Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons

Long, Jeffrey R.; Xiao, Dianne J.

Title: Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons

Abstract

The disclosure provides for metal organic frameworks (MOFs) which comprise a plurality of redox-active metals or metal ions that are linked together by a plurality of dioxide-benzenedicarboxylate-based organic linking ligands. The disclosure further provides for the use of these MOFs in variety of applications, including catalyzing the oxidization of various hydrocarbons to higher oxidation states.

Inventors:: Long, Jeffrey R.; Xiao, Dianne J.

Issue Date:: 2018-08-28

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1478746

Patent Number(s):: 10058855

Application Number:: 15/153,997

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

Show more

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2231/70 - Oxidation reactions, e.g. epoxidation,
B01J2531/22 - Magnesium
B01J2531/26 - Zinc
B01J2531/842 - Iron
B01J31/1691 - {Coordination polymers, e.g. metal-organic frameworks [MOF]
B01J31/2239 - {Bridging ligands, e.g. OAc in Cr2

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C29/48 - by oxidation reactions with formation of hydroxy groups
C07C35/08 - containing a six-membered rings
C07C45/28 - of CHx-moieties
C07C45/33 - of CHx-moieties
C07C49/403 - of a six-membered ring
C07C65/05 - o-Hydrocy carboxylic acids

Show less

DOE Contract Number:: AC02-05CH11231; SC0008688

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 May 13

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Long, Jeffrey R., and Xiao, Dianne J. Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons.  United States: N. p., 2018. 
        Web.

Copy to clipboard


                    Long, Jeffrey R., & Xiao, Dianne J. Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons.  United States.

Copy to clipboard


                    Long, Jeffrey R., and Xiao, Dianne J. Tue .  
        "Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons".  United States.  https://www.osti.gov/servlets/purl/1478746.

Copy to clipboard


                    
@article{osti_1478746,

  title        = {Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons},

  author       = {Long, Jeffrey R. and Xiao, Dianne J.},

  abstractNote = {The disclosure provides for metal organic frameworks (MOFs) which comprise a plurality of redox-active metals or metal ions that are linked together by a plurality of dioxide-benzenedicarboxylate-based organic linking ligands. The disclosure further provides for the use of these MOFs in variety of applications, including catalyzing the oxidization of various hydrocarbons to higher oxidation states.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {8}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Adsorption process with on-line adsorbent removal
patent-application, November 2006

Pilliod, Dana Lynn; Randall, Katy Conley; Harding, Eric Martin
US Patent Application 11/122312; 20060252972
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060252972

Crystallography of metal–organic frameworks
journal, October 2014

Gándara, Felipe; Bennett, Thomas D.
IUCrJ, Vol. 1, Issue 6, p. 563-570
https://doi.org/10.1107/S2052252514020351

Process for preparing an organometallic framework material
patent-application, July 2005

Muller, Ulrich; Lippert, Gerald; Schubert, Olga
US Patent Application 10/755231; 20050154222
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050154222

Covalently linked organic frameworks and polyhedra
patent, September 2009

Yaghi, Omar M.; Matzger, Adam J.; Benin, Annabelle I.
US Patent Document 7,582,798
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7582798

Fluorinated metal-organic frameworks for gas storage
patent, January 2013

Omary, Mohammad A.; Yang, Chi
US Patent Document 8,343,260
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8343260

Gas storage system
patent-application, December 2004

Muller, Ulrich; Hesse, Michael; Hess, Reinhard
US Patent Application 10/608146; 20040265670
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040265670

Process for preparing hydrogen peroxide from the elements
patent-application, March 2006

Muller, Ulrich; Metelkina, Olga; Junicke, Henrik
US Patent Application 11/258265; 20060057057
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060057057

1,2,3-triazole based metal-organic framework as photo-active materials
patent-application, November 2011

Shi, Xiaodong
US Patent Document 13/068489; 20110282071
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110282071

Metal−Organic Frameworks As Templates for Nanoscale NaAlH₄
journal, September 2009

Bhakta, Raghunandan K.; Herberg, Julie L.; Jacobs, Benjamin
Journal of the American Chemical Society, Vol. 131, Issue 37, p. 13198-13199
https://doi.org/10.1021/ja904431x

Donor-acceptor rotaxanes with tetracationic cyclophane ring
journal, September 2012

Deska, Malgorzata; Nowik-Zajac, Anna; Sliwa, Wanda
Arkivoc, Vol. 2013, Issue 1, p. 185-242
https://doi.org/10.3998/ark.5550190.0014.107

PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS
patent-application, August 2007

Yaghi, Omar M.; Hayashi, Hideki; Banerjee, Rahul
US Patent Application 11/680386; 20070202038
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070202038

Bone graft composition
patent-application, October 2007

Connor, Jerome; Qiu, Qing-Qing
US Patent Application 11/407446; 20070248575
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070248575

Two new metal–triazole-benzenedicarboxylate frameworks affording an uncommon 3,4-connected net and unique 4,6-connected rod packing: hydrothermal synthesis, structure, thermostability and luminescence studies
journal, January 2009

Luo, Feng; Che, Yun-xia; Zheng, Ji-min
CrystEngComm, Vol. 11, Issue 6, p. 1097-1102
https://doi.org/10.1039/b812479e

Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent, October 2007

Mueller, Ulrich; Stoesser, Michael; Ruppel, Raimund
US Patent Document 7,279,517
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7279517

Air Collector with Functionalized Ion Exchange Membrane for Capturing Ambient CO₂
patent-application, September 2007

Wright, Allen B.; Peters, Eddy J.
US Patent Document 11/683824; 20070217982
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070217982

Gas storage system
patent, December 2007

Müller, Ulrich; Hesse, Michael; Heβ, Reinhard
US Patent Document 7,309,380
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7309380

Covalently linked organic frameworks and polyhedra
patent-application, July 2006

Yaghi, Omar M.; Matzger, Adam J.; Benin, Annabelle
US Patent Application 11/256859; 20060154807
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060154807

Strong CO₂ Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
journal, July 2009

Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin
Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786
https://doi.org/10.1021/ja903411w

Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide
journal, January 2009

Dietzel, Pascal D. C.; Besikiotis, Vasileios; Blom, Richard
Journal of Materials Chemistry, Vol. 19, Issue 39, p. 7362-7370
https://doi.org/10.1039/b911242a

Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature
patent-application, March 2007

Yaghi, Omar M.
US Patent Application 11/527232; 20070068389
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070068389

Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
journal, October 2007

Côté, Adrien P.; El-Kaderi, Hani M.; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 129, Issue 43, p. 12914-12915
https://doi.org/10.1021/ja0751781

Metal catalyzed reactions
patent, February 2004

Zhang, Xumu; Lei, Aiwen
US Patent Document 6,686,428
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6686428

CH₄ storage and CO₂ capture in highly porous zirconium oxide based metal–organic frameworks
journal, January 2012

Yang, Qingyuan; Guillerm, Vincent; Ragon, Florence
Chemical Communications, Vol. 48, Issue 79, p. 9831-9833
https://doi.org/10.1039/c2cc34714h

Preparation of metal-containing zeolite catalysts of increased stability and activity
patent, July 1985

Tsao, Ying-Yen P.; Wong, Stephen S.
US Patent Document 4,532,225
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4532225

Metal organic framework—polymer mixed matrix membranes
patent, December 2009

Liu, Chunqing; McCulloch, Beth; Wilson, Stephen T.
US Patent Document 7,637,983
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7637983

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
patent-application, September 2005

Yaghi, Omar M.; Eddaoudi, Mohamed; Li, Hailian
US Patent Application 11/119563; 20050192175
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050192175

Polymerisation and oligomerisation catalysts
patent, June 2007

Gibson, Vernon Charles; Tomov, Atanas
US Patent Document 7,229,943
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7229943

Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent-application, December 2004

Mueller, Ulrich; Stober, Michael; Ruppel, Raimund
US Patent Application 10/492192; 20040249189
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040249189

Nanoporous three-dimensional networks topologically related to Cooperite from the self-assembly of copper(I) centres and the "‘square-planar’' building block 1,2,4,5-tetracyanobenzene
journal, January 1999

Carlucci, Lucia; Ciani, Gianfranco; W.v. Gudenberg, Dorothea
New Journal of Chemistry, Vol. 23, Issue 4, p. 397-402
https://doi.org/10.1039/a809144g

Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method
journal, June 2012

Gándara, Felipe; Uribe-Romo, Fernando J.; Britt, David K.
Chemistry - A European Journal, Vol. 18, Issue 34, p. 10595-10601
https://doi.org/10.1002/chem.201103433

Cu₂O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species
journal, April 2010

Chun, Jiseul; Lee, Han Sol; Jung, Il Gu
Organometallics, Vol. 29, Issue 7, p. 1518-1521
https://doi.org/10.1021/om900768w

Gas sensor incorporating a porous framework
patent, May 2014

Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo
US Patent Document 8,735,161
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8735161

Concomitant Formation of N-Heterocyclic Carbene−Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions
journal, July 2009

Chun, Jiseul; Jung, Il Gu; Kim, Hae Jin
Inorganic Chemistry, Vol. 48, Issue 14, p. 6353-6355
https://doi.org/10.1021/ic900846s

Bleaching composition for dry cleaning containing transition metal bleach catalyst
patent, November 2002

Bijl, Dirk Johannes; Hage, Ronald; Kevelam, Jan
US Patent Document 6,479,447
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6479447

Homogeneous and heterogenized Au(III) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids
journal, January 2005

González-Arellano, C.; Corma, A.; Iglesias, M.
Chemical Communications, Vol. 0, Issue 15, p. 1990-1992
https://doi.org/10.1039/B418897G

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008

Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
Angewandte Chemie, Vol. 120, Issue 4, p. 689-692
https://doi.org/10.1002/ange.200705020

Reversible ethylene oxide capture in porous frameworks
patent, April 2014

Yaghi, Omar M.; Britt, David K.; Czaja, Alexander U.
US Patent Document 8,709,134
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8709134

Adsorption of Harmful Organic Vapors by Flexible Hydrophobic Bis-pyrazolate Based MOFs
journal, March 2010

Galli, S.; Masciocchi, N.; Colombo, V.
Chemistry of Materials, Vol. 22, Issue 5, p. 1664-1672
https://doi.org/10.1021/cm902899t

Isoreticular synthesis and modification of frameworks with the UiO-66 topology
journal, January 2010

Garibay, Sergio J.; Cohen, Seth M.
Chemical Communications, Vol. 46, Issue 41, p. 7700-7702
https://doi.org/10.1039/c0cc02990d

“Clickable” Metal−Organic Framework
journal, November 2008

Goto, Yuta; Sato, Hiroki; Shinkai, Seiji
Journal of the American Chemical Society, Vol. 130, Issue 44, p. 14354-14355
https://doi.org/10.1021/ja7114053

Evaluating metal–organic frameworks for natural gas storage
journal, January 2014

Mason, Jarad A.; Veenstra, Mike; Long, Jeffrey R.
Chemical Science, Vol. 5, Issue 1, p. 32-51
https://doi.org/10.1039/C3SC52633J

Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials
patent-application, August 2009

Reyes, Sebastian C.; Santiesteban, Jose G.; Ni, Zheng
US Patent Document 12/322364; 20090216059
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090216059

Gas sensor incorporating a porous framework
patent, July 2013

Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo
US Patent Document 8,480,955
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8480955

Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012

Deng, H.; Grunder, S.; Cordova, K. E.
Science, Vol. 336, Issue 6084, p. 1018-1023
https://doi.org/10.1126/science.1220131

Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications
journal, January 2011

Burrows, Andrew D.
CrystEngComm, Vol. 13, Issue 11, p. 3623-3642
https://doi.org/10.1039/c0ce00568a

Framework mobility in the metal–organic framework crystal IRMOF-3: Evidence for aromatic ring and amine rotation
journal, October 2011

Morris, William; Taylor, R. E.; Dybowski, C.
Journal of Molecular Structure, Vol. 1004, Issue 1-3, p. 94-101
https://doi.org/10.1016/j.molstruc.2011.07.037

Crystalline membranes
patent-application, January 2005

Tsapatsis, Michael; Lai, Zhiping
US Patent Application 10/794483; 20050014371
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050014371

