Semi-solid electrodes with gel polymer additive
Abstract
Embodiments described herein relate generally to electrochemical cells having semi-solid electrodes that include a gel polymer additive such that the electrodes demonstrate longer cycle life while significantly retaining the electronic performance of the electrodes and the electrochemical cells formed therefrom. In some embodiments, a semi-solid electrode can include about 20% to about 75% by volume of an active material, about 0.5% to about 25% by volume of a conductive material, and about 20% to about 70% by volume of an electrolyte. The electrolyte further includes about 0.01% to about 1.5% by weight of a polymer additive. In some embodiments, the electrolyte can include about 0.1% to about 0.7% of the polymer additive.
- Inventors:
- Issue Date:
- Research Org.:
- 24M Technologies, Inc., Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1492811
- Patent Number(s):
- 10122044
- Application Number:
- 14/336,119
- Assignee:
- 24M Technologies, Inc. (Cambridge, MA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AR0000102
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Jul 21
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Tan, Taison, Ota, Naoki, and Disko, Jeffry. Semi-solid electrodes with gel polymer additive. United States: N. p., 2018.
Web.
Tan, Taison, Ota, Naoki, & Disko, Jeffry. Semi-solid electrodes with gel polymer additive. United States.
Tan, Taison, Ota, Naoki, and Disko, Jeffry. Tue .
"Semi-solid electrodes with gel polymer additive". United States. https://www.osti.gov/servlets/purl/1492811.
@article{osti_1492811,
title = {Semi-solid electrodes with gel polymer additive},
author = {Tan, Taison and Ota, Naoki and Disko, Jeffry},
abstractNote = {Embodiments described herein relate generally to electrochemical cells having semi-solid electrodes that include a gel polymer additive such that the electrodes demonstrate longer cycle life while significantly retaining the electronic performance of the electrodes and the electrochemical cells formed therefrom. In some embodiments, a semi-solid electrode can include about 20% to about 75% by volume of an active material, about 0.5% to about 25% by volume of a conductive material, and about 20% to about 70% by volume of an electrolyte. The electrolyte further includes about 0.01% to about 1.5% by weight of a polymer additive. In some embodiments, the electrolyte can include about 0.1% to about 0.7% of the polymer additive.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {11}
}
Works referenced in this record:
High Energy Density Redox Flow Device
patent-application, June 2014
- Carter, W. Craig; Chiang, Yet-Ming; Duduta, Mihai
- US Patent Application 14/002304; 20140154546
Systems and Methods for Series Battery Charging
patent-application, April 2016
- Taylor, Tony L.; Ota, Naoki; Tan, Taison
- US Patent Document 14/879599; 20160105042
Single Pouch Battery Cells and Methods of Manufacture
patent-application, January 2017
- Ota, Naoki; Fukushima, Takaaki; Bazzarella, Ricardo
- US Patent Document 15/185625; 20170025646
Fuel System Using Redox Flow Battery
patent-application, December 2010
- Chiang, Yet-Ming; Bazzarella, Ricardo
- US Patent Document 12/755379; 20100323264
Fuel system using redox flow battery
patent, July 2014
- Chiang, Yet-Ming; Bazzarella, Ricardo
- US Patent Document 8,778,552
Semi-solid electrodes having high rate capability
patent, July 2016
- Chiang, Yet-Ming; Duduta, Mihai; Holman, Richard K.
- US Patent Document 9,385,392
Gel polymer electrolyte and electrochemical device comprising the same
patent-application, December 2019
- Yu, Sung-Hoon; Cho, Jeong-Ju; Kim, Soo-Jin
- US Patent Application 12/310771; 20090317723
Semi-Solid Electrodes Having High Rate Capability
patent-application, February 2017
- Chiang, Yet-Ming; Duduta, Mihai; Holman, Richard
- US Patent Document 15/174172; 20170033390
Pre-Lithiation of Electrode Materials in a Semi-Solid Electrode
patent-application, May 2016
- Ota, Naoki; Duduta, Mihai; Fukushima, Takaaki
- US Patent Document 14/930991; 20160126543
Electrochemical cells and methods of manufacturing the same
patent, November 2015
- Bazzarella, Ricardo; Slocum, Alexander H.; Doherty, Tristan
- US Patent Document 9,178,200
Electrochemical cell having a pre-passivated electrode and associated fabrication process
patent-application, July 2002
- Fauteux, Denis G.; Kolb, Eric S.
