Functionalization of Diels-Alder polyphenylene polymers
Abstract
The present invention relates to functionalized polymers including a poly(phenylene) structure. The structure can include any useful modifications, such as the inclusion of one or more reactive handles having an aryl group. Methods and uses of such structures and polymers are also described herein.
- Inventors:
- Issue Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1471227
- Patent Number(s):
- 10053534
- Application Number:
- 15/398,545
- Assignee:
- National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08J - WORKING-UP
- DOE Contract Number:
- AC04-94AL85000
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2017 Jan 04
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Fujimoto, Cy. Functionalization of Diels-Alder polyphenylene polymers. United States: N. p., 2018.
Web.
Fujimoto, Cy. Functionalization of Diels-Alder polyphenylene polymers. United States.
Fujimoto, Cy. Tue .
"Functionalization of Diels-Alder polyphenylene polymers". United States. https://www.osti.gov/servlets/purl/1471227.
@article{osti_1471227,
title = {Functionalization of Diels-Alder polyphenylene polymers},
author = {Fujimoto, Cy},
abstractNote = {The present invention relates to functionalized polymers including a poly(phenylene) structure. The structure can include any useful modifications, such as the inclusion of one or more reactive handles having an aryl group. Methods and uses of such structures and polymers are also described herein.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {8}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s
journal, July 2012
- Fujimoto, Cy; Kim, Soowhan; Stains, Ronald
- Electrochemistry Communications, Vol. 20, p. 48-51
Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology
patent, April 2006
- Cornelius, Christopher
- US Patent Document 7,022,810
Metal triflates and triflimides as Lewis “superacids”: preparation, synthetic application and affinity tests by mass spectrometry
journal, September 2012
- Gal, Jean-François; Iacobucci, Claudio; Monfardini, Ilaria
- Journal of Physical Organic Chemistry, Vol. 26, Issue 2, p. 87-97
Anion exchange polymer electrolytes
patent, July 2013
- Kim, Yu Seung; Kim, Dae-sik; Lee, Kwan-Soo
- US Patent Document 8,492,049
Polyarylene polymers and ion conducting functionalized polyarylene polymers resulting from pairing bis-diene arylenes and bis-dienophile arylenes via a Diels-Alder reaction
patent-application, October 2009
- Loy, Dougles Anson
- US Patent Application 12/148341; 20090264544
Mecanisme de la C acylation : Etude cinetique du mecanisme de l'acetylation des composes aromatiques catalysee par AlCl3
journal, January 1971
- Corriu, R.; Dore, M.; Thomassin, R.
- Tetrahedron, Vol. 27, Issue 23, p. 5819-5831
Poly(arylene)-based anion exchange polymer electrolytes
patent, June 2015
- Kim, Yu Seung; Bae, Chulsung
- US Patent Document 9,051,431
Processes for Preparing Of Glucopyranosyl-Substituted Benzyl-Benzene Derivatives
patent-application, September 2011
- Weber, Dirk; Fiedler, Tobias; Filser, Christian
- US Patent Application 12/892326; 20110237789
Process catalysed by bis-trifilmide compounds
patent, August 2010
- Earle, Martyn; Mcauley, Barry Joseph; Ramani, Alwar
- US Patent Document 7,781,625
Anion-conducting polymer, composition, and membrane
patent, September 2009
- Pivovar, Bryan S.; Thorn, David L.
- US Patent Document 7,582,683
Stable Elastomeric Anion Exchange Membranes Based on Quaternary Ammonium-Tethered Polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene Triblock Copolymers
journal, September 2015
- Mohanty, Angela D.; Ryu, Chang Y.; Kim, Yu Seung
- Macromolecules, Vol. 48, Issue 19, p. 7085-7095
Metal Triflimidates: Better than Metal Triflates as Catalysts in Organic Synthesis-The Effect of a Highly Delocalized Counteranion
journal, August 2010
- Antoniotti, Sylvain; Dalla, Vincent; Duñach, Elisabet
- Angewandte Chemie International Edition, Vol. 49, Issue 43, p. 7860-7888
Alkaline stability of poly(phenylene)-based anion exchange membranes with various cations
journal, August 2012
- Hibbs, Michael R.; Hickner, Michael A.; Coughlin, E. Bryan
- Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 24, p. 1736-1742
Sulfonated polyphenylene polymers
patent, November 2007
- Cornelius, Christopher; Fujimoto, Cy; Hickner, Michael
- US Patent Document 7,301,002
Palladium-Catalyzed Phosphonation of Polyphenylsulfone
journal, February 2003
- Jakoby, Kai; Peinemann, K. V.; Nunes, Suzana P.