Synthesis of inorganic membranes on supports
patent, July 1998

Ruderman, Warren; Fehlner, James R.; Zhang, Zhenyu
US Patent Document 5,779,904
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5779904

Polymeric Foams with Nanocellular Morphology and Methods for Making Them
patent-application, October 2009

Rajendran, Santhosh Kumar; Sinha, Vikash Kumar; Sriraman, Ravi
US Patent Document 12/054773; 20090247654
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090247654

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
patent, August 2005

Yaghi, Omar M.; Eddaoudi, Mohamed; Li, Hailian
US Patent Document 6,930,193
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6930193

Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005

Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
Science, Vol. 310, Issue 5751, p. 1166-1170
https://doi.org/10.1126/science.1120411

Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011

O’Keeffe, Michael; Yaghi, Omar M.
Chemical Reviews, Vol. 112, Issue 2, p. 675-702
https://doi.org/10.1021/cr200205j

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008

Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
Angewandte Chemie International Edition, Vol. 47, Issue 4, p. 677-680
https://doi.org/10.1002/anie.200705020

Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach
journal, July 2008

Tanabe, Kristine K.; Wang, Zhenqiang; Cohen, Seth M.
Journal of the American Chemical Society, Vol. 130, Issue 26, p. 8508-8517
https://doi.org/10.1021/ja801848j

A zinc(ii) metal–organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers
journal, January 2011

Ling, Yun; Chen, Zhen-Xia; Zhai, Fu-Peng
Chemical Communications, Vol. 47, Issue 25, p. 7197-7199
https://doi.org/10.1039/c1cc12253c

Shaped bodies containing metal-organic frameworks
patent-application, December 2003

Mueller, Ulrich; Lobree, Lisa; Hesse, Michael
US Patent Application 10/157182; 20030222023
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030222023

Highly porous and stable metal–organic frameworks for uranium extraction
journal, January 2013

Carboni, Michaël; Abney, Carter W.; Liu, Shubin
Chemical Science, Vol. 4, Issue 6, p. 2396-2402
https://doi.org/10.1039/c3sc50230a

Four Novel Three-Dimensional Triazole-Based Zinc(II) Metal−Organic Frameworks Controlled by the Spacers of Dicarboxylate Ligands: Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties
journal, October 2007

Yang, En-Cui; Zhao, Hong-Kun; Ding, Bin
Crystal Growth & Design, Vol. 7, Issue 10, p. 2009-2015
https://doi.org/10.1021/cg070356n

Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
journal, September 2008

Han, Sang Soo; Furukawa, Hiroyasu; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 130, Issue 35, p. 11580-11581
https://doi.org/10.1021/ja803247y

Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure (Eur. J. Inorg. Chem. 10/2008)
journal, April 2008

Costa, José Sánchez; Gamez, Patrick; Black, Cory A.
European Journal of Inorganic Chemistry, Vol. 2008, Issue 10, p. 1539-1539
https://doi.org/10.1002/ejic.200890023

Organic Porous Materials Comprising Shape-Persistent Three-Dimensional Molecular Cage Building Blocks
patent-application, February 2013

Zhang, Wei; Noble, Richard D.; Jin, Yinghua
US Patent Document 13/635882; 20130047849
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20130047849

Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition
journal, July 2012

Choi, Sang Beom; Furukawa, Hiroyasu; Nam, Hye Jin
Angewandte Chemie International Edition, Vol. 51, Issue 35, p. 8791-8795
https://doi.org/10.1002/anie.201202925

Zeolite synthesis using an alcohol or like molecules
patent, November 1992

Chu, Pochen; Klocke, Donald J.; Marler, David O.
US Patent Document 5,160,500
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5160500

Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates
journal, June 2009

Chen, Long; Kim, Jangbae; Ishizuka, Tomoya
Journal of the American Chemical Society, Vol. 131, Issue 21, p. 7287-7292
https://doi.org/10.1021/ja901357h

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
patent-application, January 2003

Yaghi, Omar M.; Eddaoudi, Mohamed; Li, Hailian
US Patent Application 10/137043; 20030004364
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030004364

Metal-organic polyhedra
patent-application, June 2005

Yaghi, Omar M.; Sudik, Andrea C.
US Patent Application 11/004696; 20050124819
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050124819

Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
journal, June 2014

Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866
https://doi.org/10.1021/ja503296c

Shaped bodies containing metal-organic frameworks
patent, May 2005

Mueller, Ulrich; Lobree, Lisa; Hesse, Michael
US Patent Document 6,893,564
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6893564

Metal-organic framework materials for gaseous hydrocarbon storage
patent, March 2008

Müller, Ulrich; Hesse, Michael; Putter, Hermann
US Patent Document 7,343,747
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7343747

Metal-organic framework materials for gaseous hydrocarbon storage
patent-application, August 2006

Muller, Ulrich; Hesse, Michael; Puetter, Hermann
US Patent Application 11/062861; 20060185388
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060185388

Metal-organic frameworks with exceptionally large pore aperatures
patent, July 2015

Yaghi, Omar M.; Furukawa, Hiroyasu; Deng, Hexiang
US Patent Document 9,078,922
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9078922

Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent-application, April 2003

Muller, Ulrich; Stober, Michael; Ruppel, Raimund
US Patent Application 10/039733; 20030078311
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030078311

Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014

Chen, Binling; Yang, Zhuxian; Zhu, Yanqiu
Journal of Materials Chemistry A, Vol. 2, Issue 40, p. 16811-16831
https://doi.org/10.1039/C4TA02984D

Process for preparing and organometallic framework material
patent, August 2008

Mueller, Ulrich; Lippert, Gerald; Schubert, Olga
US Patent Document 7,411,081
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7411081

Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air
journal, March 2009

Kirai, Naohiro; Yamamoto, Yoshihiko
European Journal of Organic Chemistry, Vol. 2009, Issue 12, p. 1864-1867
https://doi.org/10.1002/ejoc.200900173

A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination
journal, October 2011

Song, Jie; Luo, Zhen; Britt, David K.
Journal of the American Chemical Society, Vol. 133, Issue 42, p. 16839-16846
https://doi.org/10.1021/ja203695h

