DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Advanced electrocatalysts for oxygen reduction reaction

Abstract

Provided are nanocomposites including an iron-based core and a nitrogen-doped graphitic carbon shell, and methods of making and using the same. Included in the nanocomposites is an Fe3C-based interlayer between the core and the shell. The nanocomposites can show a catalytic activity toward reducing oxygen comparable to commercial Pt/C catalysts.

Inventors:
;
Issue Date:
Research Org.:
UWM Research Foundation, Inc., Milwaukee, WI (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1493593
Patent Number(s):
10128510
Application Number:
14/173,430
Assignee:
UWM Research Foundation, Inc. (Milwaukee, WI)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
EE0003208
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Feb 05
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Chen, Junhong, and Wen, Zhenhai. Advanced electrocatalysts for oxygen reduction reaction. United States: N. p., 2018. Web.
Chen, Junhong, & Wen, Zhenhai. Advanced electrocatalysts for oxygen reduction reaction. United States.
Chen, Junhong, and Wen, Zhenhai. Tue . "Advanced electrocatalysts for oxygen reduction reaction". United States. https://www.osti.gov/servlets/purl/1493593.
@article{osti_1493593,
title = {Advanced electrocatalysts for oxygen reduction reaction},
author = {Chen, Junhong and Wen, Zhenhai},
abstractNote = {Provided are nanocomposites including an iron-based core and a nitrogen-doped graphitic carbon shell, and methods of making and using the same. Included in the nanocomposites is an Fe3C-based interlayer between the core and the shell. The nanocomposites can show a catalytic activity toward reducing oxygen comparable to commercial Pt/C catalysts.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 13 00:00:00 EST 2018},
month = {Tue Nov 13 00:00:00 EST 2018}
}

Works referenced in this record:

A Cytochrome c Oxidase Model Catalyzes Oxygen to Water Reduction Under Rate-Limiting Electron Flux
journal, March 2007


Formation mechanism of carbon-encapsulated iron nanorods in a co-carbonization process
journal, March 2011


Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction
journal, February 2009


Nanowire structures comprising carbon
patent-application, September 2007


Cyanamide-derived non-precious metal catalyst for oxygen reduction
journal, December 2010


Effect of oxidation and heat treatment on the morphology and electronic structure of carbon-encapsulated iron carbide nanoparticles
journal, July 2012


An Upflow Microbial Fuel Cell with an Interior Cathode:  Assessment of the Internal Resistance by Impedance Spectroscopy
journal, September 2006


Powering a wireless temperature sensor using sediment microbial fuel cells with vertical arrangement of electrodes
journal, November 2011


Non-conventional Fe3C-based nanostructures
journal, January 2011


On Active-Site Heterogeneity in Pyrolyzed Carbon-Supported Iron Porphyrin Catalysts for the Electrochemical Reduction of Oxygen:  An In Situ Mössbauer Study
journal, December 2002

  • Bouwkamp-Wijnoltz, A. L.; Visscher, W.; van Veen, J. A. R.
  • The Journal of Physical Chemistry B, Vol. 106, Issue 50, p. 12993-13001
  • https://doi.org/10.1021/jp0266087

Enhancement of Pt and Pt-alloy fuel cell catalyst activity and durability via nitrogen-modified carbon supports
journal, January 2010


Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
journal, September 2009


Enzymes as Working or Inspirational Electrocatalysts for Fuel Cells and Electrolysis
journal, July 2008


In Search of the Active Site in Nitrogen-Doped Carbon Nanotube Electrodes for the Oxygen Reduction Reaction
journal, August 2010


Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells
journal, April 2009


Designing PbSe Nanowires and Nanorings through Oriented Attachment of Nanoparticles
journal, May 2005


A class of non-precious metal composite catalysts for fuel cells
journal, September 2006


Nitrogen-Enriched Core-Shell Structured Fe/Fe3C-C Nanorods as Advanced Electrocatalysts for Oxygen Reduction Reaction
journal, February 2012


Synthesis and characterization of iron-impregnated porous carbon spheres prepared by ultrasonic spray pyrolysis
journal, February 2011


Oxygen reduction in nanoporous metal–ionic liquid composite electrocatalysts
journal, October 2010


A metal-free polymeric photocatalyst for hydrogen production from water under visible light
journal, November 2008


Synthesis of Ternary Metal Nitride Nanoparticles Using Mesoporous Carbon Nitride as Reactive Template
journal, November 2008


Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction
journal, August 2011


A New Fuel Cell Cathode Catalyst
journal, March 1964


High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
journal, April 2011


CoSe nanoparticles prepared by the microwave-assisted polyol method as an alcohol and formic acid tolerant oxygen reduction catalyst
journal, June 2010


Fe-g-C3N4 -Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light
journal, August 2009


From Carbon-Encapsulated Iron Nanorods to Carbon Nanotubes
journal, April 2008


Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011


Effect of Confinement in Carbon Nanotubes on the Activity of Fischer−Tropsch Iron Catalyst
journal, July 2008


Iron nanoparticles in carbon nanotubes at various temperatures
journal, April 2005


Synthesis and characterization of carbon-encapsulated iron/iron carbide nanoparticles by a detonation method
journal, November 2010


Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability
journal, January 2007


Low-platinum and platinum-free catalysts for the oxygen reduction reaction at fuel cell cathodes
journal, January 2011


Oxygen Reduction Catalysts for Polymer Electrolyte Fuel Cells from the Pyrolysis of Iron Acetate Adsorbed on Various Carbon Supports
journal, February 2003


Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries
journal, June 2011


Unraveling Oxygen Reduction Reaction Mechanisms on Carbon-Supported Fe-Phthalocyanine and Co-Phthalocyanine Catalysts in Alkaline Solutions
journal, November 2009


3-D Carbon Nanotube Structures Used as High Performance Catalyst for Oxygen Reduction Reaction
journal, November 2010


Graphene-Based Non-Noble-Metal Catalysts for Oxygen Reduction Reaction in Acid
journal, August 2011


Oxygen Reduction Activity of a Copper Complex of 3,5-Diamino-1,2,4-triazole Supported on Carbon Black
journal, November 2008


Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles
journal, March 2011


Molecular Oxygen Reduction in PEM Fuel Cells:  Evidence for the Simultaneous Presence of Two Active Sites in Fe-Based Catalysts
journal, August 2002


Nitrogen-Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction
journal, March 2010


Iron Carbide Nanoparticles Encapsulated in Mesoporous Fe–N-Doped Graphene-Like Carbon Hybrids as Efficient Bifunctional Oxygen Electrocatalysts
journal, September 2015


Structural transformation of carbon-encapsulated iron nanoparticles during heat treatment at 1000°C
journal, January 2007


MnO 2 -Based Nanostructures as Catalysts for Electrochemical Oxygen Reduction in Alkaline Media
journal, February 2010


Fe x O y @C Spheres as an Excellent Catalyst for Fischer−Tropsch Synthesis
journal, January 2010


Imperfect Oriented Attachment: Dislocation Generation in Defect-Free Nanocrystals
journal, August 1998


Mesoporous, 2D Hexagonal Carbon Nitride and Titanium Nitride/Carbon Composites
journal, November 2009


Electrochemical Reduction of Oxygen on Gold Nanoparticle-Electrodeposited Glassy Carbon Electrodes
journal, January 2003