- Macromolecular Chemistry and Physics, Vol. 204, Issue 1, p. 61-67
Anion exchange polymer electrolytes
patent, June 2015
- Kim, Yu Seung; Kim, Dae-sik
- US Patent Document 9,048,480
Transport in sulfonated poly(phenylene)s: Proton conductivity, permeability, and the state of water
journal, May 2006
- Hickner, Michael A.; Fujimoto, Cy H.; Cornelius, Chris J.
- Polymer, Vol. 47, Issue 11, p. 4238-4244
Evaluation of hydrogen and methanol fuel cell performance of sulfonated diels alder poly(phenylene) membranes
journal, January 2010
- Stanis, Ronald J.; Yaklin, Melissa A.; Cornelius, Chris J.
- Journal of Power Sources, Vol. 195, Issue 1, p. 104-110
Branched Polyphenylenes by Repetitive Diels−Alder Cycloaddition
journal, May 2000
- Shifrina, Zinaida B.; Averina, Marina S.; Rusanov, Alexander L.
- Macromolecules, Vol. 33, Issue 10, p. 3525-3529
Mécanisme de la C acylation : Étude cinétique du mécanisme de la benzoylation des composés aromatiques catalysee par AlCl3
journal, January 1971
- Corriu, R.; Dore, M.; Thomassin, R.
- Tetrahedron, Vol. 27, Issue 22, p. 5601-5618
Backbone stability of quaternized polyaromatics for alkaline membrane fuel cells
journal, December 2012
- Fujimoto, Cy; Kim, Dae-Sik; Hibbs, Michael
- Journal of Membrane Science, Vol. 423-424, p. 438-449
An operationally flexible fuel cell based on quaternary ammonium-biphosphate ion pairs
journal, August 2016
- Lee, Kwan-Soo; Spendelow, Jacob S.; Choe, Yoong-Kee
- Nature Energy, Vol. 1, Issue 9, Article No. 16120
Secondary Benzylation Using Benzyl Alcohols Catalyzed by Lanthanoid, Scandium, and Hafnium Triflate
journal, November 2003
- Noji, Masahiro; Ohno, Tomoko; Fuji, Koji
- The Journal of Organic Chemistry, Vol. 68, Issue 24, p. 9340-9347
Epoxy-crosslinked sulfonated poly (phenylene) copolymer proton exchange membranes
patent, October 2010
- Hibbs, Michael; Fujimoto, Cy; Norman, Kirsten
- US Patent Document 7,816,482
Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells
journal, November 2009
- Hibbs, Michael R.; Fujimoto, Cy H.; Cornelius, Christopher J.
- Macromolecules, Vol. 42, Issue 21, p. 8316-8321
Electrophilic Aromatic Aroylation with CF3‐Bearing Arenecarboxylic Acid Derivatives: Reaction Behavior and Acidic Mediator Dependence
journal, August 2007
- Akiko, Okamoto; Katsuya, Maeyama; Hideaki, Oike
- Synthetic Communications, Vol. 37, Issue 16, p. 2701-2715
Resonance Stabilized Perfluorinated Ionomers for Alkaline Membrane Fuel Cells
journal, September 2013
- Kim, Dae Sik; Fujimoto, Cy H.; Hibbs, Michael R.
- Macromolecules, Vol. 46, Issue 19, p. 7826-7833
Poly(phenylene)-based anion exchange membrane
patent, February 2011
- Hibbs, Michael; Cornelius, Christopher; Fujimoto, Cy
- US Patent Document 7,888,397
Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes
patent, February 2012
- Fujimoto, Cy; Hibbs, Michael; Ambrosini, Andrea
- US Patent Document 8,110,636
Ionomer for alkaline fuel cell
patent-application, September 2012
- Kim, Yu Seung; Kim, Dae Sik
- US Patent Application 13/409505; 20120225371
Structurally-Defined, Sulfo-Phenylated, Oligophenylenes and Polyphenylenes
journal, September 2015
- Skalski, Thomas J. G.; Britton, Benjamin; Peckham, Timothy J.
- Journal of the American Chemical Society, Vol. 137, Issue 38, p. 12223-12226
Trifluoromethanesulfonic-Carboxylic Anhydrides, Highly Active Acylating Agents
journal, April 1972
- Effenberger, Franz; Epple, Gerhard
- Angewandte Chemie International Edition in English, Vol. 11, Issue 4, p. 299-300
Functionalization of poly(phenylene) by the attachment of sidechains
patent, August 2014
- Hibbs, Michael
- US Patent Document 8,809,483
Catalytic Friedel-Crafts Acylation of Aromatic Compounds
journal, April 1972
- Effenberger, Franz; Epple, Gerhard
- Angewandte Chemie International Edition in English, Vol. 11, Issue 4, p. 300-301
Factors enabling high mobility of protons and water in perfluorosulfonate membranes under low hydration conditions
journal, February 2014
- Maalouf, Manale; Sun, Che-Nan; Pyle, Brandon
- International Journal of Hydrogen Energy, Vol. 39, Issue 6, p. 2795-2800
Carboxylated and Sulfonated Poly(arylene- co -arylene sulfone)s: Thermostable Polyelectrolytes for Fuel Cell Applications
journal, September 2002
- Poppe, D.; Frey, H.; Kreuer, K. D.