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
journal, July 2009

Furukawa, Hiroyasu; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8875-8883
https://doi.org/10.1021/ja9015765

Introduction to Metal–Organic Frameworks
journal, September 2011

Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
Chemical Reviews, Vol. 112, Issue 2, p. 673-674
https://doi.org/10.1021/cr300014x

Isomers of Metal–Organic Complex Arrays
journal, June 2012

Fracaroli, Alejandro M.; Tashiro, Kentaro; Yaghi, Omar M.
Inorganic Chemistry, Vol. 51, Issue 12, p. 6437-6439
https://doi.org/10.1021/ic300744x

Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry
journal, September 2009

Gadzikwa, Tendai; Farha, Omar K.; Malliakas, Christos D.
Journal of the American Chemical Society, Vol. 131, Issue 38, p. 13613-13615
https://doi.org/10.1021/ja904189d

Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008

Wang, Zhenqiang; Cohen, Seth M.
Angewandte Chemie International Edition, Vol. 47, Issue 25, p. 4699-4702
https://doi.org/10.1002/anie.200800686

Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions
journal, September 2005

Whitfield, Tabatha R.; Wang, Xiqu; Liu, Lumei
Solid State Sciences, Vol. 7, Issue 9, p. 1096-1103
https://doi.org/10.1016/j.solidstatesciences.2005.03.007

Supramolecular Assemblies of Trinuclear Triangular Copper(II) Secondary Building Units through Hydrogen Bonds. Generation of Different Metal−Organic Frameworks, Valuable Catalysts for Peroxidative Oxidation of Alkanes
journal, January 2007

Di Nicola, Corrado; Karabach, Yauhen Yu.; Kirillov, Alexander M.
Inorganic Chemistry, Vol. 46, Issue 1, p. 221-230
https://doi.org/10.1021/ic061595n

Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework
journal, October 2011

Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A.
Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315
https://doi.org/10.1021/ja206525x

Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
journal, October 2010

Mendoza-Cortés, José L.; Han, Sang Soo; Furukawa, Hiroyasu
The Journal of Physical Chemistry A, Vol. 114, Issue 40, p. 10824-10833
https://doi.org/10.1021/jp1044139

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
patent, March 2007

Yaghi, Omar M.; Eddaoudi, Mohamed; Li, Hailian
US Patent Document 7,196,210
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7196210

Post-Synthetic Modification of Tagged Metal-Organic Frameworks
journal, October 2008

Burrows, Andrew D.; Frost, Christopher G.; Mahon, Mary F.
Angewandte Chemie International Edition, Vol. 47, Issue 44, p. 8482-8486
https://doi.org/10.1002/anie.200802908

Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of Cu^II(1,4-C₄H₄N₂)(C₄O₄)(OH₂)₄
journal, July 1995

Yaghi, O. M.; Li, Guangming; Groy, T. L.
Journal of Solid State Chemistry, Vol. 117, Issue 2, p. 256-260
https://doi.org/10.1006/jssc.1995.1271

Synthesis of a Zinc(II) Imidazolium Dicarboxylate Ligand Metal−Organic Framework (MOF): a Potential Precursor to MOF-Tethered N-Heterocyclic Carbene Compounds
journal, February 2010

Crees, Rachel S.; Cole, Marcus L.; Hanton, Lyall R.
Inorganic Chemistry, Vol. 49, Issue 4, p. 1712-1719
https://doi.org/10.1021/ic9021118

SHAPED BODIES CONTAINING METAL-ORGANIC FRAMEWORKS
patent-application, June 2009

Hesse, Michael; Mueller, Ulrich; Yaghi, Omar
US Patent Application 12/372118; 20090155588
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090155588

Covalent Organic Frameworks and Methods of Making Same
patent-application, May 2014

Dichtel, William R.; Spitler, Eric L.
US Patent Document 13/639164; 20140148596
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140148596

Zeolite-like metal organic frameworks (ZMOFS): modular approach to the synthesis of organic-inorganic hybrid porous materials having a zeolite like topology
patent-application, December 2006

Eddaoudi, Mohamed; Liu, Yunling
US Patent Application 11/410359; 20060287190
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060287190

Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008

Britt, D.; Tranchemontagne, D.; Yaghi, O. M.
Proceedings of the National Academy of Sciences, Vol. 105, Issue 33, p. 11623-11627
https://doi.org/10.1073/pnas.0804900105

Gas Sensor Incorporating a Porous Framework
patent-application, February 2012

Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo
US Patent Document 13/142564; 20120028846
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120028846

Hydrogen Storage in New Metal–Organic Frameworks
journal, June 2012

Tranchemontagne, David J.; Park, Kyo Sung; Furukawa, Hiroyasu
The Journal of Physical Chemistry C, Vol. 116, Issue 24, p. 13143-13151
https://doi.org/10.1021/jp302356q

Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007

Wang, Zhenqiang; Cohen, Seth M.
Journal of the American Chemical Society, Vol. 129, Issue 41, p. 12368-12369
https://doi.org/10.1021/ja074366o

Substituted benzazoloporphyrazines for polymerization and surface attachment and articles formed therefrom
patent-application, January 2011

Youngblood, W. Justin; Lindsey, Jonathan S.
US Patent Document 11/447219; 20110015388
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110015388

Metal oxides from metal-organic framework materials
patent, August 2013

Schubert, Markus; Müller, Ulrich; Trukhan, Natalia
US Patent Document 8,501,150
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8501150

Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals
journal, September 2011

Furukawa, Hiroyasu; Go, Yong Bok; Ko, Nakeun
Inorganic Chemistry, Vol. 50, Issue 18, p. 9147-9152
https://doi.org/10.1021/ic201376t

A Thermally Stable Pt/Y-Based Metal−Organic Framework: Exploring the Accessibility of the Metal Centers with Spectroscopic Methods Using H₂O, CH₃OH, and CH₃CN as Probes
journal, November 2006

Szeto, Kai Chung; Lillerud, Karl Petter; Tilset, Mats
The Journal of Physical Chemistry B, Vol. 110, Issue 43, p. 21509-21520
https://doi.org/10.1021/jp0634611