- 09/981316; 20020086206
Optimum Electronic and Ionic Conductivity Ratios in Semi-Solid Electrodes
patent-application, January 2017
- Tan, Taison; Ota, Naoki; Woodford, William
- US Patent Document 15/013497; 20170025674
Dendrite-Inhibiting Additive for Battery Cell Having Zinc Electrode
patent, May 1972
- Rampel, Guy
- US Patent Document 3,660,170
Electrolyte for a lithium battery and a lithium battery and a lithium battery comprising the same
patent-application, March 2004
- Park, Yong-Chul; Jung, Won-II; Kim, Geun-Bae
- 10/656086; 20040048163
Methods for Electrochemical Cell Remediation
patent-application, December 2016
- Chiang, Yet-Ming; Woodford, William; Yu, Hiuling Zoe
- US Patent Document 15/186928; 20160372802
Asymmetric Battery Having A Semi-Solid Cathode And High Energy Density Anode
patent-application, October 2014
- Tan, Taison; Chiang, Yet-Ming; Ota, Naoki
- US Patent Application 14/202606; 20140315097
Stationary Semi-Solid Battery Module And Method Of Manufacture
patent-application, March 2013
- Slocum, Alexander; Doherty, Tristan; Bazzarella, Ricardo
- US Patent Application 13/607021; 20130055559
High energy density redox flow device
patent, October 2015
- Chiang, Yet-Ming; Carter, W. Craig; Duduta, Mihai
- US Patent Document 9,153,833
Electrochemical Slurry Compositions and Methods for Preparing the Same
patent-application, December 2013
- Doherty, Tristan; Limthongkul, Pimpa; Butros, Asli
- US Patent Document 13/832861; 20130337319
High Energy Density Redox Flow Device
patent-application, August 2011
- Carter, William; Chiang, Yet-Ming; Duduta, Mihai
- US Patent Application 12/970773; 20110189520
Semi-Solid Electrodes Having High Rate Capability
patent-application, February 2016
- Chiang, Yet-Ming; Duduta, Mihai; Holman, Richard
- US Patent Document 14/875076; 20160056491
Fuel system using redox flow battery
patent, March 2016
- Chiang, Yet-Ming; Bazzarella, Ricardo
- US Patent Document 9,293,781
Semi-Solid Electrodes Having High Rate Capability
patent-application, June 2014
- Chiang, Yet-Ming; Duduta, Mihai; Holman, Richard
- US Patent Application 13/872613; 20140170524
Semi-Solid Electrodes with Porous Current Collectors and Methods of Manufacture
patent-application, October 2016
- Ota, Naoki; Tan, Taison
- US Patent Document 15/097838; 20160308218
Semi-Solid Electrodes Having High Rate Capability
patent-application, February 2017
- Chiang, Yet-Ming; Duduta, Mihai; Holma, Richard
- US Patent Document 15/148048; 20170033389
Battery with an agent for converting hydrogen to water and a second agent for retaining formed water
patent, October 1977
- O'Nan, Thomas Charles; Ciliberti, Jr., Frank L.
- US Patent Document 4,054,727
Stacked Flow Cell Design And Method
patent-application, January 2014
- Slocum, Alexander; Bazzarella, Ricardo; Carter, William
- US Patent Application 13/915309; 20140004437
Energy Storage Modeling And Control
patent-application, February 2014
- Carter, W. Craig; Ferrara, Marco; Goroff, Michael
- US Patent Application 13/838014; 20140039710
High Energy Density Redox Flow Device
patent-application, September 2014
- Chiang, Yet-Ming; Carter, W. Craig; Duduta, Mihai
- US Patent Document 14/276723; 20140248521
Fuel System Using Redox Flow Battery
patent-application, May 2015
- Chiang, Yet-Ming; Bazzarella, Ricardo
- US Patent Application 14/306610; 20150129081
Electrochemical Cells Having Semi-Solid Electrodes and Methods of Manufacturing the Same
patent-application, May 2016
- Zagars, Raymond; Curhan, Jeffrey; Doherty, Tristan
- US Patent Document 14/932153; 20160133916
Electrochemical cells and methods of manufacturing the same
patent, July 2016
- Bazzarella, Ricardo; Slocum, Alexander H.; Doherty, Tristan
- US Patent Document 9,401,501
Stationary Semi-Solid Battery Module and Method of Manufacture
patent-application, June 2016
- Slocum, Alexander H.; Doherty, Tristan; Bazzarella, Ricardo
- US Patent Document 14/926760; 20160190544
Semi-Solid Electrode Cell Having A Porous Current Collector And Methods Of Manufacture
patent-application, March 2013
- Chiang, Yet-Ming; Carter, William; Cross, James
- US Patent Application 13/606986; 20130065122
Curved Battery Container
patent-application, May 2015
- Slocum, Alexander H.
- US Patent Document 14/513602; 20150140371
Semi-Solid Electrodes Having High Rate Capability
patent-application, February 2016
- Chiang, Yet-Ming; Dudata, Mihai; Holman, Richard
- US Patent Document 14/719566; 20160056490
High Energy Density Redox Flow Device
patent-application, February 2010
- Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan H.
- US Patent Document 12/484113; 20100047671
Semi-solid electrodes having high rate capability
patent, November 2015
- Chiang, Yet-Ming; Duduta, Mihai; Holman, Richard K.
