Capture and release of acid gasses using tunable organic solvents with aminopyridine

Koech, Phillip K.; Malhotra, Deepika; Heldebrant, David J.; Glezakou, Vassiliki-Alexandra; Rousseau, Rober J.; Cantu, David C.

Title: Capture and release of acid gasses using tunable organic solvents with aminopyridine

Abstract

A class of water lean, organic solvents that can bind with various acid gasses to form acid gas bound molecules having a high degree of intramolecular hydrogen bonding which enables their use as regenerable solvents for acid gas capture. Unlike the other devices described in the prior art, the present invention takes advantage of shortened distances between the portions of the molecule that form hydrogen bonds within the structures when loaded with an acid gas so as to create a molecule with a higher internal bonding affinity and a reduced proclivity for agglomeration with other molecules.

Inventors:: Koech, Phillip K.; Malhotra, Deepika; Heldebrant, David J.; Glezakou, Vassiliki-Alexandra; Rousseau, Rober J.; Cantu, David C.

Issue Date:: 2018-11-20

Research Org.:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1495039

Patent Number(s):: 10130907

Application Number:: 15/410,523

Assignee:: BATTELLE MEMORIAL INSTITUTE (Richland, WA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

Show more

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2252/2041 - Diamines
B01D2252/20426 - Secondary amines
B01D2252/20431 - Tertiary amines
B01D2252/20457 - containing a pyridine-ring
B01D2257/302 - Sulfur oxides
B01D2257/308 - Carbonoxysulfide COS
B01D2257/504 - Carbon dioxide
B01D53/1425 - {Regeneration of liquid absorbents}
B01D53/1456 - {Removing acid components}
B01D53/1493 - {Selection of liquid materials for use as absorbents}

Show less

DOE Contract Number:: AC0576RL01830

Resource Type:: Patent

Resource Relation:: Patent File Date: 2017 Jan 19

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Koech, Phillip K., Malhotra, Deepika, Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Rober J., and Cantu, David C.. Capture and release of acid gasses using tunable organic solvents with aminopyridine.  United States: N. p., 2018. 
        Web.

Copy to clipboard


                    Koech, Phillip K., Malhotra, Deepika, Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Rober J., & Cantu, David C.. Capture and release of acid gasses using tunable organic solvents with aminopyridine.  United States.

Copy to clipboard


                    Koech, Phillip K., Malhotra, Deepika, Heldebrant, David J., Glezakou, Vassiliki-Alexandra, Rousseau, Rober J., and Cantu, David C.. Tue .  
        "Capture and release of acid gasses using tunable organic solvents with aminopyridine".  United States.  https://www.osti.gov/servlets/purl/1495039.

Copy to clipboard


                    
@article{osti_1495039,

  title        = {Capture and release of acid gasses using tunable organic solvents with aminopyridine},

  author       = {Koech, Phillip K. and Malhotra, Deepika and Heldebrant, David J. and Glezakou, Vassiliki-Alexandra and Rousseau, Rober J. and Cantu, David C.},

  abstractNote = {A class of water lean, organic solvents that can bind with various acid gasses to form acid gas bound molecules having a high degree of intramolecular hydrogen bonding which enables their use as regenerable solvents for acid gas capture. Unlike the other devices described in the prior art, the present invention takes advantage of shortened distances between the portions of the molecule that form hydrogen bonds within the structures when loaded with an acid gas so as to create a molecule with a higher internal bonding affinity and a reduced proclivity for agglomeration with other molecules.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {11}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Liquid absorbent for acidic gases and process of deacidification of a gas
patent, November 1994

Peytavy, Jean-Louis; Le Coz, Philippe; Oliveau, Olivier
US Patent Document 5,366,709
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5366709

The reaction of trimethylamine in liquid hydrogen sulphide: an electrical conductivity study
journal, June 1983

Halliday, James; Bindner, Patrick
Canadian Journal of Chemistry, Vol. 61, Issue 6, p. 1142-1145
https://doi.org/10.1139/v83-203

