Aluminum-based metal-air batteries

Friesen, Cody A.; Martinez, Jose Antonio Bautista

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Title: Aluminum-based metal-air batteries

Abstract

Provided in one embodiment is an electrochemical cell, comprising: (i) a plurality of electrodes, comprising a fuel electrode that comprises aluminum and an air electrode that absorbs gaseous oxygen, the electrodes being operable in a discharge mode wherein the aluminum is oxidized at the fuel electrode and oxygen is reduced at the air electrode, and (ii) an ionically conductive medium, comprising an organic solvent; wherein during non-use of the cell, the organic solvent promotes formation of a protective interface between the aluminum of the fuel electrode and the ionically conductive medium, and wherein at an onset of the discharge mode, at least some of the protective interface is removed from the aluminum to thereafter permit oxidation of the aluminum during the discharge mode.

Inventors:: Friesen, Cody A.; Martinez, Jose Antonio Bautista

Issue Date:: 2018-10-02

Research Org.:: US Department of Energy (USDOE), Washington, DC (United States). Advanced Research Projects Agency-Energy (ARPA-E)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1489035

Patent Number(s):: 10090520

Application Number:: 14/958,270

Assignee:: ARIZONA BOARD OF REGENTS ACTING FOR AND ON BEHALF OF ARIZONA STATE UNIVERSITY (Tempe, AZ)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M12/02 - Details
H01M12/06 - with one metallic and one gaseous electrode
H01M12/08 - composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
H01M2300/0002 - Aqueous electrolytes
H01M2300/0028 - characterised by the solvent
H01M4/38 - of elements or alloys

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T29/49108 - Electric battery cell making

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DOE Contract Number:: AR-00000038

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Dec 03

Country of Publication:: United States

Language:: English

Citation Formats


                    Friesen, Cody A., and Martinez, Jose Antonio Bautista. Aluminum-based metal-air batteries.  United States: N. p., 2018. 
        Web.

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                    Friesen, Cody A., & Martinez, Jose Antonio Bautista. Aluminum-based metal-air batteries.  United States.

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                    Friesen, Cody A., and Martinez, Jose Antonio Bautista. Tue .  
        "Aluminum-based metal-air batteries".  United States.  https://www.osti.gov/servlets/purl/1489035.

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@article{osti_1489035,

  title        = {Aluminum-based metal-air batteries},

  author       = {Friesen, Cody A. and Martinez, Jose Antonio Bautista},

  abstractNote = {Provided in one embodiment is an electrochemical cell, comprising: (i) a plurality of electrodes, comprising a fuel electrode that comprises aluminum and an air electrode that absorbs gaseous oxygen, the electrodes being operable in a discharge mode wherein the aluminum is oxidized at the fuel electrode and oxygen is reduced at the air electrode, and (ii) an ionically conductive medium, comprising an organic solvent; wherein during non-use of the cell, the organic solvent promotes formation of a protective interface between the aluminum of the fuel electrode and the ionically conductive medium, and wherein at an onset of the discharge mode, at least some of the protective interface is removed from the aluminum to thereafter permit oxidation of the aluminum during the discharge mode.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {10}

}

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Similar Records

Title: Aluminum-based metal-air batteries

Abstract

Citation Formats

Electrolyte for aluminum electrolytic capacitor patent, September 1988

Metal/air battery with seeded recirculating electrolyte patent, November 1993

Secondary battery with nonaqueous electrolyte and method of manufacturing same patent, May 1994

Secondary battery patent, May 1997

Electrolytic solution for electrolytic capacitor and electrolytic capacitor using the same patent, September 2001

Ion conductive laminate and production method and use thereof patent, October 2001

Electrolytic capacitor patent, February 2002

Electrolyte for very high voltage electrolytic capacitors patent, November 2003

Non-aqueous electrolytes for lithium electrochemical cells patent, February 2005

Methods for increased removal of drag reducer additives from liquid hydrocarbon fuel patent, April 2008

Non-aqueous electrolyte secondary battery and electrolyte for the same patent, May 2010