Adsorbing Agent, Dust Collection Chamber And Method For Adsorbing Odours
patent-application, January 2008

Schultink, Jan; Sauer, Ralf
US Patent Application 10/590175; 20080017036
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080017036

Novel Eclipsed 2D Cadmium(II) Coordination Polymers with Open-Channel Structure Constructed from Terephthalate and 3-(2-Pyridyl)pyrazole: Crystal Structures, Emission Properties, and Inclusion of Guest Molecules
journal, August 2004

Zou, Ru-Qiang; Bu, Xian-He; Zhang, Ruo-Hua
Inorganic Chemistry, Vol. 43, Issue 17, p. 5382-5386
https://doi.org/10.1021/ic049625e

Microporous Coordination Polymers as Novel Sorbents for Gas Separation
patent-application, October 2010

Matzger, Adam J.; Wong-Foy, Antek G.; Caskey, Stephen
US Patent Document 12/744709; 20100258004
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100258004

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
Science, Vol. 295, Issue 5554, p. 469-472
https://doi.org/10.1126/science.1067208

Reversible oxygen sorbent compositions
patent, May 1993

Ramprasad, Dorai; Pez, Guido P.; Pearlstein, Ronald Martin
US Patent Document 5,208,335
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5208335

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012

Morris, William; Volosskiy, Boris; Demir, Selcuk
Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
https://doi.org/10.1021/ic300825s

A Metal−Organic Framework with Covalently Bound Organometallic Complexes
journal, July 2010

Oisaki, Kounosuke; Li, Qiaowei; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 132, Issue 27, p. 9262-9264
https://doi.org/10.1021/ja103016y

Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013

Kong, X.; Deng, H.; Yan, F.
Science, Vol. 341, Issue 6148, p. 882-885
https://doi.org/10.1126/science.1238339

Porous Metal Organic Framework Based On Pyrroles And Pyridinones
patent-application, July 2009

Richter, Ingo; Schubert, Markus; Muller, Ulrich
US Patent Application 12/300942; 20090183996
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090183996

20090115825
patent-application, September 2016

Long, Jeffrey R.; Kapelewski, Matthew T.; Geier, Stephen J.
US Patent Application 15/033748; 20160250618
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160250618

Mixed metal framework compositions for monoalkylene glycol production
patent, November 1991

Soo, Hwaili; Ream, Bernard C.; Robson, John H.
US Patent Document 5,064,804
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5064804

Metal–organic frameworks as heterogeneous catalysts for oxidation reactions
journal, January 2011

Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes; Garcia, Hermenegildo
Catalysis Science & Technology, Vol. 1, Issue 6, p. 856-867
https://doi.org/10.1039/c1cy00068c

Gas Odorous Substance Separation
patent-application, August 2008

Muller, Ulrich; Schubert, Markus; Hesse, Michael
US Patent Document 11/913977; 20080190289
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080190289

Gas Adsorption on Metal-Organic Frameworks
patent-application, March 2010

Willis, Richard R.; Low, John J.; Faheem, Syed A.
US Patent Document 12/552037; 20100069234
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100069234

Porous organo-metallic skeleton material containing an additional polymer
patent, October 2010

Mueller, Ulrich; Hesse, Michael; Schubert, Markus
US Patent Document 7,815,716
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7815716

Photoluminescent Metal−Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates
journal, February 2003

Chen, Wei; Wang, Jia-Yu; Chen, Cheng
Inorganic Chemistry, Vol. 42, Issue 4, p. 944-946
https://doi.org/10.1021/ic025871j

High Methane Storage Capacity in Aluminum Metal–Organic Frameworks
journal, February 2014

Gándara, Felipe; Furukawa, Hiroyasu; Lee, Seungkyu
Journal of the American Chemical Society, Vol. 136, Issue 14, p. 5271-5274
https://doi.org/10.1021/ja501606h

In Situ Hydrothermal Growth of Metal−Organic Framework 199 Films on Stainless Steel Fibers for Solid-Phase Microextraction of Gaseous Benzene Homologues
journal, December 2009

Cui, Xiao-Yan; Gu, Zhi-Yuan; Jiang, Dong-Qing
Analytical Chemistry, Vol. 81, Issue 23, p. 9771-9777
https://doi.org/10.1021/ac901663x

Method of storing, uptaking, releasing of gases by novel framework materials
patent-application, August 2003

Muller, Ulrich; Harth, Klaus; Holzle, Markus
US Patent Application 10/061147; 20030148165
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030148165

Process for preparing porous metal-organic frameworks based on aluminum fumarate
patent, September 2013

Leung, Emi; Müller, Ulrich; Trukhan, Natalia
US Patent Document 8,524,932
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8524932

Method of using a metal organic frameworks based on aluminum fumarate
patent, August 2013

Kiener, Christoph; Müller, Ulrich; Schubert, Markus
US Patent Document 8,518,264
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8518264

Role of Copper Species in the Oxidative Dimerization of Arylboronic Acids: Synthesis of Symmetrical Biaryls
journal, December 2003

Demir, Ayhan S.; Reis, Ömer; Emrullahoglu, Mustafa
The Journal of Organic Chemistry, Vol. 68, Issue 26, p. 10130-10134
https://doi.org/10.1021/jo034680a

Late transition metal catalyst complexes and oligomers therefrom
patent, December 2002

Stibrany, Robert T.; Matturro, Michael G.; Zushma, Stephen
US Patent Document 6,501,000
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6501000

Shaped bodies containing metal-organic frameworks
patent, April 2009

Hesse, Michael; Mueller, Ulrich; Yaghi, Omar M.
US Patent Document 7,524,444
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7524444

Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene
patent-application, November 2011

Li, Jing; Li, Kunhao; Olson, David H.
US Patent Document 13/109614; 20110282067
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110282067

Reversible Ethylene Oxide Capture in Porous Frameworks
patent-application, February 2012

Yaghi, Omar M.; Britt, David Kyle; Czaja, Alexander U.
US Patent Document 13/147357; 20120031268
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120031268

Carbon Dioxide Capture and Storage Using Open Frameworks
patent-application, May 2012

Yaghi, Omar M.; Britt, David Kyle; Wang, Bo
US Patent Document 13/377805; 20120133939
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120133939