Equimolar CO₂ Absorption by Anion-Functionalized Ionic Liquids
journal, February 2010

Gurkan, Burcu E.; de la Fuente, Juan C.; Mindrup, Elaine M.
Journal of the American Chemical Society, Vol. 132, Issue 7, p. 2116-2117
https://doi.org/10.1021/ja909305t

Single component, reversible ionic liquids for energy applications
journal, June 2010

Blasucci, Vittoria; Hart, Ryan; Mestre, Veronica Llopis
Fuel, Vol. 89, Issue 6, p. 1315-1319
https://doi.org/10.1016/j.fuel.2009.11.015

Reversible Uptake of COS, CS₂, and SO₂: Ionic Liquids with O-Alkylxanthate, O-Alkylthiocarbonyl, and O-Alkylsulfite Anions
journal, August 2009

Heldebrant, David J.; Yonker, Clement R.; Jessop, Philip G.
Chemistry - A European Journal, Vol. 15, Issue 31, p. 7619-7627
https://doi.org/10.1002/chem.200802602

Removing hydrogen sulphide from a gas mixture
patent, September 1990

Van Baar, Johannes F.; Van Lith, Walterus J.
US Patent Document 4,959,086
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4959086

CO₂ -binding organic liquids (CO₂ BOLs) for post-combustion CO₂ capture
journal, February 2009

Heldebrant, David J.; Yonker, Clement R.; Jessop, Philip G.
Energy Procedia, Vol. 1, Issue 1, p. 1187-1195
https://doi.org/10.1016/j.egypro.2009.01.156

Capture and Release of Mixed Acid Gasses with Binding Organic Liquids
patent-application, May 2009

Heldebrant, David J.; Yonker, Clement R.
US Patent Application 12/360717; 20090136402
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090136402

Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures
journal, February 2008

Phan, Lam; Chiu, Daniel; Heldebrant, David J.
Industrial & Engineering Chemistry Research, Vol. 47, Issue 3, p. 539-545
https://doi.org/10.1021/ie070552r

Strong Hydrogen Bonds. III. Hydrogen Sulfide-Hydrosulfide Anion Interactions
journal, December 1966

McDaniel, Darl; Evans, Wilbur
Inorganic Chemistry, Vol. 5, Issue 12, p. 2180-2181
https://doi.org/10.1021/ic50046a022

Reversibly Switchable Surfactants and Methods of Use Thereof
patent-application, August 2008

Jessop, Philip G.
US Patent Application 11/599623; 20080197084
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080197084

A reversible zwitterionic SO₂-binding organic liquid
journal, January 2010

Heldebrant, David; Koech, Phillip; Yonker, Clement
Energy Environ. Sci., Vol. 3, Issue 1, p. 111-113
https://doi.org/10.1039/B916550A

Method of decarbonating a combustion fume with extraction of the solvent contained in the purified fume
patent, December 2008

Cadours, Renaud; Lecomte, Fabrice; Magna, Lionel
US Patent Document 7,459,134
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7459134

Process for the preparation of porous products based on cobalt fluoride or lead fluoride
patent, October 1985

Bergez, Pierre; Deguelte, Alain; Seigneurin, Laurent
US Patent Document 4,545,964
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4545964

Imidazolium-Methyl Sulfites for Use as Starting Compounds for Producing Ionic Liquids
patent-application, November 2007

Szarvas, Laszlo; Massonne, Klemens
US Patent Application 11/661306; 20070255064
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070255064

CO₂ Capture by a Task-Specific Ionic Liquid
journal, February 2002

Bates, Eleanor D.; Mayton, Rebecca D.; Ntai, Ioanna
Journal of the American Chemical Society, Vol. 124, Issue 6, p. 926-927
https://doi.org/10.1021/ja017593d

System and process for capture of H2S from gaseous process streams and process for regeneration of the capture agent
patent, February 2014

