Surface modifications for electrode compositions and their methods of making

Parans Paranthaman, Mariappan; Bridges, Craig A.; Yoon, Sukeun

Title: Surface modifications for electrode compositions and their methods of making

Abstract

Compositions and methods of making are provided for surface modified electrodes and batteries comprising the same. The compositions may comprise a base composition having an active material capable of intercalating the metal ions during a discharge cycle and deintercalating the metal ions during a charge cycle, wherein the active material is selected from the group consisting of LiCoO₂, LiMn₂O₄, Li₂MnO₃, LiNiO₂, LiMn_1.5Ni_0.5O₄, LiFePO₄, Li₂FePO₄F, Li₃CoNiMnO₆, Li(Li_aNi_xMn_yCo_z)O₂, Li_aMn_1.5-bNi_0.5-cM_dO_4-x, and mixtures thereof. The compositions may also comprise an annealed composition covering a portion of the base composition, formed by a reaction of the base composition in a reducing atmosphere. The methods of making comprise providing the base composition and annealing the base electrode in a reducing atmosphere.

Inventors:: Parans Paranthaman, Mariappan; Bridges, Craig A.; Yoon, Sukeun

Issue Date:: 2018-11-13

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1493595

Patent Number(s):: 10128489

Application Number:: 15/002,528

Assignee:: UT-BATTELLE, LLC (Oak Ridge, TN)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/625 - {Carbon or graphite}
H01M4/1397 - of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M2220/20 - Batteries in motive systems, e.g. vehicle, ship, plane
H01M4/0442 - {Anodisation, Oxidation

B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
B82Y30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/0471 - {involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis}
H01M4/0402 - {Methods of deposition of the material}
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M4/5825 - {Oxygenated metallic slats or polyanionic structures, e.g. borates, phosphates, silicates, olivines}
H01M2220/30 - Batteries in portable systems, e.g. mobile phone, laptop
H01M4/366 - {as layered products}
H01M2004/028 - {Positive electrodes}
H01M4/1391 - of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M2220/10 - Batteries in stationary systems, e.g. emergency power source in plant
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Jan 21

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Parans Paranthaman, Mariappan, Bridges, Craig A., and Yoon, Sukeun. Surface modifications for electrode compositions and their methods of making.  United States: N. p., 2018. 
        Web.

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                    Parans Paranthaman, Mariappan, Bridges, Craig A., & Yoon, Sukeun. Surface modifications for electrode compositions and their methods of making.  United States.

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                    Parans Paranthaman, Mariappan, Bridges, Craig A., and Yoon, Sukeun. Tue .  
        "Surface modifications for electrode compositions and their methods of making".  United States.  https://www.osti.gov/servlets/purl/1493595.

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@article{osti_1493595,

  title        = {Surface modifications for electrode compositions and their methods of making},

  author       = {Parans Paranthaman, Mariappan and Bridges, Craig A. and Yoon, Sukeun},

  abstractNote = {Compositions and methods of making are provided for surface modified electrodes and batteries comprising the same. The compositions may comprise a base composition having an active material capable of intercalating the metal ions during a discharge cycle and deintercalating the metal ions during a charge cycle, wherein the active material is selected from the group consisting of LiCoO2, LiMn2O4, Li2MnO3, LiNiO2, LiMn1.5Ni0.5O4, LiFePO4, Li2FePO4F, Li3CoNiMnO6, Li(LiaNixMnyCoz)O2, LiaMn1.5-bNi0.5-cMdO4-x, and mixtures thereof. The compositions may also comprise an annealed composition covering a portion of the base composition, formed by a reaction of the base composition in a reducing atmosphere. The methods of making comprise providing the base composition and annealing the base electrode in a reducing atmosphere.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {11}

}

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Works referenced in this record:

Research on Advanced Materials for Li-ion Batteries
journal, December 2009

Li, Hong; Wang, Zhaoxiang; Chen, Liquan
Advanced Materials, Vol. 21, Issue 45, p. 4593-4607
https://doi.org/10.1002/adma.200901710

Porous Li₄Ti₅O₁₂ Coated with N-Doped Carbon from Ionic Liquids for Li-Ion Batteries
journal, February 2011

Zhao, Liang; Hu, Yong-Sheng; Li, Hong
Advanced Materials, Vol. 23, Issue 11, p. 1385-1388
https://doi.org/10.1002/adma.201003294

Mesoporous TiO₂-B Microspheres with Superior Rate Performance for Lithium Ion Batteries
journal, July 2011

Liu, Hansan; Bi, Zhonghe; Sun, Xiao-Guang
Advanced Materials, Vol. 23, Issue 30, p. 3450-3454
https://doi.org/10.1002/adma.201100599

Superior cycle stability of nitrogen-doped graphene nanosheets as anodes for lithium ion batteries
journal, August 2011

Li, Xifei; Geng, Dongsheng; Zhang, Yong
Electrochemistry Communications, Vol. 13, Issue 8, p. 822-825
https://doi.org/10.1016/j.elecom.2011.05.012

Synthesis of pure phase disordered LiMn_1.45Cr_0.1Ni_0.45O₄ by a post-annealing method
journal, November 2012

Liu, D.; Hamel-Paquet, J.; Trottier, J.
Journal of Power Sources, Vol. 217, p. 400-406
https://doi.org/10.1016/j.jpowsour.2012.06.063

Towards understanding the effects of carbon and nitrogen-doped carbon coating on the electrochemical performance of Li₄Ti₅O₁₂ in lithium ion batteries: a combined experimental and theoretical study
journal, January 2011

Ding, Zijing; Zhao, Liang; Suo, Liumin
Physical Chemistry Chemical Physics, Vol. 13, Issue 33, p. 15127-15133
https://doi.org/10.1039/c1cp21513b

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