Process for the epoxidation of an organic compound with oxygen or an oxygen-delivering compounds using catalysts containing metal-organic frame-work materials
patent, September 2003

Müller, Ulrich; Lobree, Lisa; Hesse, Michael
US Patent Document 6,624,318
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6624318

Process for the alkoxylation of monools in the presence of metallo-organic framework materials
patent-application, January 2005

Muller, Ulrich; Metelkina, Olga; Hesse, Michael
US Patent Application 10/611863; 20050004404
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050004404

Non-regenerating carbon monoxide sensor
patent, March 1998

Goldstein, Mark K.; Taniguchi, Vernon T.; Helfman, William B.
US Patent Document 5,733,505
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5733505

Preparation of metal-catecholate frameworks
patent, June 2014

Yaghi, Omar M.; Gandara-Barragan, Felipe; Lu, Zheng-Hong
US Patent Document 8,742,152
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8742152

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg₂(dobpdc)
journal, April 2012

McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.
Journal of the American Chemical Society, Vol. 134, Issue 16, p. 7056-7065
https://doi.org/10.1021/ja300034j

A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials
journal, November 2005

Forster, Paul M.; Stock, Norbert; Cheetham, Anthony K.
Angewandte Chemie International Edition, Vol. 44, Issue 46, p. 7608-7611
https://doi.org/10.1002/anie.200501766

Role of Exposed Metal Sites in Hydrogen Storage in MOFs
journal, July 2008

Vitillo, Jenny G.; Regli, Laura; Chavan, Sachin
Journal of the American Chemical Society, Vol. 130, Issue 26, p. 8386-8396
https://doi.org/10.1021/ja8007159

Process for preparing hydrogen peroxide from the elements
patent-application, April 2004

Muller, Ulrich; Metelkina, Olga; Junicke, Henrik
US Patent Application 10/280013; 20040081611
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040081611

From MOFs to zeolites: zirconium sites for epoxide rearrangement
journal, January 2013

Corma, Avelino; Orozco, Lina M.; Renz, Michael
New Journal of Chemistry, Vol. 37, Issue 11, p. 3496-3502
https://doi.org/10.1039/c3nj00551h

Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals
patent-application, November 2004

Yaghi, Omar M.; Matzger, Adam J.; Rowsell, Jesse L.C.
US Patent Application 10/841983; 20040225134
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040225134

Characterization of a New Porous Pt-Containing Metal-Organic Framework Containing Potentially Catalytically Active Sites: Local Electronic Structure at the Metal Centers
journal, January 2007

Szeto, Kai Chung; Prestipino, Carmelo; Lamberti, Carlo
Chemistry of Materials, Vol. 19, Issue 2, p. 211-220
https://doi.org/10.1021/cm0616432

An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids
journal, January 2002

Koza, Darrell J.; Carita, Eric
Synthesis, Vol. 2002, Issue 15, p. 2183-2186
https://doi.org/10.1055/s-2002-34855

A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst
journal, August 2002

Corma, Avelino; Díaz-Cabañas, María J.; Martínez-Triguero, Joaquín
Nature, Vol. 418, Issue 6897, p. 514-517
https://doi.org/10.1038/nature00924

High gas adsorption in a microporous metal-organic framework with open-metal sites
patent-application, November 2006

Yaghi, Omar; Chen, Banglin
US Patent Application 11/400478; 20060252641
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060252641

Process for producing polyalkylene carbonates
patent, September 2003

Müller, Ulrich; Luinstra, Gerrit; Yaghi, Omar M.
US Patent Document 6,617,467
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6617467

Direction of unusual mixed-ligand metal–organic frameworks: a new type of 3-D polythreading involving 1-D and 2-D structural motifs and a 2-fold interpenetrating porous network
journal, January 2005

Du, Miao; Jiang, Xiu-Juan; Zhao, Xiao-Jun
Chemical Communications, Vol. 0, Issue 44, p. 5521-5523
https://doi.org/10.1039/b509875k

Process for the alkoxylation of monools in the presence of metallo-organic framework materials
patent-application, June 2006

Mueller, Ulrich; Metelkina, Olga; Hesse, Michael
US Patent Application 11/285070; 20060135824
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060135824

Crystalline metal-organic microporous materials
patent, July 1997

Yaghi, Omar M.
US Patent Document 5,648,508
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5648508

Covalent Organic Framework Films, and Methods of Making and Uses of Same
patent-application, February 2014

Dichtel, William R.; Park, Jiwoong; Mukherjee, Arnab
US Patent Document 13/821136; 20140037944
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140037944

Metal-Organic Frameworks with Exceptionally Large Pore Aperatures
patent-application, April 2013

Yaghi, Omar M.; Furukawa, Hiroyasu; Deng, Hexiang
US Patent Document 13/650232; 20130096210
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20130096210

Process for Manufacture of Olefin Oxides
patent, July 1954

Berg, Clyde H.O.
US Patent Document 2,684,967
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/2684967

Metal-Organic Frameworks for Aromatic Hydrocarbon Separations
patent-application, June 2016

Long, Jeffrey R.; Bloch, Eric D.; Kapelewski, Matthew
US Patent Document 14/957494; 20160159713
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160159713

Process for the alkoxylation of monools in the presence of metallo-organic framework materials
patent, April 2007

Mueller, Ulrich; Metelkina, Olga; Hesse, Michael
US Patent Document 7,202,385
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7202385

Metal-Organic Frameworks Incorporating Copper-Complexed Rotaxanes
journal, January 2012

Coskun, Ali; Hmadeh, Mohamad; Barin, Gokhan
Angewandte Chemie International Edition, Vol. 51, Issue 9, p. 2160-2163
https://doi.org/10.1002/anie.201107873

Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014

Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao
Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
https://doi.org/10.1021/ja500330a

Facile Synthesis of a Highly Crystalline, Covalently Linked Porous Boronate Network
journal, October 2006

Tilford, R. William; Gemmill, William R.; zur Loye, Hans-Conrad
Chemistry of Materials, Vol. 18, Issue 22, p. 5296-5301
https://doi.org/10.1021/cm061177g

Method of storing, uptaking, releasing of gases by novel framework materials
patent, August 2005

Müller, Ulrich; Harth, Klaus; Hölzle, Markus
US Patent Document 6,929,679
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6929679

Oxidative Homo-Coupling Reactions of Aryl Boronic Acids Using a Porous Copper Metal-Organic Framework as a Highly Efficient Heterogeneous Catalyst
patent-application, May 2012

Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo
US Patent Document 13/387598; 20120130113
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120130113

Similar Records in DOE Patents and OSTI.GOV collections:

Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents

Patent Hupp, Joseph T.; Farha, Omar K.; Katz, Michael J.; ...

