August 2009
- Heldebrant, Davidā J.; Yonker, Clementā R.; Jessop, Philipā G.
- Chemistry - A European Journal, Vol. 15, Issue 31, p. 7619-7627
Removing hydrogen sulphide from a gas mixture
patent, September 1990
- Van Baar, Johannes F.; Van Lith, Walterus J.
- US Patent Document 4,959,086
CO2 -binding organic liquids (CO2 BOLs) for post-combustion CO2 capture
journal, February 2009
- Heldebrant, David J.; Yonker, Clement R.; Jessop, Philip G.
- Energy Procedia, Vol. 1, Issue 1, p. 1187-1195
Capture and Release of Mixed Acid Gasses with Binding Organic Liquids
patent-application, May 2009
- Heldebrant, David J.; Yonker, Clement R.
- US Patent Application 12/360717; 20090136402
Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures
journal, February 2008
- Phan, Lam; Chiu, Daniel; Heldebrant, David J.
- Industrial & Engineering Chemistry Research, Vol. 47, Issue 3, p. 539-545
Strong Hydrogen Bonds. III. Hydrogen Sulfide-Hydrosulfide Anion Interactions
journal, December 1966
- McDaniel, Darl; Evans, Wilbur
- Inorganic Chemistry, Vol. 5, Issue 12, p. 2180-2181
Reversibly Switchable Surfactants and Methods of Use Thereof
patent-application, August 2008
- Jessop, Philip G.
- US Patent Application 11/599623; 20080197084
A reversible zwitterionic SO2-binding organic liquid
journal, January 2010
- Heldebrant, David; Koech, Phillip; Yonker, Clement
- Energy Environ. Sci., Vol. 3, Issue 1, p. 111-113
Method of decarbonating a combustion fume with extraction of the solvent contained in the purified fume
patent, December 2008
- Cadours, Renaud; Lecomte, Fabrice; Magna, Lionel
- US Patent Document 7,459,134
Process for the preparation of porous products based on cobalt fluoride or lead fluoride
patent, October 1985
- Bergez, Pierre; Deguelte, Alain; Seigneurin, Laurent
- US Patent Document 4,545,964
Imidazolium-Methyl Sulfites for Use as Starting Compounds for Producing Ionic Liquids
patent-application, November 2007
- Szarvas, Laszlo; Massonne, Klemens
- US Patent Application 11/661306; 20070255064
CO2 Capture by a Task-Specific Ionic Liquid
journal, February 2002
- Bates, Eleanor D.; Mayton, Rebecca D.; Ntai, Ioanna
- Journal of the American Chemical Society, Vol. 124, Issue 6, p. 926-927
System and process for capture of H2S from gaseous process streams and process for regeneration of the capture agent
patent, February 2014
- Heldebrant, David J.; Koech, Phillip K.; Rainbolt, James E.
- US Patent Document 8,652,237
Process of selective separation of hydrogen sulfide from gaseous mixtures containing also carbon dioxide
patent, October 1985
- Gazzi, Luigi; Rescalli, Carlo; Scaramucci, Maria A.
- US Patent Document 4,545,965
Process for the Oxidation of Hydrogen Sulfide to Elementary Sulfur
patent, April 1973
- Schulze, Gerhard; Heck, Wolfgang
- US Patent Document 3725537
Supercritical fluids as diluents in combustion of liquid fuels and waste materials
patent, December 1992
- Nielsen, Kenneth A.
- US Patent Document 5,170,727
Antibacterial Agents
patent-application, May 2005
- Thorarensen, Atli; Ruble, J. Craig; Romero, Donna Lee
- US Patent Application 10/645732; 20050113450
Shielding of Ionic Interactions by Sulfur Dioxide in an Ionic Liquid
journal, May 2008
- Siqueira, Leonardo J. A.; Ando, RoĢmulo A.; Bazito, Fernanda F. C.
- The Journal of Physical Chemistry B, Vol. 112, Issue 20
Using solvents for acidic gas removal
patent, December 1980
- Hong, Charles C.
- US Patent Document 4,238,206
Switchable solvents and methods of use thereof
patent-application, March 2008
- Jessop, Philip G.; Eckert, Charles A.; Liotta, Charles L.
- US Patent Application 11/717172; 20080058549
Desulfurization of Flue Gas: SO2 Absorption by an Ionic Liquid
journal, April 2004
- Wu, Weize; Han, Buxing; Gao, Haixiang
- Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2415-2417
Method for removing carbon dioxide from combustion exhaust gas
patent, March 2000
- Yoshida, Kunihiko; Mimura, Tomio; Shimojo, Shigeru
- US Patent Document 6,036,931
Arylamine Substituted Bicyclic Heteroaromatic Compounds as p38 Kinase Inhibitors
patent-application, January 2006
- Brookings, Daniel Christopher; Davis, Jeremy Martin; Langham, Barry John
- US Patent Application 10/518725; 20060004025
Methods of use of pyridylalkyl phenylthioureas
patent, September 1978
- Callahan, William A.; Glenn, Eldridge Myles; Rector, Douglas L.
- US Patent Document 4,112,100
The use of the Fused Eutectic of Sodium Amide and Potassium Amide in Organic Syntheses
journal, May 1946
- Bergstrom, F. W.; Sturz, H. G.; Tracy, H. W.
- The Journal of Organic Chemistry, Vol. 11, Issue 3
Functionalized Ionic Liquids, and Methods of Use Thereof
patent-application, May 2008
- Davis, James Hillard
- US Patent Application 11/789429; 20080112866
Acid gas disposal method
patent-application, March 2003
- Thomas, Eugene R.; Northrop, P. Scott; Hu, Hua
- US Patent Application 10/234620; 20030047309
Capture and Release of Acid-Gasses with Acid-Gas Binding Organic Compounds
patent-application, September 2009
- Heldebrant, David J.; Yonker, Clement R.; Koech, Phillip K.