Lithium secondary cell and its nonaqueous electrolyte patent, August 2010

Electrochemical cell, and particularly a metal fueled cell with non-parallel flow patent, May 2012

Efficient dual source battery pack system for an electric vehicle patent, May 2012

Efficient dual source battery pack system for an electric vehicle patent, May 2012

Electrochemical cell, and particularly a cell with electrodeposited fuel patent, November 2012

Metal air battery including a composite anode patent, December 2013

Lactone Solvents For Electrochemical Cells patent-application, April 2002

Electrodes comprising mixed active particles patent-application, October 2004

Alkali Metal Air Battery patent-application, September 2009

Electrochemical cell, and particularly a cell with electrodeposited fuel patent-application, November 2009

Oxygen Recovery System and Method for Recovering Oxygen in an Electrochemical Cell patent-application, May 2010

Metal-Air Low Temperature Ionic Liquid Cell patent-application, November 2010

Electrochemical Cells Connected in Fluid Flow Series patent-application, December 2010

Electrochemical cell, and particularly a metal fueled cell with non-parallel flow patent-application, February 2011

Rechargeable Electrochemical Cell System with a Charging Electrode Charge/Discharge Mode Switching in the Cells patent-application, March 2011

Electrochemical Cell with Flow Management System patent-application, April 2011

Lithium-Ion Secondary Battery, Anode For Lithium-Ion Secondary Battery, Power Tool, Electric Vehicle And Energy Storage System patent-application, June 2011

Operation System For Providing Backup Batteries For Hybrid Vehicles And/Or Electric Vehicles And Method Thereof patent-application, July 2011

Manufacturing Methods For Air Electrode patent-application, September 2011

Power Supply System For Electrically Powered Vehicle And Method For Controlling The Same patent-application, October 2011

Metal-Air Cell With Performance Enhancing Additive patent-application, November 2011

High Energy Density Aluminum Battery patent-application, April 2012

Air Battery and Air Battery Pack patent-application, December 2012

The effect of water on the anodic dissolution of aluminum in non-aqueous electrolytes journal, May 2000

Electrodeposition of aluminium from ionic liquids: Part II - studies on the electrodeposition of aluminum from aluminum chloride (AICl3) - trimethylphenylammonium chloride (TMPAC) ionic liquids journal, September 2006

In Situ Stress Measurements during Aluminum Deposition from AlCl[sub 3]-EtMeImCl Ionic Liquid journal, January 2006

Electrodeposition Studies of Aluminum on Tungsten Electrode from DMSO[sub 2] Electrolytes journal, January 1994

Behaviour of aluminium as anode in dimethylsulfone-based electrolytes journal, July 1994

Sulfone-based electrolytes for aluminum electrodeposition journal, August 1995

Effects of trifluoroethanol as a co-solvent on the electrochemical oxidation of hardly oxidizable organic compounds journal, July 2001

A solar-hydrogen economy for U.S.A. journal, January 1983

21st Century’s energy: Hydrogen energy system journal, July 2008

Solution Activators of Aluminum Electrochemistry in Organic Media journal, January 2000

Electrochemical properties of aluminum anodes in gel electrolyte-based aluminum-air batteries journal, December 2008

Electrodeposition of Al in 1-Butyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)amide and 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)amide Ionic Liquids: In Situ STM and EQCM Studies † journal, May 2007

Electrodeposition of Nano- and Microcrystalline Aluminium in Three Different Air and Water Stable Ionic Liquids journal, June 2006

Aluminum as anode for energy storage and conversion: a review journal, July 2002

Hydrogen Redox in Protic Ionic Liquids and a Direct Measurement of Proton Thermodynamics journal, June 2009

Electrolyte for aluminum electrolytic capacitor
patent, September 1988

Metal/air battery with seeded recirculating electrolyte
patent, November 1993

Secondary battery with nonaqueous electrolyte and method of manufacturing same
patent, May 1994

Secondary battery
patent, May 1997

Electrolytic solution for electrolytic capacitor and electrolytic capacitor using the same
patent, September 2001

Ion conductive laminate and production method and use thereof
patent, October 2001

