Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof

Title: Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof

Full Record
Other Related Research

Abstract

A process for preparing a lithium-rich antiperovskite electrolyte film involves forming a composite target of precursor metal oxide(s) and metal halide(s), and exposing the target to a pulsed laser beam under conditions suitable for depositing a film of lithium-rich antiperovskite on a surface. In some embodiments the process is used to prepare a film of Li.sub.3OCl from a target largely composed of Li.sub.2O and LiCl. Exposure of the target to a pulsed laser beam deposits antiperovskite electrolyte Li.sub.3OCl on a substrate. In another embodiment, sputtering may be used to prepare films of lithium-rich antiperovskites using the composite target of precursor metal oxide(s) and metal halide(s).

Inventors:: Lu, Xujie; Howard, John; Daemen, Luc; Zhao, Yusheng; Jia, Quanxi

Issue Date:: 2018-08-07

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1469104

Patent Number(s):: 10044061

Application Number:: 14/736,109

Assignee:: Los Alamos National Security, LLC (Los Alamos, NM)

Patent Classifications (CPCs):: C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL

Show more

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/553 - based on fluorides
C04B2235/3203 - Lithium oxide or oxide-forming salts thereof
C04B2235/3206 - Magnesium oxides or oxide-forming salts thereof

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C23C14/28 - by wave energy or particle radiation

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3215 - Barium oxides or oxide-forming salts thereof

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3213 - Strontium oxides or oxide-forming salts thereof

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C23C14/06 - characterised by the coating material

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0562 - Solid materials

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/5152 - {based on halogenides other than fluorides}
C04B2235/3208 - Calcium oxide or oxide-forming salts thereof, e.g. lime
C04B2235/3217 - Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES
H01B1/06 - mainly consisting of other non-metallic substances

Show less

DOE Contract Number:: AC52-06NA25396

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Jun 10

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Lu, Xujie, Howard, John, Daemen, Luc, Zhao, Yusheng, and Jia, Quanxi. Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof.  United States: N. p., 2018. 
        Web.

Copy to clipboard


                    Lu, Xujie, Howard, John, Daemen, Luc, Zhao, Yusheng, & Jia, Quanxi. Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof.  United States.

Copy to clipboard


                    Lu, Xujie, Howard, John, Daemen, Luc, Zhao, Yusheng, and Jia, Quanxi. Tue .  
        "Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof".  United States.  https://www.osti.gov/servlets/purl/1469104.

Copy to clipboard


                    
@article{osti_1469104,

  title        = {Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof},

  author       = {Lu, Xujie and Howard, John and Daemen, Luc and Zhao, Yusheng and Jia, Quanxi},

  abstractNote = {A process for preparing a lithium-rich antiperovskite electrolyte film involves forming a composite target of precursor metal oxide(s) and metal halide(s), and exposing the target to a pulsed laser beam under conditions suitable for depositing a film of lithium-rich antiperovskite on a surface. In some embodiments the process is used to prepare a film of Li.sub.3OCl from a target largely composed of Li.sub.2O and LiCl. Exposure of the target to a pulsed laser beam deposits antiperovskite electrolyte Li.sub.3OCl on a substrate. In another embodiment, sputtering may be used to prepare films of lithium-rich antiperovskites using the composite target of precursor metal oxide(s) and metal halide(s).},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {8}

}

Copy to clipboard

Patent:

View Patent

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE Patents and OSTI.GOV collections:

Methods for using atomic layer deposition to produce a film for solid state electrolytes and protective electrode coatings for lithium batteries

Patent Elam, Jeffrey W.; Meng, Xiangbo

A method for using atomic layer deposition to produce a film configured for use in an anode, cathode, or solid state electrolyte of a lithium-ion battery or a lithium-sulfur battery. The method includes repeating a cycle for a predetermined number of times in an inert atmosphere. The cycle includes exposing a substrate to a first precursor, purging the substrate with inert gas, exposing the substrate to a second precursor, and purging the substrate with inert gas. The film is a metal sulfide.
Full Text Available
Electrolytic method for the production of lithium using a lithium-amalgam electrode

Patent Cooper, John F [Castro Valley, CA]; Krikorian, Oscar H [Danville, CA]; Homsy, Robert V [Oakland, CA]

A method for recovering lithium from its molten amalgam by electrolysis of the amalgam in an electrolytic cell containing as a molten electrolyte a fused-salt consisting essentially of a mixture of two or more alkali metal halides, preferably alkali metal halides selected from lithium iodide, lithium chloride, potassium iodide and potassium chloride. A particularly suitable molten electrolyte is a fused-salt consisting essentially of a mixture of at least three components obtained by modifying an eutectic mixture of LiI-KI by the addition of a minor amount of one or more alkali metal halides. The lithium-amalgam fused-salt cell may be used inmore »« less
Full Text Available
Lithium sulfur batteries and electrolytes and sulfur cathodes thereof

Patent Visco, Steven J.; Goncharenko, Nikolay; Nimon, Vitaliy; ...

Lithium sulfur battery cells that use water as an electrolyte solvent provide significant cost reductions. Electrolytes for the battery cells may include water solvent for maintaining electroactive sulfur species in solution during cell discharge and a sufficient amount of a cycle life-enhancing compound that facilitates charging at the cathode. The combination of these two components enhances one or more of the following cell attributes: energy density, power density and cycle life. For instance, in applications where cost per Watt-Hour (Wh) is paramount, such as grid storage and traction applications, the use of an aqueous electrolyte in combination with inexpensive sulfurmore »« less
Full Text Available
Electrolyte membrane, methods of manufacture thereof and articles comprising the same

Patent Tamaki, Ryo [Santa Clarita, CA]; Rice, Steven Thomas [Scotia, NY]; Yeager, Gary William [Rexford, NY]

Disclosed herein is a method of forming an electrolyte membrane comprising forming a mixture; the mixture comprising a polyhydroxy compound, an aromatic polyhalide compound and an alkali metal hydroxide; disposing the mixture on a porous substrate; reacting the mixture to form a proton conductor; and crosslinking the proton conductor to form a cross-linked proton-conducting network. Disclosed herein too is an article comprising a porous substrate; and a crosslinked proton conductor disposed on the porous substrate.
Full Text Available
Electrolyte membrane, methods of manufacture thereof and articles comprising the same

Patent Tamaki, Ryo; Rice, Steven Thomas; Yeager, Gary William

Disclosed herein is a method of forming an electrolyte membrane comprising forming a mixture; the mixture comprising a polyhydroxy compound, an aromatic polyhalide compound and an alkali metal hydroxide; disposing the mixture on a porous substrate; reacting the mixture to form a crosslinked proton conductor; and sulfonating the proton conductor. Disclosed herein too is an article comprising a porous substrate; and a sulfonated crosslinked proton conductor disposed within pores of the porous substrate.
Full Text Available

Similar Records