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Title: Functionalization of Diels-Alder polyphenylene polymers

Abstract

The present invention relates to functionalized polymers including a poly(phenylene) structure. The structure can include any useful modifications, such as the inclusion of one or more reactive handles having an aryl group. Methods and uses of such structures and polymers are also described herein.

Inventors:
Issue Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1471227
Patent Number(s):
10053534
Application Number:
15/398,545
Assignee:
National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
Patent Classifications (CPCs):
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08J - WORKING-UP
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Resource Relation:
Patent File Date: 2017 Jan 04
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats

Fujimoto, Cy. Functionalization of Diels-Alder polyphenylene polymers. United States: N. p., 2018. Web.
Fujimoto, Cy. Functionalization of Diels-Alder polyphenylene polymers. United States.
Fujimoto, Cy. Tue . "Functionalization of Diels-Alder polyphenylene polymers". United States. https://www.osti.gov/servlets/purl/1471227.
@article{osti_1471227,
title = {Functionalization of Diels-Alder polyphenylene polymers},
author = {Fujimoto, Cy},
abstractNote = {The present invention relates to functionalized polymers including a poly(phenylene) structure. The structure can include any useful modifications, such as the inclusion of one or more reactive handles having an aryl group. Methods and uses of such structures and polymers are also described herein.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {8}
}

Works referenced in this record:

Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s
journal, July 2012


Metal triflates and triflimides as Lewis “superacids”: preparation, synthetic application and affinity tests by mass spectrometry
journal, September 2012

  • Gal, Jean-François; Iacobucci, Claudio; Monfardini, Ilaria
  • Journal of Physical Organic Chemistry, Vol. 26, Issue 2, p. 87-97
  • https://doi.org/10.1002/poc.3019

Anion exchange polymer electrolytes
patent, July 2013


Poly(arylene)-based anion exchange polymer electrolytes
patent, June 2015


Processes for Preparing Of Glucopyranosyl-Substituted Benzyl-Benzene Derivatives
patent-application, September 2011


Process catalysed by bis-trifilmide compounds
patent, August 2010


Anion-conducting polymer, composition, and membrane
patent, September 2009


Metal Triflimidates: Better than Metal Triflates as Catalysts in Organic Synthesis-The Effect of a Highly Delocalized Counteranion
journal, August 2010


Alkaline stability of poly(phenylene)-based anion exchange membranes with various cations
journal, August 2012

  • Hibbs, Michael R.; Hickner, Michael A.; Coughlin, E. Bryan
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 24, p. 1736-1742
  • https://doi.org/10.1002/polb.23149

Sulfonated polyphenylene polymers
patent, November 2007


Palladium-Catalyzed Phosphonation of Polyphenylsulfone
journal, February 2003


Anion exchange polymer electrolytes
patent, June 2015


Transport in sulfonated poly(phenylene)s: Proton conductivity, permeability, and the state of water
journal, May 2006


Evaluation of hydrogen and methanol fuel cell performance of sulfonated diels alder poly(phenylene) membranes
journal, January 2010


Branched Polyphenylenes by Repetitive Diels−Alder Cycloaddition
journal, May 2000


Backbone stability of quaternized polyaromatics for alkaline membrane fuel cells
journal, December 2012


An operationally flexible fuel cell based on quaternary ammonium-biphosphate ion pairs
journal, August 2016


Secondary Benzylation Using Benzyl Alcohols Catalyzed by Lanthanoid, Scandium, and Hafnium Triflate
journal, November 2003


Epoxy-crosslinked sulfonated poly (phenylene) copolymer proton exchange membranes
patent, October 2010


Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells
journal, November 2009


Electrophilic Aromatic Aroylation with CF3‐Bearing Arenecarboxylic Acid Derivatives: Reaction Behavior and Acidic Mediator Dependence
journal, August 2007


Resonance Stabilized Perfluorinated Ionomers for Alkaline Membrane Fuel Cells
journal, September 2013


Poly(phenylene)-based anion exchange membrane
patent, February 2011


Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes
patent, February 2012


Ionomer for alkaline fuel cell
patent-application, September 2012


Structurally-Defined, Sulfo-Phenylated, Oligophenylenes and Polyphenylenes
journal, September 2015


Trifluoromethanesulfonic-Carboxylic Anhydrides, Highly Active Acylating Agents
journal, April 1972


Catalytic Friedel-Crafts Acylation of Aromatic Compounds
journal, April 1972


Factors enabling high mobility of protons and water in perfluorosulfonate membranes under low hydration conditions
journal, February 2014


Carboxylated and Sulfonated Poly(arylene- co -arylene sulfone)s:  Thermostable Polyelectrolytes for Fuel Cell Applications
journal, September 2002


Anion exchange polymer electrolytes
patent, September 2013


Aluminum Chloride as a Solid Is Not a Strong Lewis Acid
journal, April 2006


Polymer Electrolyte Membranes Derived from New Sulfone Monomers with Pendent Sulfonic Acid Groups
journal, December 2010


Anion-conducting polymer, composition, and membrane
patent, December 2010


Poly(phenylene)-based anion exchange polymers and methods thereof
patent-application, July 2017


Anion exchange membranes for alkaline fuel cells: A review
journal, July 2011


Highly selective catalytic Friedel–Crafts acylation and sulfonylation of activated aromatic compounds using indium metal
journal, August 2006


Advanced membrane electrode assemblies for fuel cells
patent, July 2012


Evaluation of Diels–Alder poly(phenylene) anion exchange membranes in all-vanadium redox flow batteries
journal, June 2014


Luminescent material for organic optoelectric device and organic optoelectric device and display device
patent-application, December 2015


Phosphonated and sulfonated polyhphenylsulfone membranes for fuel cell application
journal, November 2006


Trifluoromethanesulfonamides and Related Compounds
journal, November 2012


Ionomeric Poly(phenylene) Prepared by Diels−Alder Polymerization:  Synthesis and Physical Properties of a Novel Polyelectrolyte
journal, June 2005


Hybrid membrane—PSA system for separating oxygen from air
patent, January 2011


High performance, durable polymers including poly(phenylene)
patent, February 2017


An efficient method for aromatic Friedel–Crafts alkylation, acylation, benzoylation, and sulfonylation reactions
journal, January 2001