Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof
Abstract
A process for preparing a lithium-rich antiperovskite electrolyte film involves forming a composite target of precursor metal oxide(s) and metal halide(s), and exposing the target to a pulsed laser beam under conditions suitable for depositing a film of lithium-rich antiperovskite on a surface. In some embodiments the process is used to prepare a film of Li.sub.3OCl from a target largely composed of Li.sub.2O and LiCl. Exposure of the target to a pulsed laser beam deposits antiperovskite electrolyte Li.sub.3OCl on a substrate. In another embodiment, sputtering may be used to prepare films of lithium-rich antiperovskites using the composite target of precursor metal oxide(s) and metal halide(s).
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1469104
- Patent Number(s):
- 10,044,061
- Application Number:
- 14/736,109
- Assignee:
- Los Alamos National Security, LLC (Los Alamos, NM)
- DOE Contract Number:
- AC52-06NA25396
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Jun 10
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Lu, Xujie, Howard, John, Daemen, Luc, Zhao, Yusheng, and Jia, Quanxi. Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof. United States: N. p., 2018.
Web.
Lu, Xujie, Howard, John, Daemen, Luc, Zhao, Yusheng, & Jia, Quanxi. Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof. United States.
Lu, Xujie, Howard, John, Daemen, Luc, Zhao, Yusheng, and Jia, Quanxi. Tue .
"Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof". United States. https://www.osti.gov/servlets/purl/1469104.
@article{osti_1469104,
title = {Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof},
author = {Lu, Xujie and Howard, John and Daemen, Luc and Zhao, Yusheng and Jia, Quanxi},
abstractNote = {A process for preparing a lithium-rich antiperovskite electrolyte film involves forming a composite target of precursor metal oxide(s) and metal halide(s), and exposing the target to a pulsed laser beam under conditions suitable for depositing a film of lithium-rich antiperovskite on a surface. In some embodiments the process is used to prepare a film of Li.sub.3OCl from a target largely composed of Li.sub.2O and LiCl. Exposure of the target to a pulsed laser beam deposits antiperovskite electrolyte Li.sub.3OCl on a substrate. In another embodiment, sputtering may be used to prepare films of lithium-rich antiperovskites using the composite target of precursor metal oxide(s) and metal halide(s).},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {8}
}
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