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Title: Non-noble metal based electro-catalyst compositions for proton exchange membrane based water electrolysis and methods of making

Abstract

The invention provides electro-catalyst compositions for an anode electrode of an acid mediated proton exchange membrane-based water electrolysis system. The compositions include a noble metal component selected from the group consisting of iridium oxide, ruthenium oxide, rhenium oxide and mixtures thereof, and a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, cooper oxide, zirconium oxide, nickel oxide and mixtures thereof. Further, the non-noble metal component can include a dopant. The dopant can be at least one element selected from Groups III, V, VI and VII of the Periodic Table. The compositions can be prepared using any solution based methods involving a surfactant approach or a sol gel approach. Further, the compositions are prepared using noble metal and non-noble metal precursors. Furthermore, a thin film containing the compositions can be deposited onto a substrate to form the anode electrode.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
University of Pittsburgh-Of the Commonwealth System of Higher Education, Pittsburgh, PA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1469329
Patent Number(s):
10,041,179
Application Number:
15/387,100
Assignee:
University of Pittsburgh--Of the Commonwealth System of Higher Education (Pittsburgh, PA)
DOE Contract Number:  
SC0001531
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Dec 21
Country of Publication:
United States
Language:
English
Subject:
33 ADVANCED PROPULSION SYSTEMS; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Kumta, Prashant N., Kadakia, Karan Sandeep, Datta, Moni Kanchan, Velikokhatnyi, Oleg, and Hanumantha, Prashanth Jampani. Non-noble metal based electro-catalyst compositions for proton exchange membrane based water electrolysis and methods of making. United States: N. p., 2018. Web.
Kumta, Prashant N., Kadakia, Karan Sandeep, Datta, Moni Kanchan, Velikokhatnyi, Oleg, & Hanumantha, Prashanth Jampani. Non-noble metal based electro-catalyst compositions for proton exchange membrane based water electrolysis and methods of making. United States.
Kumta, Prashant N., Kadakia, Karan Sandeep, Datta, Moni Kanchan, Velikokhatnyi, Oleg, and Hanumantha, Prashanth Jampani. Tue . "Non-noble metal based electro-catalyst compositions for proton exchange membrane based water electrolysis and methods of making". United States. https://www.osti.gov/servlets/purl/1469329.
@article{osti_1469329,
title = {Non-noble metal based electro-catalyst compositions for proton exchange membrane based water electrolysis and methods of making},
author = {Kumta, Prashant N. and Kadakia, Karan Sandeep and Datta, Moni Kanchan and Velikokhatnyi, Oleg and Hanumantha, Prashanth Jampani},
abstractNote = {The invention provides electro-catalyst compositions for an anode electrode of an acid mediated proton exchange membrane-based water electrolysis system. The compositions include a noble metal component selected from the group consisting of iridium oxide, ruthenium oxide, rhenium oxide and mixtures thereof, and a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, cooper oxide, zirconium oxide, nickel oxide and mixtures thereof. Further, the non-noble metal component can include a dopant. The dopant can be at least one element selected from Groups III, V, VI and VII of the Periodic Table. The compositions can be prepared using any solution based methods involving a surfactant approach or a sol gel approach. Further, the compositions are prepared using noble metal and non-noble metal precursors. Furthermore, a thin film containing the compositions can be deposited onto a substrate to form the anode electrode.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {8}
}

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Works referenced in this record:

Ab-initio study of fluorine-doped tin dioxide: A prospective catalyst support for water electrolysis
journal, February 2011

  • Velikokhatnyi, Oleg I.; Kumta, Prashant N.
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Exploring calcium tantalates and niobates as prospective catalyst supports for water electrolysis
journal, March 2012


Novel (Ir,Sn,Nb)O2 anode electrocatalysts with reduced noble metal content for PEM based water electrolysis
journal, February 2012

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Novel F-doped IrO2 oxygen evolution electrocatalyst for PEM based water electrolysis
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Theoretical Study of Magnesium and Zinc Tantalates and Niobates as Prospective Catalyst Supports for Water Electrolysis
journal, January 2012

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High performance fluorine doped (Sn,Ru)O2 oxygen evolution reaction electro-catalysts for proton exchange membrane based water electrolysis
journal, January 2014


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Transparent conducting F-doped SnO2 thin films grown by pulsed laser deposition
journal, June 2008