Heldebrant, David J.; Koech, Phillip K.; Rainbolt, James E.
US Patent Document 8,652,237
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8652237

Process of selective separation of hydrogen sulfide from gaseous mixtures containing also carbon dioxide
patent, October 1985

Gazzi, Luigi; Rescalli, Carlo; Scaramucci, Maria A.
US Patent Document 4,545,965
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4545965

Process for the Oxidation of Hydrogen Sulfide to Elementary Sulfur
patent, April 1973

Schulze, Gerhard; Heck, Wolfgang
US Patent Document 3725537
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3725537

Supercritical fluids as diluents in combustion of liquid fuels and waste materials
patent, December 1992

Nielsen, Kenneth A.
US Patent Document 5,170,727
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5170727

Antibacterial Agents
patent-application, May 2005

Thorarensen, Atli; Ruble, J. Craig; Romero, Donna Lee
US Patent Application 10/645732; 20050113450
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050113450

Shielding of Ionic Interactions by Sulfur Dioxide in an Ionic Liquid
journal, May 2008

Siqueira, Leonardo J. A.; Ando, Rômulo A.; Bazito, Fernanda F. C.
The Journal of Physical Chemistry B, Vol. 112, Issue 20
https://doi.org/10.1021/jp800665y

Using solvents for acidic gas removal
patent, December 1980

Hong, Charles C.
US Patent Document 4,238,206
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4238206

Switchable solvents and methods of use thereof
patent-application, March 2008

Jessop, Philip G.; Eckert, Charles A.; Liotta, Charles L.
US Patent Application 11/717172; 20080058549
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080058549

Desulfurization of Flue Gas: SO₂ Absorption by an Ionic Liquid
journal, April 2004

Wu, Weize; Han, Buxing; Gao, Haixiang
Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2415-2417
https://doi.org/10.1002/anie.200353437

Method for removing carbon dioxide from combustion exhaust gas
patent, March 2000

Yoshida, Kunihiko; Mimura, Tomio; Shimojo, Shigeru
US Patent Document 6,036,931
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6036931

Arylamine Substituted Bicyclic Heteroaromatic Compounds as p38 Kinase Inhibitors
patent-application, January 2006

Brookings, Daniel Christopher; Davis, Jeremy Martin; Langham, Barry John
US Patent Application 10/518725; 20060004025
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060004025

Methods of use of pyridylalkyl phenylthioureas
patent, September 1978

Callahan, William A.; Glenn, Eldridge Myles; Rector, Douglas L.
US Patent Document 4,112,100
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4112100

The use of the Fused Eutectic of Sodium Amide and Potassium Amide in Organic Syntheses
journal, May 1946

Bergstrom, F. W.; Sturz, H. G.; Tracy, H. W.
The Journal of Organic Chemistry, Vol. 11, Issue 3
https://doi.org/10.1021/jo01173a005

Functionalized Ionic Liquids, and Methods of Use Thereof
patent-application, May 2008

Davis, James Hillard
US Patent Application 11/789429; 20080112866
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080112866

Acid gas disposal method
patent-application, March 2003

Thomas, Eugene R.; Northrop, P. Scott; Hu, Hua
US Patent Application 10/234620; 20030047309
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030047309

Capture and Release of Acid-Gasses with Acid-Gas Binding Organic Compounds
patent-application, September 2009

Heldebrant, David J.; Yonker, Clement R.; Koech, Phillip K.
US Patent Application 12/427851; 20090220397
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090220397

Recovering sulfur from gas streams containing hydrogen sulfide
patent, September 1978

Atwood, Gilbert R.
US Patent Document 4,113,849
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4113849

Process for removal of nitrogen containing contaminants from gas oil feedstreams
patent-application, June 2004

Lesemann, Markus Friedrich Manfred; Setzer, Constance
US Patent Application 10/322614; 20040118749
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040118749