- Macromolecules, Vol. 35, Issue 21, p. 7936-7941
Anion exchange polymer electrolytes
patent, September 2013
- Kim, Yu Seung; Kim, Dae-sik
- US Patent Document 8,530,109
Aluminum Chloride as a Solid Is Not a Strong Lewis Acid
journal, April 2006
- Murthy, J. Krishna; Gross, Udo; Rüdiger, Stephan
- The Journal of Physical Chemistry B, Vol. 110, Issue 16, p. 8314-8319
Polymer Electrolyte Membranes Derived from New Sulfone Monomers with Pendent Sulfonic Acid Groups
journal, December 2010
- Li, Nanwen; Shin, Dong Won; Hwang, Doo Sung
- Macromolecules, Vol. 43, Issue 23, p. 9810-9820
Anion-conducting polymer, composition, and membrane
patent, December 2010
- Pivovar, Bryan S.; Thorn, David L.
- US Patent Document 7,846,980
Poly(phenylene)-based anion exchange polymers and methods thereof
patent-application, July 2017
- Kim, Yu Seung; Lee, Kwan-Soo; Fujimoto, Cy
- US Patent Application 15/398547; 20170190831
Anion exchange membranes for alkaline fuel cells: A review
journal, July 2011
- Merle, Géraldine; Wessling, Matthias; Nijmeijer, Kitty
- Journal of Membrane Science, Vol. 377, Issue 1-2, p. 1-35
Highly selective catalytic Friedel–Crafts acylation and sulfonylation of activated aromatic compounds using indium metal
journal, August 2006
- Jang, Doo Ok; Moon, Kyung Soo; Cho, Dae Hyan
- Tetrahedron Letters, Vol. 47, Issue 34, p. 6063-6066
Synthesis and properties of sulfonated poly(phenylene sulfone)s without ether linkage by Diels–Alder reaction for PEMFC application
journal, February 2014
- Lim, Youngdon; Lee, Hyunchul; Lee, Soonho
- Electrochimica Acta, Vol. 119, p. 16-23
Advanced membrane electrode assemblies for fuel cells
patent, July 2012
- Kim, Yu Seung; Pivovar, Bryan S.
- US Patent Document 8,227,147
Evaluation of Diels–Alder poly(phenylene) anion exchange membranes in all-vanadium redox flow batteries
journal, June 2014
- Sun, Che-Nan; Tang, Zhijiang; Belcher, Cami
- Electrochemistry Communications, Vol. 43, p. 63-66
Luminescent material for organic optoelectric device and organic optoelectric device and display device
patent-application, December 2015
- Lee, Han-Ill; Yu, Eun-Sun; Kang, Dong-Min
- US Patent Application 14/760169; 20150349269
Catalytic Friedel-Crafts acylation of benzene, chlorobenzene, and fluorobenzene using a novel catalyst system, hafnium triflate and trifluoromethanesulfonic acid
journal, June 1998
- Kobayashi, Shū; Iwamoto, Shunsuke
- Tetrahedron Letters, Vol. 39, Issue 26, p. 4697-4700
Phosphonated and sulfonated polyhphenylsulfone membranes for fuel cell application
journal, November 2006
- Parcero, Ethel; Herrera, Rafael; Nunes, Suzana P.
- Journal of Membrane Science, Vol. 285, Issue 1-2, p. 206-213
Trifluoromethanesulfonamides and Related Compounds
journal, November 2012
- Shainyan, Bagrat A.; Tolstikova, Ljudmila L.
- Chemical Reviews, Vol. 113, Issue 1, p. 699-733
Ionomeric Poly(phenylene) Prepared by Diels−Alder Polymerization: Synthesis and Physical Properties of a Novel Polyelectrolyte
journal, June 2005
- Fujimoto, Cy H.; Hickner, Michael A.; Cornelius, Christopher J.
- Macromolecules, Vol. 38, Issue 12, p. 5010-5016
Hybrid membrane—PSA system for separating oxygen from air
patent, January 2011
- Staiger, Chad; Vaughn, Mark R.; Miller, A. Keith
- US Patent Document 7,875,101
High performance, durable polymers including poly(phenylene)
patent, February 2017
- Fujimoto, Cy; Pratt, Harry; Anderson, Travis Mark
- US Patent Document 9,580,541
An efficient method for aromatic Friedel–Crafts alkylation, acylation, benzoylation, and sulfonylation reactions
journal, January 2001
- Singh, Ravi P.; Kamble, Rajesh M.; Chandra, Kusum L.
- Tetrahedron, Vol. 57, Issue 1, p. 241-247