- US Patent Application 12/427851; 20090220397
Recovering sulfur from gas streams containing hydrogen sulfide
patent, September 1978
- Atwood, Gilbert R.
- US Patent Document 4,113,849
Process for removal of nitrogen containing contaminants from gas oil feedstreams
patent-application, June 2004
- Lesemann, Markus Friedrich Manfred; Setzer, Constance
- US Patent Application 10/322614; 20040118749
Methods for regenerating a sulfur scavenging compound from a product of a sulfur scavenging reaction
patent, September 1994
- Trauffer, Edward A.; Evans, Robert D.
- US Patent Document 5,347,003
High CO2 to Amine Adsorption Capacity CO2 Scrubbing Processes
patent-application, March 2012
- Kortunov, Pavel; Baugh, Lisa; Calabro, David
- US Patent Application 13/228999; 20120063979
A New Class of Single-Component Absorbents for Reversible Carbon Dioxide Capture under Mild Conditions
journal, November 2014
- Barzagli, Francesco; Lai, Sarah; Mani, Fabrizio
- ChemSusChem, Vol. 8, Issue 1, p. 184-191
Tuning ionic liquids for high gas solubility and reversible gas sorption
journal, January 2008
- Huang, Jun; Riisager, Anders; Berg, Rolf W.
- Journal of Molecular Catalysis A: Chemical, Vol. 279, Issue 2, p. 170-176
Acidic gas absorbent, acidic gas removal device, and acidic gas removal method
patent-application, November 2012
- Murai, Shinji; Saito, Satoshi; Kato, Yasuhiro
- US Patent Application 13/519274; 20120294785
Capture and release of mixed acid gasses with binding organic liquids
patent, September 2010
- Heldebrant, David J.; Yonker, Clement R.
- US Patent Document 7,799,299
Process of scrubbing fuel synthesis gases to remove acid gases and organic sulfur compounds
patent, January 1979
- Braizler, Karl; Doerges, Alexander
- US Patent Document 4,137,294
Efficient CO2 absorption and low temperature desorption with non-aqueous solvents based on 2-amino-2-methyl-1-propanol (AMP)
journal, August 2013
- Barzagli, Francesco; Mani, Fabrizio; Peruzzini, Maurizio
- International Journal of Greenhouse Gas Control, Vol. 16, p. 217-223
Heterocyclic Compound Having Oxime Group
patent-application, October 2005
- Yoshida, Ichiro; Suzuki, Shuichi
- US Patent Application 11/047995; 20050227959
Reactions of carbon dioxide and hydrogen sulfide with some alkanolamines
journal, January 1987
- Maddox, Robert; Mains, Gilbert; Rahman, Mahmud
- Industrial & Engineering Chemistry Research, Vol. 26, Issue 1, p. 27-31
Process for nitrogen oxides reduction and minimization of the production of other pollutants
patent, May 1991
- Epperly, William R.; Sullivan, James C.; Sprague, Barry N.
- US Patent Document 5,017,347
Solubility of Methane in Methyldiethanolamine
journal, July 2006
- Jou, Fang-Yuan; Mather, Alan
- Journal of Chemical & Engineering Data, Vol. 51, Issue 4, p. 1429-1430
Process for treating gas with ultra-lean amine
patent, June 2000
- Dingman, Jr., John Charles; Cummings, Arthur L.
- US Patent Document 6,071,484
Removing sulphur oxides from a fluid stream
patent, April 2014
- Katz, Torsten; Riemann, Christian; Bartling, Karsten
- US Patent Document 8,691,171
Nitric Oxide Donors and Uses Thereof
patent-application, January 2007
- Assaf, Peter; Gazaleen-Mariee, Elham; Naveh, Michael
- US Patent Application 10/555664; 20070021382
Improved Solvent Formulations for Efficient CO2 Absorption and Low-Temperature Desorption
journal, July 2012
- Barzagli, Francesco; Diā Vaira, Massimo; Mani, Fabrizio
- ChemSusChem, Vol. 5, Issue 9, p. 1724-1731
Cyclic Amine Derivatives and Methods of Use
patent-application, October 2005
- Groneberg, Robert D.; Zhan, James; Askew, Jr., Benny C.
- US Patent Application 10/823372; 20050234044
Green chemistry: Reversible nonpolar-to-polar solvent
journal, August 2005
- Jessop, Philip G.; Heldebrant, David J.; Li, Xiaowang
- Nature, Vol. 436, Issue 7054, p. 1102-1102
Reversible Ionic Liquid Stabilized Carbamic Acids: A Pathway Toward Enhanced CO2 Capture
journal, August 2013
- Switzer, Jackson R.; Ethier, Amy L.; Flack, Kyle M.
- Industrial & Engineering Chemistry Research, Vol. 52, Issue 36, p. 13159-13163
Removal Of Acid Gases By Means Of An Absorbent Comprising A Stripping Aid
patent-application, December 2010
- Garcia Andarcia, Hugo Rafael; Notz, Ralf; Sieder, Georg
- US Patent Application 12/819872; 20100319540
Method of removing acidic gases from gaseous mixtures
patent, December 1964
- Deal, Jr., Carl H.; Derr, Elwood L.; Papadopoulos, Michael N.
- US Patent Document 3,161,461
Methods and systems for deacidizing gaseous mixtures
patent, May 2010
- Hu, Liang
- US Patent Document 7,718,151