Methods for regenerating a sulfur scavenging compound from a product of a sulfur scavenging reaction
patent, September 1994

Trauffer, Edward A.; Evans, Robert D.
US Patent Document 5,347,003
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5347003

High CO₂ to Amine Adsorption Capacity CO₂ Scrubbing Processes
patent-application, March 2012

Kortunov, Pavel; Baugh, Lisa; Calabro, David
US Patent Application 13/228999; 20120063979
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120063979

A New Class of Single-Component Absorbents for Reversible Carbon Dioxide Capture under Mild Conditions
journal, November 2014

Barzagli, Francesco; Lai, Sarah; Mani, Fabrizio
ChemSusChem, Vol. 8, Issue 1, p. 184-191
https://doi.org/10.1002/cssc.201402421

Tuning ionic liquids for high gas solubility and reversible gas sorption
journal, January 2008

Huang, Jun; Riisager, Anders; Berg, Rolf W.
Journal of Molecular Catalysis A: Chemical, Vol. 279, Issue 2, p. 170-176
https://doi.org/10.1016/j.molcata.2007.07.036

Acidic gas absorbent, acidic gas removal device, and acidic gas removal method
patent-application, November 2012

Murai, Shinji; Saito, Satoshi; Kato, Yasuhiro
US Patent Application 13/519274; 20120294785
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120294785

Capture and release of mixed acid gasses with binding organic liquids
patent, September 2010

Heldebrant, David J.; Yonker, Clement R.
US Patent Document 7,799,299
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7799299

Process of scrubbing fuel synthesis gases to remove acid gases and organic sulfur compounds
patent, January 1979

Braizler, Karl; Doerges, Alexander
US Patent Document 4,137,294
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4137294

Efficient CO₂ absorption and low temperature desorption with non-aqueous solvents based on 2-amino-2-methyl-1-propanol (AMP)
journal, August 2013

Barzagli, Francesco; Mani, Fabrizio; Peruzzini, Maurizio
International Journal of Greenhouse Gas Control, Vol. 16, p. 217-223
https://doi.org/10.1016/j.ijggc.2013.03.026

Heterocyclic Compound Having Oxime Group
patent-application, October 2005

Yoshida, Ichiro; Suzuki, Shuichi
US Patent Application 11/047995; 20050227959
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050227959

Reactions of carbon dioxide and hydrogen sulfide with some alkanolamines
journal, January 1987

Maddox, Robert; Mains, Gilbert; Rahman, Mahmud
Industrial & Engineering Chemistry Research, Vol. 26, Issue 1, p. 27-31
https://doi.org/10.1021/ie00061a006

Process for nitrogen oxides reduction and minimization of the production of other pollutants
patent, May 1991

Epperly, William R.; Sullivan, James C.; Sprague, Barry N.
US Patent Document 5,017,347
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5017347

Solubility of Methane in Methyldiethanolamine
journal, July 2006

Jou, Fang-Yuan; Mather, Alan
Journal of Chemical & Engineering Data, Vol. 51, Issue 4, p. 1429-1430
https://doi.org/10.1021/je060118g

Process for treating gas with ultra-lean amine
patent, June 2000

Dingman, Jr., John Charles; Cummings, Arthur L.
US Patent Document 6,071,484
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6071484

Removing sulphur oxides from a fluid stream
patent, April 2014

Katz, Torsten; Riemann, Christian; Bartling, Karsten
US Patent Document 8,691,171
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8691171

Nitric Oxide Donors and Uses Thereof
patent-application, January 2007

Assaf, Peter; Gazaleen-Mariee, Elham; Naveh, Michael
US Patent Application 10/555664; 20070021382
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070021382

Improved Solvent Formulations for Efficient CO₂ Absorption and Low-Temperature Desorption
journal, July 2012

Barzagli, Francesco; Di Vaira, Massimo; Mani, Fabrizio
ChemSusChem, Vol. 5, Issue 9, p. 1724-1731
https://doi.org/10.1002/cssc.201200062