- US Patent Document 9,184,464
Electrochemical slurry compositions and methods for preparing the same
patent, November 2016
- Doherty, Tristan; Limthongkul, Pimpa; Butros, Asli
- US Patent Document 9,484,569
Fuel System Using Redox Flow Battery
patent-application, January 2016
- Chiang, Yet-Ming; Bazzarella, Ricardo
- US Patent Document 14/824664; 20160013507
Mechanical Systems and Methods for Providing Edge Support and Protection in Semi-Solid Electrodes
patent-application, November 2016
- Ota, Naoki; Fukushima, Takaaki; Bazarella, Ricardo
- US Patent Document 15/157843; 20160344006
Electrochemical Cells and Methods of Manufacturing the Same
patent-application, November 2013
- Bazzarella, Ricardo; Slocum, Alexander H.; Doherty, Tristan
- US Patent Document 13/832836; 20130309547
Method for Preparing an Electrochemical Cell Having a Gel Electrolyte
patent-application, November 2011
- Zaghib, Karim; Kikuta, Manabu; Dontigay, Martin
- US Patent Application 12/921453; 20110287325
Stationary, Fluid Redox Electrode
patent-application, June 2012
- Chiang, Yet-Ming; Carter, W. Craig; Duduta, Mihai
- US Patent Document 13/212607; 20120164499
Semi-solid electrodes having high rate capability
patent, June 2016
- Chiang, Yet-Ming; Duduta, Mihai; Holman, Richard K.
- US Patent Document 9,362,583
Carboxymethyl cellulose-based binder material and lithium battery using the same
patent-application, April 2005
- Park, Jin-Hwan; Hwang, Seung-Sik
- US Patent Application 10/948679; 20050074669
High energy density redox flow device
patent, May 2014
- Chiang, Yet-Ming; Carter, William Craig; Duduta, Mihai
- US Patent Document 8,722,226
Semi-solid electrodes having high rate capability
patent, March 2015
- Chiang, Yet-Ming; Duduta, Mihai; Holman, Richard K.
- US Patent Document 8,993,159
High energy density redox flow device
patent, May 2014
- Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan Y.
- US Patent Document 8,722,227
Electrochemical Cells and Methods of Manufacturing the Same
patent-application, June 2015
- Bazzarella, Ricardo; Slocum, Alexander H.; Doherty, Tristan
- US Patent Document 14/543489; 20150171406
Fuel System Using Redox Flow Battery
patent-application, September 2016
- Chiang, Yet-Ming; Bazzarella, Ricardo
- US Patent Document 15/045718; 20160268621
High Energy Density Redox Flow Device
patent-application, August 2011
- Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan
- US Patent Application 12/970753; 20110200848
Damage Tolerant Batteries
patent-application, October 2015
- Chiang, Yet-Ming; Tan, Taison; Disko, Jeffry
- US Patent Document 14/682417; 20150295272
High Energy Density Redox Flow Device
patent-application, July 2016
- Chiang, Yet-Ming; Carter, W. Craig; Duduta, Mihai
- US Patent Document 14/840810; 20160218375
Asymmetric Battery Having a Semi-Solid Cathode and High Energy Density Anode
patent-application, January 2017
- Tan, Taison; Chiang, Yet-Ming; Ota, Naoki
- US Patent Document 15/228259; 20170018798
Semi-Solid Electrodes Having High Rate Capability
patent-application, October 2015
- Chiang, Yet-Ming; Duduta, Mihai; Holman, Richard
- US Patent Document 14/597869; 20150280267
Energy Transfer Using Electrochemically Isolated Fluids
patent-application, November 2011
- Duduta, Mihai; Carter, W. Craig; Chiang, Yet-Ming
- US Patent Document 13/083167; 20110274948
Stationary semi-solid battery module and method of manufacture
patent, December 2015
- Slocum, Alexander H.; Doherty, Tristan; Bazzarella, Ricardo
- US Patent Document 9,203,092
Porous Semi-Solid Electrode and Methods of Manufacturing the Same
patent-application, December 2015
- Holman, Richard; Ota, Naoki
- US Patent Document 14/732298; 20150357626
Electrolyte for lithium secondary battery and lithium secondary battery comprising same
patent-application, January 2005
- Yamiguchi, Takitaro; Shimizu, Ryuichi; Chung, Hyun-Jei
- 10/891233; 20050014072
Asymmetric battery having a semi-solid cathode and high energy density anode
patent, September 2016
- Tan, Taison; Chiang, Yet-Ming; Ota, Naoki
- US Patent Document 9,437,864
Semi-Solid Filled Battery And Method Of Manufacture
patent-application, January 2014
- Chiang, Yet-Ming; Carter, William; Limthongkul, Pimpa
- US Patent Application 13/915312; 20140030623