Production of 1,5-pentanediol via upgrading of tetrahydrofurfuryl alcohol
Abstract
A method of making 1,5-pentanediol from tetrahydrofurfural alcohol. The method includes the steps of dehydrating tetrahydrofurfural alcohol (THFA) to dihydropyran (DHP); hydrating at least a portion of the DHP to 2-hydroxy-tetrahydropyran (2-HY-THP) in the presence of a solid acid catalyst; and hydrogenating at least a portion of the 2-HY-THP to 1,5-pentanediol. The method can be conducted entirely in the absence of noble metal catalysts.
- Inventors:
- Issue Date:
- Research Org.:
- Wisconsin Alumni Research Foundation, Madison, WI (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1483644
- Patent Number(s):
- 10077224
- Application Number:
- 15/782,593
- Assignee:
- Wisconsin Alumni Research Foundation (Madison, WI)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- EE0006878
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2017 Oct 12
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Huber, George Willis, Dumesic, James A., and Barnett, Kevin J. Production of 1,5-pentanediol via upgrading of tetrahydrofurfuryl alcohol. United States: N. p., 2018.
Web.
Huber, George Willis, Dumesic, James A., & Barnett, Kevin J. Production of 1,5-pentanediol via upgrading of tetrahydrofurfuryl alcohol. United States.
Huber, George Willis, Dumesic, James A., and Barnett, Kevin J. Tue .
"Production of 1,5-pentanediol via upgrading of tetrahydrofurfuryl alcohol". United States. https://www.osti.gov/servlets/purl/1483644.
@article{osti_1483644,
title = {Production of 1,5-pentanediol via upgrading of tetrahydrofurfuryl alcohol},
author = {Huber, George Willis and Dumesic, James A. and Barnett, Kevin J.},
abstractNote = {A method of making 1,5-pentanediol from tetrahydrofurfural alcohol. The method includes the steps of dehydrating tetrahydrofurfural alcohol (THFA) to dihydropyran (DHP); hydrating at least a portion of the DHP to 2-hydroxy-tetrahydropyran (2-HY-THP) in the presence of a solid acid catalyst; and hydrogenating at least a portion of the 2-HY-THP to 1,5-pentanediol. The method can be conducted entirely in the absence of noble metal catalysts.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {9}
}
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Works referenced in this record:
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