Switchable Surfactants
journal, August 2006

Liu, Y.
Science, Vol. 313, Issue 5789
https://doi.org/10.1126/science.1128142

Cyclic Amine Derivatives and Methods of Use
patent-application, October 2005

Groneberg, Robert D.; Zhan, James; Askew, Jr., Benny C.
US Patent Application 10/823372; 20050234044
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050234044

Green chemistry: Reversible nonpolar-to-polar solvent
journal, August 2005

Jessop, Philip G.; Heldebrant, David J.; Li, Xiaowang
Nature, Vol. 436, Issue 7054, p. 1102-1102
https://doi.org/10.1038/4361102a

Reversible Ionic Liquid Stabilized Carbamic Acids: A Pathway Toward Enhanced CO₂ Capture
journal, August 2013

Switzer, Jackson R.; Ethier, Amy L.; Flack, Kyle M.
Industrial & Engineering Chemistry Research, Vol. 52, Issue 36, p. 13159-13163
https://doi.org/10.1021/ie4018836

Removal Of Acid Gases By Means Of An Absorbent Comprising A Stripping Aid
patent-application, December 2010

Garcia Andarcia, Hugo Rafael; Notz, Ralf; Sieder, Georg
US Patent Application 12/819872; 20100319540
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100319540

Method of removing acidic gases from gaseous mixtures
patent, December 1964

Deal, Jr., Carl H.; Derr, Elwood L.; Papadopoulos, Michael N.
US Patent Document 3,161,461
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3161461

Methods and systems for deacidizing gaseous mixtures
patent, May 2010

Hu, Liang
US Patent Document 7,718,151
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7718151

Similar Records in DOE Patents and OSTI.GOV collections:

Capture and release of acid gasses using tunable organic solvents with aminopyridine

Patent Koech, Phillip K.; Malhotra, Deepika; Heldebrant, David J.; ...

A class of water lean, organic solvents that can bind with various acid gasses to form acid gas bound molecules having a high degree of intramolecular hydrogen bonding which enables their use as regenerable solvents for acid gas capture. Unlike the other devices described in the prior art, the present invention takes advantage of shortened distances between the portions of the molecule that form hydrogen bonds within the structures when loaded with an acid gas so as to create a molecule with a higher internal bonding affinity and a reduced proclivity for agglomeration with other molecules.
Full Text Available
Capture and release of acid gasses using tunable organic solvents with aminopyridine

Patent Koech, Phillip K.; Malhotra, Deepika; Heldebrant, David J.; ...

A class of water lean, organic solvents that can bind with various acid gasses to form acid gas bound molecules having a high degree of intramolecular hydrogen bonding which enables their use as regenerable solvents for acid gas capture. Unlike the other devices described in the prior art, the present invention takes advantage of shortened distances between the portions of the molecule that form hydrogen bonds within the structures when loaded with an acid gas so as to create a molecule with a higher internal bonding affinity and a reduced proclivity for agglomeration with other molecules.
Full Text Available
Capture and release of acid gasses using tunable organic solvents with aminopyridine

Patent Koech, Phillip K.; Malhotra, Deepika; Heldebrant, David J.; ...

A class of water lean, organic solvents that can bind with various acid gasses to form acid gas bound molecules having a high degree of intramolecular hydrogen bonding which enables their use as regenerable solvents for acid gas capture. Unlike the other devices described in the prior art, the present invention takes advantage of shortened distances between the portions of the molecule that form hydrogen bonds within the structures when loaded with an acid gas so as to create a molecule with a higher internal bonding affinity and a reduced proclivity for agglomeration with other molecules.
Full Text Available
Capture and release of acid gasses using tunable organic solvents with binding organic liquids

Patent Koech, Phillip K.; Malhotra, Deepika; Heldebrant, David J.; ...