A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.
Full Text Available
Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents

Patent Hupp, Joseph T.; Farha, Omar K.; Katz, Michael J.; ...

A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.
Full Text Available
Metal-organic frameworks for the adsorption and catalytic transformations of carbon dioxide

Patent Morris, Amanda Jean; Zhu, Jie

Novel crystalline porous materials known as metal-organic frameworks (MOFs) and methods for their synthesis are provided herein. The MOFs include a M6(μ3-OH)8(OH)8(μ2,η2-(O2C)2cyclam)8 cluster, and a metal atom coordinated to the one or more cyclam of the cluster, wherein M is Zr or Hf, and the metal atom is any one of Cu, Ni, Cr, Ru, Co, and Gd. The MOFs can be used as an adsorbent, alone or in a medium with other components, of CO2. The MOFs can also be used as a catalyst for the transformation of CO2 and epoxides to cyclic carbonates. The MOFs can also bemore » « less
Full Text Available
Metal-organic frameworks for aromatic hydrocarbon separations

Patent Long, Jeffrey R.; Bloch, Eric D.; Kapelewski, Matthew; ...

The disclosure provides for metal organic frameworks (MOFs) that are selective adsorbents for aromatic hydrocarbons, devices comprising the MOFs thereof, and methods using the MOFS thereof for separating and/or storing aromatic hydrocarbons.
Full Text Available
Oxidative homo-coupling reactions of aryl boronic acids using a porous copper metal-organic framework as a highly efficient heterogeneous catalyst

Patent Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo; ...

The disclosure provides methods for the use of open metal frameworks to catalyze coupling reactions.
Full Text Available

Similar Records

Title: Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons

Abstract

Citation Formats

Adsorption process with on-line adsorbent removal patent-application, November 2006

Crystallography of metal–organic frameworks journal, October 2014

Process for preparing an organometallic framework material patent-application, July 2005

Covalently linked organic frameworks and polyhedra patent, September 2009

Fluorinated metal-organic frameworks for gas storage patent, January 2013

Gas storage system patent-application, December 2004

Process for preparing hydrogen peroxide from the elements patent-application, March 2006

1,2,3-triazole based metal-organic framework as photo-active materials patent-application, November 2011

Metal−Organic Frameworks As Templates for Nanoscale NaAlH4 journal, September 2009

Donor-acceptor rotaxanes with tetracationic cyclophane ring journal, September 2012

PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS patent-application, August 2007

Bone graft composition patent-application, October 2007

Two new metal–triazole-benzenedicarboxylate frameworks affording an uncommon 3,4-connected net and unique 4,6-connected rod packing: hydrothermal synthesis, structure, thermostability and luminescence studies journal, January 2009

Process for the alkoxylation of organic compounds in the presence of novel framework materials patent, October 2007

Air Collector with Functionalized Ion Exchange Membrane for Capturing Ambient CO2 patent-application, September 2007

Gas storage system patent, December 2007

Covalently linked organic frameworks and polyhedra patent-application, July 2006

Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine journal, July 2009

Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide journal, January 2009

Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature patent-application, March 2007

Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks journal, October 2007

Metal catalyzed reactions patent, February 2004

CH4 storage and CO2 capture in highly porous zirconium oxide based metal–organic frameworks journal, January 2012

Preparation of metal-containing zeolite catalysts of increased stability and activity patent, July 1985

Metal organic framework—polymer mixed matrix membranes patent, December 2009

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application, September 2005

Polymerisation and oligomerisation catalysts patent, June 2007

Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application, December 2004

Nanoporous three-dimensional networks topologically related to Cooperite from the self-assembly of copper(I) centres and the "‘square-planar’' building block 1,2,4,5-tetracyanobenzene journal, January 1999

Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method journal, June 2012

Cu2O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species journal, April 2010

Gas sensor incorporating a porous framework patent, May 2014

Concomitant Formation of N-Heterocyclic Carbene−Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions journal, July 2009

Bleaching composition for dry cleaning containing transition metal bleach catalyst patent, November 2002

Homogeneous and heterogenized Au(III) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids journal, January 2005

A Crystalline Mesoporous Coordination Copolymer with High Microporosity journal, January 2008

Reversible ethylene oxide capture in porous frameworks patent, April 2014

Adsorption of Harmful Organic Vapors by Flexible Hydrophobic Bis-pyrazolate Based MOFs journal, March 2010

Isoreticular synthesis and modification of frameworks with the UiO-66 topology journal, January 2010

“Clickable” Metal−Organic Framework journal, November 2008

Evaluating metal–organic frameworks for natural gas storage journal, January 2014

Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials patent-application, August 2009

Gas sensor incorporating a porous framework patent, July 2013

Large-Pore Apertures in a Series of Metal-Organic Frameworks journal, May 2012

Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications journal, January 2011

Framework mobility in the metal–organic framework crystal IRMOF-3: Evidence for aromatic ring and amine rotation journal, October 2011

Crystalline membranes patent-application, January 2005

Synthesis of inorganic membranes on supports patent, July 1998

Polymeric Foams with Nanocellular Morphology and Methods for Making Them patent-application, October 2009

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent, August 2005

Porous, Crystalline, Covalent Organic Frameworks journal, November 2005

Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets journal, September 2011

A Crystalline Mesoporous Coordination Copolymer with High Microporosity journal, January 2008

Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach journal, July 2008

A zinc(ii) metal–organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers journal, January 2011

Shaped bodies containing metal-organic frameworks patent-application, December 2003

Highly porous and stable metal–organic frameworks for uranium extraction journal, January 2013