Electrolytic capacitor
patent, February 2002

Electrolyte for very high voltage electrolytic capacitors
patent, November 2003

Non-aqueous electrolytes for lithium electrochemical cells
patent, February 2005

Methods for increased removal of drag reducer additives from liquid hydrocarbon fuel
patent, April 2008

Non-aqueous electrolyte secondary battery and electrolyte for the same
patent, May 2010

Lithium secondary cell and its nonaqueous electrolyte
patent, August 2010

Electrochemical cell, and particularly a metal fueled cell with non-parallel flow
patent, May 2012

Efficient dual source battery pack system for an electric vehicle
patent, May 2012

Efficient dual source battery pack system for an electric vehicle
patent, May 2012

Electrochemical cell, and particularly a cell with electrodeposited fuel
patent, November 2012

Metal air battery including a composite anode
patent, December 2013

Lactone Solvents For Electrochemical Cells
patent-application, April 2002

Electrodes comprising mixed active particles
patent-application, October 2004

Alkali Metal Air Battery
patent-application, September 2009

Electrochemical cell, and particularly a cell with electrodeposited fuel
patent-application, November 2009

Oxygen Recovery System and Method for Recovering Oxygen in an Electrochemical Cell
patent-application, May 2010

Metal-Air Low Temperature Ionic Liquid Cell
patent-application, November 2010

Electrochemical Cells Connected in Fluid Flow Series
patent-application, December 2010

Electrochemical cell, and particularly a metal fueled cell with non-parallel flow
patent-application, February 2011

Rechargeable Electrochemical Cell System with a Charging Electrode Charge/Discharge Mode Switching in the Cells
patent-application, March 2011

Electrochemical Cell with Flow Management System
patent-application, April 2011

Lithium-Ion Secondary Battery, Anode For Lithium-Ion Secondary Battery, Power Tool, Electric Vehicle And Energy Storage System
patent-application, June 2011

Operation System For Providing Backup Batteries For Hybrid Vehicles And/Or Electric Vehicles And Method Thereof
patent-application, July 2011

Manufacturing Methods For Air Electrode
patent-application, September 2011

Power Supply System For Electrically Powered Vehicle And Method For Controlling The Same
patent-application, October 2011

Metal-Air Cell With Performance Enhancing Additive
patent-application, November 2011

High Energy Density Aluminum Battery
patent-application, April 2012

Air Battery and Air Battery Pack
patent-application, December 2012

The effect of water on the anodic dissolution of aluminum in non-aqueous electrolytes
journal, May 2000

Electrodeposition of aluminium from ionic liquids: Part II - studies on the electrodeposition of aluminum from aluminum chloride (AICl₃) - trimethylphenylammonium chloride (TMPAC) ionic liquids
journal, September 2006

In Situ Stress Measurements during Aluminum Deposition from AlCl[sub 3]-EtMeImCl Ionic Liquid
journal, January 2006

Electrodeposition Studies of Aluminum on Tungsten Electrode from DMSO[sub 2] Electrolytes
journal, January 1994

Behaviour of aluminium as anode in dimethylsulfone-based electrolytes
journal, July 1994

Sulfone-based electrolytes for aluminum electrodeposition
journal, August 1995

Effects of trifluoroethanol as a co-solvent on the electrochemical oxidation of hardly oxidizable organic compounds
journal, July 2001

A solar-hydrogen economy for U.S.A.
journal, January 1983

21st Century’s energy: Hydrogen energy system
journal, July 2008

Solution Activators of Aluminum Electrochemistry in Organic Media
journal, January 2000

Electrochemical properties of aluminum anodes in gel electrolyte-based aluminum-air batteries
journal, December 2008

Electrodeposition of Al in 1-Butyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)amide and 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)amide Ionic Liquids: In Situ STM and EQCM Studies ^†
journal, May 2007

Electrodeposition of Nano- and Microcrystalline Aluminium in Three Different Air and Water Stable Ionic Liquids
journal, June 2006

Aluminum as anode for energy storage and conversion: a review
journal, July 2002

Hydrogen Redox in Protic Ionic Liquids and a Direct Measurement of Proton Thermodynamics
journal, June 2009