A class of water lean, organic solvents that can bind with various acid gasses to form acid gas bound molecules having a high degree of intramolecular hydrogen bonding which enables their use as regenerable solvents for acid gas capture. Unlike the other devices described in the prior art, the present invention takes advantage of shortened distances between the portions of the molecule that form hydrogen bonds within the structures when loaded with an acid gas so as to create a molecule with a higher internal bonding affinity and a reduced proclivity for agglomeration with other molecules.
Full Text Available
Capture and release of acid-gasses with acid-gas binding organic compounds

Patent Heldebrant, David J; Yonker, Clement R; Koech, Phillip K

A system and method for acid-gas capture wherein organic acid-gas capture materials form hetero-atom analogs of alkyl-carbonate when contacted with an acid gas. These organic-acid gas capture materials include combinations of a weak acid and a base, or zwitterionic liquids. This invention allows for reversible acid-gas binding to these organic binding materials thus allowing for the capture and release of one or more acid gases. These acid-gas binding organic compounds can be regenerated to release the captured acid gasses and enable these organic acid-gas binding materials to be reused. This enables transport of the liquid capture compounds and the releasemore » « less
Full Text Available

Similar Records

Title: Capture and release of acid gasses using tunable organic solvents with aminopyridine

Abstract

Citation Formats

Liquid absorbent for acidic gases and process of deacidification of a gas patent, November 1994

The reaction of trimethylamine in liquid hydrogen sulphide: an electrical conductivity study journal, June 1983

Equimolar CO2 Absorption by Anion-Functionalized Ionic Liquids journal, February 2010

Single component, reversible ionic liquids for energy applications journal, June 2010

Reversible Uptake of COS, CS2, and SO2: Ionic Liquids with O-Alkylxanthate, O-Alkylthiocarbonyl, and O-Alkylsulfite Anions journal, August 2009

Removing hydrogen sulphide from a gas mixture patent, September 1990

CO2 -binding organic liquids (CO2 BOLs) for post-combustion CO2 capture journal, February 2009

Capture and Release of Mixed Acid Gasses with Binding Organic Liquids patent-application, May 2009

Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures journal, February 2008

Strong Hydrogen Bonds. III. Hydrogen Sulfide-Hydrosulfide Anion Interactions journal, December 1966

Reversibly Switchable Surfactants and Methods of Use Thereof patent-application, August 2008

A reversible zwitterionic SO2-binding organic liquid journal, January 2010

Method of decarbonating a combustion fume with extraction of the solvent contained in the purified fume patent, December 2008

Process for the preparation of porous products based on cobalt fluoride or lead fluoride patent, October 1985

Imidazolium-Methyl Sulfites for Use as Starting Compounds for Producing Ionic Liquids patent-application, November 2007

CO2 Capture by a Task-Specific Ionic Liquid journal, February 2002

System and process for capture of H2S from gaseous process streams and process for regeneration of the capture agent patent, February 2014

Process of selective separation of hydrogen sulfide from gaseous mixtures containing also carbon dioxide patent, October 1985

Process for the Oxidation of Hydrogen Sulfide to Elementary Sulfur patent, April 1973

Supercritical fluids as diluents in combustion of liquid fuels and waste materials patent, December 1992

Antibacterial Agents patent-application, May 2005

Shielding of Ionic Interactions by Sulfur Dioxide in an Ionic Liquid journal, May 2008

Using solvents for acidic gas removal patent, December 1980

Switchable solvents and methods of use thereof patent-application, March 2008

Desulfurization of Flue Gas: SO2 Absorption by an Ionic Liquid journal, April 2004

Method for removing carbon dioxide from combustion exhaust gas patent, March 2000

Arylamine Substituted Bicyclic Heteroaromatic Compounds as p38 Kinase Inhibitors patent-application, January 2006

Methods of use of pyridylalkyl phenylthioureas patent, September 1978

The use of the Fused Eutectic of Sodium Amide and Potassium Amide in Organic Syntheses journal, May 1946