Four Novel Three-Dimensional Triazole-Based Zinc(II) Metal−Organic Frameworks Controlled by the Spacers of Dicarboxylate Ligands: Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties journal, October 2007

Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials journal, September 2008

Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure (Eur. J. Inorg. Chem. 10/2008) journal, April 2008

Organic Porous Materials Comprising Shape-Persistent Three-Dimensional Molecular Cage Building Blocks patent-application, February 2013

Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition journal, July 2012

Zeolite synthesis using an alcohol or like molecules patent, November 1992

Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates journal, June 2009

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application, January 2003

Metal-organic polyhedra patent-application, June 2005

Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water journal, June 2014

Shaped bodies containing metal-organic frameworks patent, May 2005

Metal-organic framework materials for gaseous hydrocarbon storage patent, March 2008

Metal-organic framework materials for gaseous hydrocarbon storage patent-application, August 2006

Metal-organic frameworks with exceptionally large pore aperatures patent, July 2015

Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application, April 2003

Zeolitic imidazolate framework materials: recent progress in synthesis and applications journal, January 2014

Process for preparing and organometallic framework material patent, August 2008

Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air journal, March 2009

A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination journal, October 2011

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications journal, July 2009

Adsorption process with on-line adsorbent removal
patent-application, November 2006

Crystallography of metal–organic frameworks
journal, October 2014

Process for preparing an organometallic framework material
patent-application, July 2005

Covalently linked organic frameworks and polyhedra
patent, September 2009

Fluorinated metal-organic frameworks for gas storage
patent, January 2013

Gas storage system
patent-application, December 2004

Process for preparing hydrogen peroxide from the elements
patent-application, March 2006

1,2,3-triazole based metal-organic framework as photo-active materials
patent-application, November 2011

Metal−Organic Frameworks As Templates for Nanoscale NaAlH₄
journal, September 2009

Donor-acceptor rotaxanes with tetracationic cyclophane ring
journal, September 2012

PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS
patent-application, August 2007

Bone graft composition
patent-application, October 2007

Two new metal–triazole-benzenedicarboxylate frameworks affording an uncommon 3,4-connected net and unique 4,6-connected rod packing: hydrothermal synthesis, structure, thermostability and luminescence studies
journal, January 2009

Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent, October 2007

Air Collector with Functionalized Ion Exchange Membrane for Capturing Ambient CO₂
patent-application, September 2007

Gas storage system
patent, December 2007

Covalently linked organic frameworks and polyhedra
patent-application, July 2006

Strong CO₂ Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
journal, July 2009

Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide
journal, January 2009

Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature
patent-application, March 2007

Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
journal, October 2007

Metal catalyzed reactions
patent, February 2004

CH₄ storage and CO₂ capture in highly porous zirconium oxide based metal–organic frameworks
journal, January 2012

Preparation of metal-containing zeolite catalysts of increased stability and activity
patent, July 1985

Metal organic framework—polymer mixed matrix membranes
patent, December 2009

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
patent-application, September 2005

Polymerisation and oligomerisation catalysts
patent, June 2007

Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent-application, December 2004

Nanoporous three-dimensional networks topologically related to Cooperite from the self-assembly of copper(I) centres and the "‘square-planar’' building block 1,2,4,5-tetracyanobenzene
journal, January 1999

Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method
journal, June 2012

Cu₂O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species
journal, April 2010

Gas sensor incorporating a porous framework
patent, May 2014

Concomitant Formation of N-Heterocyclic Carbene−Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions
journal, July 2009

Bleaching composition for dry cleaning containing transition metal bleach catalyst
patent, November 2002

Homogeneous and heterogenized Au(III) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids
journal, January 2005

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008

Reversible ethylene oxide capture in porous frameworks
patent, April 2014

Adsorption of Harmful Organic Vapors by Flexible Hydrophobic Bis-pyrazolate Based MOFs
journal, March 2010

Isoreticular synthesis and modification of frameworks with the UiO-66 topology
journal, January 2010

“Clickable” Metal−Organic Framework
journal, November 2008

Evaluating metal–organic frameworks for natural gas storage
journal, January 2014

Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials
patent-application, August 2009

Gas sensor incorporating a porous framework
patent, July 2013

Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012

Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications
journal, January 2011

Framework mobility in the metal–organic framework crystal IRMOF-3: Evidence for aromatic ring and amine rotation
journal, October 2011

Crystalline membranes
patent-application, January 2005

Synthesis of inorganic membranes on supports
patent, July 1998

Polymeric Foams with Nanocellular Morphology and Methods for Making Them
patent-application, October 2009

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
patent, August 2005

Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005

Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008

Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach
journal, July 2008

A zinc(ii) metal–organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers
journal, January 2011

Shaped bodies containing metal-organic frameworks
patent-application, December 2003

Highly porous and stable metal–organic frameworks for uranium extraction
journal, January 2013

Four Novel Three-Dimensional Triazole-Based Zinc(II) Metal−Organic Frameworks Controlled by the Spacers of Dicarboxylate Ligands: Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties
journal, October 2007

Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
journal, September 2008

Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure (Eur. J. Inorg. Chem. 10/2008)
journal, April 2008

Organic Porous Materials Comprising Shape-Persistent Three-Dimensional Molecular Cage Building Blocks
patent-application, February 2013

Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition
journal, July 2012

Zeolite synthesis using an alcohol or like molecules
patent, November 1992

Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates
journal, June 2009

Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
patent-application, January 2003

Metal-organic polyhedra
patent-application, June 2005

Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
journal, June 2014

Shaped bodies containing metal-organic frameworks
patent, May 2005

Metal-organic framework materials for gaseous hydrocarbon storage
patent, March 2008

Metal-organic framework materials for gaseous hydrocarbon storage
patent-application, August 2006

Metal-organic frameworks with exceptionally large pore aperatures
patent, July 2015

Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent-application, April 2003

Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014

Process for preparing and organometallic framework material
patent, August 2008

Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air
journal, March 2009

A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination
journal, October 2011

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
journal, July 2009

Introduction to Metal–Organic Frameworks
journal, September 2011

Isomers of Metal–Organic Complex Arrays
journal, June 2012

Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry
journal, September 2009