Title: Solid-state three-dimensional battery assembly

Abstract

A solid-state three-dimensional battery assembly includes a solid bicontinuous monolithic carbon anode, a solid electrolyte layer, and a solid cathode. The solid monolithic carbon anode has an ordered three-dimensionally continuous network nanostructure, a length of at least 100 nm, and an average thickness of 3 to 90 nm. The ordered three-dimensionally continuous network nanostructure of the anode defines a plurality of pores having an average diameter of 5 to 100 nm. The solid electrolyte layer is disposed directly on the anode, has an average thickness of 3 to 90 nm, and fills a portion of the pores defined by the ordered three-dimensionally continuous network nanostructure of the anode. The solid cathode is disposed directly on the electrolyte layer, has an average thickness of 3 to 90 nm, and also fills a portion of the pores defined by the ordered three-dimensionally continuous network nanostructure of the anode. Related devices and methods are also provided.

Inventors:

Wiesner, Ulrich; Werner, Joerg G.; Abruna, Hector D.; Rodriguez-Caler, Gabriel

Issue Date:

Tue Oct 16 00:00:00 EDT 2018

Research Org.:

Cornell Univ., Ithaca, NY (United States)

Sponsoring Org.:

USDOE

OSTI Identifier:

1487260

Patent Number(s):

10103408

Application Number:

15/753,820

Assignee:

Cornell University (Ithaca, NY)

Patent Classifications (CPCs):

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M10/052 - Li-accumulators
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M10/058 - Construction or manufacture
H01M10/0585 - of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M2004/021 - {Physical characteristics, e.g. porosity, surface area}
H01M2004/027 - {Negative electrodes}
H01M2220/30 - Batteries in portable systems, e.g. mobile phone, laptop
H01M2300/0082 - Organic polymers
H01M4/0407 - {by coating on an electrolyte layer}
H01M4/0471 - {involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis}
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/133 - Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/137 - Electrodes based on electro-active polymers
H01M4/1393 - of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M4/38 - of elements or alloys
H01M4/587 - for inserting or intercalating light metals
H01M4/602 - {Polymers}
H01M4/66 - Selection of materials

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Y02E60/10 - Energy storage

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

Y02P70/50 - Manufacturing or production processes characterised by the final manufactured product

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DOE Contract Number:  

SC0001086; SC0010560

Resource Type:

Patent

Resource Relation:

Patent File Date: 2016 Aug 26

Country of Publication:

United States

Language:

English

Subject:

25 ENERGY STORAGE; 42 ENGINEERING