Functionalized Ionic Liquids, and Methods of Use Thereof patent-application, May 2008

Acid gas disposal method patent-application, March 2003

Capture and Release of Acid-Gasses with Acid-Gas Binding Organic Compounds patent-application, September 2009

Recovering sulfur from gas streams containing hydrogen sulfide patent, September 1978

Process for removal of nitrogen containing contaminants from gas oil feedstreams patent-application, June 2004

Methods for regenerating a sulfur scavenging compound from a product of a sulfur scavenging reaction patent, September 1994

High CO2 to Amine Adsorption Capacity CO2 Scrubbing Processes patent-application, March 2012

A New Class of Single-Component Absorbents for Reversible Carbon Dioxide Capture under Mild Conditions journal, November 2014

Tuning ionic liquids for high gas solubility and reversible gas sorption journal, January 2008

Acidic gas absorbent, acidic gas removal device, and acidic gas removal method patent-application, November 2012

Capture and release of mixed acid gasses with binding organic liquids patent, September 2010

Process of scrubbing fuel synthesis gases to remove acid gases and organic sulfur compounds patent, January 1979

Efficient CO2 absorption and low temperature desorption with non-aqueous solvents based on 2-amino-2-methyl-1-propanol (AMP) journal, August 2013

Heterocyclic Compound Having Oxime Group patent-application, October 2005

Reactions of carbon dioxide and hydrogen sulfide with some alkanolamines journal, January 1987

Process for nitrogen oxides reduction and minimization of the production of other pollutants patent, May 1991

Solubility of Methane in Methyldiethanolamine journal, July 2006

Process for treating gas with ultra-lean amine patent, June 2000

Removing sulphur oxides from a fluid stream patent, April 2014

Nitric Oxide Donors and Uses Thereof patent-application, January 2007

Improved Solvent Formulations for Efficient CO2 Absorption and Low-Temperature Desorption journal, July 2012

Switchable Surfactants journal, August 2006

Cyclic Amine Derivatives and Methods of Use patent-application, October 2005

Green chemistry: Reversible nonpolar-to-polar solvent journal, August 2005

Reversible Ionic Liquid Stabilized Carbamic Acids: A Pathway Toward Enhanced CO2 Capture journal, August 2013

Removal Of Acid Gases By Means Of An Absorbent Comprising A Stripping Aid patent-application, December 2010

Method of removing acidic gases from gaseous mixtures patent, December 1964

Methods and systems for deacidizing gaseous mixtures patent, May 2010

Liquid absorbent for acidic gases and process of deacidification of a gas
patent, November 1994

The reaction of trimethylamine in liquid hydrogen sulphide: an electrical conductivity study
journal, June 1983

Equimolar CO₂ Absorption by Anion-Functionalized Ionic Liquids
journal, February 2010

Single component, reversible ionic liquids for energy applications
journal, June 2010

Reversible Uptake of COS, CS₂, and SO₂: Ionic Liquids with O-Alkylxanthate, O-Alkylthiocarbonyl, and O-Alkylsulfite Anions
journal, August 2009

Removing hydrogen sulphide from a gas mixture
patent, September 1990

CO₂ -binding organic liquids (CO₂ BOLs) for post-combustion CO₂ capture
journal, February 2009

Capture and Release of Mixed Acid Gasses with Binding Organic Liquids
patent-application, May 2009

Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures
journal, February 2008

Strong Hydrogen Bonds. III. Hydrogen Sulfide-Hydrosulfide Anion Interactions
journal, December 1966

Reversibly Switchable Surfactants and Methods of Use Thereof
patent-application, August 2008

A reversible zwitterionic SO₂-binding organic liquid
journal, January 2010

Method of decarbonating a combustion fume with extraction of the solvent contained in the purified fume
patent, December 2008

Process for the preparation of porous products based on cobalt fluoride or lead fluoride
patent, October 1985

Imidazolium-Methyl Sulfites for Use as Starting Compounds for Producing Ionic Liquids
patent-application, November 2007

CO₂ Capture by a Task-Specific Ionic Liquid
journal, February 2002

System and process for capture of H2S from gaseous process streams and process for regeneration of the capture agent
patent, February 2014

Process of selective separation of hydrogen sulfide from gaseous mixtures containing also carbon dioxide
patent, October 1985

Process for the Oxidation of Hydrogen Sulfide to Elementary Sulfur
patent, April 1973

Supercritical fluids as diluents in combustion of liquid fuels and waste materials
patent, December 1992

Antibacterial Agents
patent-application, May 2005

Shielding of Ionic Interactions by Sulfur Dioxide in an Ionic Liquid
journal, May 2008

Using solvents for acidic gas removal
patent, December 1980

Switchable solvents and methods of use thereof
patent-application, March 2008

Desulfurization of Flue Gas: SO₂ Absorption by an Ionic Liquid
journal, April 2004

Method for removing carbon dioxide from combustion exhaust gas
patent, March 2000

Arylamine Substituted Bicyclic Heteroaromatic Compounds as p38 Kinase Inhibitors
patent-application, January 2006

Methods of use of pyridylalkyl phenylthioureas
patent, September 1978

The use of the Fused Eutectic of Sodium Amide and Potassium Amide in Organic Syntheses
journal, May 1946

Functionalized Ionic Liquids, and Methods of Use Thereof
patent-application, May 2008

Acid gas disposal method
patent-application, March 2003

Capture and Release of Acid-Gasses with Acid-Gas Binding Organic Compounds
patent-application, September 2009

Recovering sulfur from gas streams containing hydrogen sulfide
patent, September 1978

Process for removal of nitrogen containing contaminants from gas oil feedstreams
patent-application, June 2004

Methods for regenerating a sulfur scavenging compound from a product of a sulfur scavenging reaction
patent, September 1994

High CO₂ to Amine Adsorption Capacity CO₂ Scrubbing Processes
patent-application, March 2012

A New Class of Single-Component Absorbents for Reversible Carbon Dioxide Capture under Mild Conditions
journal, November 2014

Tuning ionic liquids for high gas solubility and reversible gas sorption
journal, January 2008

Acidic gas absorbent, acidic gas removal device, and acidic gas removal method
patent-application, November 2012

Capture and release of mixed acid gasses with binding organic liquids
patent, September 2010

Process of scrubbing fuel synthesis gases to remove acid gases and organic sulfur compounds
patent, January 1979

Efficient CO₂ absorption and low temperature desorption with non-aqueous solvents based on 2-amino-2-methyl-1-propanol (AMP)
journal, August 2013

Heterocyclic Compound Having Oxime Group
patent-application, October 2005

Reactions of carbon dioxide and hydrogen sulfide with some alkanolamines
journal, January 1987

Process for nitrogen oxides reduction and minimization of the production of other pollutants
patent, May 1991

Solubility of Methane in Methyldiethanolamine
journal, July 2006

Process for treating gas with ultra-lean amine
patent, June 2000

Removing sulphur oxides from a fluid stream
patent, April 2014

Nitric Oxide Donors and Uses Thereof
patent-application, January 2007

Improved Solvent Formulations for Efficient CO₂ Absorption and Low-Temperature Desorption
journal, July 2012

Switchable Surfactants
journal, August 2006

Cyclic Amine Derivatives and Methods of Use
patent-application, October 2005

Green chemistry: Reversible nonpolar-to-polar solvent
journal, August 2005

Reversible Ionic Liquid Stabilized Carbamic Acids: A Pathway Toward Enhanced CO₂ Capture
journal, August 2013

Removal Of Acid Gases By Means Of An Absorbent Comprising A Stripping Aid
patent-application, December 2010

Method of removing acidic gases from gaseous mixtures
patent, December 1964

Methods and systems for deacidizing gaseous mixtures
patent, May 2010