Carbon composition with hierarchical porosity, and methods of preparation
Abstract
A method for fabricating a porous carbon material possessing a hierarchical porosity, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic component, (iii) a dione component in which carbonyl groups are adjacent, and (iv) an acidic component, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a carbon material possessing a hierarchical porosity comprised of mesopores and macropores. Also described are the resulting hierarchical porous carbon material, a capacitive deionization device in which the porous carbon material is incorporated, as well as methods for desalinating water by use of said capacitive deionization device.
- Inventors:
- Issue Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1467382
- Patent Number(s):
- 10023480
- Application Number:
- 14/496,227
- Assignee:
- UT-BATTELLE, LLC (Oak Ridge, TN)
- Patent Classifications (CPCs):
-
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
- DOE Contract Number:
- AC05-00OR22725
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Sep 25
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Mayes, Richard T., and Dai, Sheng. Carbon composition with hierarchical porosity, and methods of preparation. United States: N. p., 2018.
Web.
Mayes, Richard T., & Dai, Sheng. Carbon composition with hierarchical porosity, and methods of preparation. United States.
Mayes, Richard T., and Dai, Sheng. Tue .
"Carbon composition with hierarchical porosity, and methods of preparation". United States. https://www.osti.gov/servlets/purl/1467382.
@article{osti_1467382,
title = {Carbon composition with hierarchical porosity, and methods of preparation},
author = {Mayes, Richard T. and Dai, Sheng},
abstractNote = {A method for fabricating a porous carbon material possessing a hierarchical porosity, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic component, (iii) a dione component in which carbonyl groups are adjacent, and (iv) an acidic component, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a carbon material possessing a hierarchical porosity comprised of mesopores and macropores. Also described are the resulting hierarchical porous carbon material, a capacitive deionization device in which the porous carbon material is incorporated, as well as methods for desalinating water by use of said capacitive deionization device.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}
Works referenced in this record:
Synthesis of a Large-Scale Highly Ordered Porous Carbon Film by Self-Assembly of Block Copolymers
journal, November 2004
- Liang, Chengdu; Hong, Kunlun; Guiochon, Georges A.
- Angewandte Chemie International Edition, Vol. 43, Issue 43, p. 5785-5789
Carbon aerogels for electrochemical applications
journal, April 1998
- Pekala, R. W.; Farmer, J. C.; Alviso, C. T.
- Journal of Non-Crystalline Solids, Vol. 225, p. 74-80
Highly ordered porous carbon materials having well defined nanostructures and method of synthesis
patent-application, March 2006
- Dai, Sheng; Liang, Chengdu
- US Patent Application 10/938895; 20060057051
Robust carbon monolith having hierarchical porosity
patent, November 2008
- Dai, Sheng; Guiochon, Georges; Liang, Chengdu
- US Patent Document 7,449,165
Formation of Mesoporous Carbon With a Face-Centered-CubicFdm Structure and Bimodal Architectural Pores From the Reverse Amphiphilic Triblock Copolymer PPO-PEO-PPO
journal, February 2007
- Huang, Yan; Cai, Huaqiang; Yu, Ting
- Angewandte Chemie International Edition, Vol. 46, Issue 7, p. 1089-1093
Hierarchical Porosity Components by Infiltration of a Ceramic Foam
journal, July 2007
- Costacurta, Stefano; Biasetto, Lisa; Pippel, Eckhard
- Journal of the American Ceramic Society, Vol. 90, Issue 7, p. 2172-2177
Fabricating solid carbon porous electrodes from powders
patent, June 1997
- Kaschmitter, James; Tran, Tri; Feikert, John
- US Patent Document 5,636,437
Planar, flow-through, electric, double-layer capacitor and a method of treating liquids with the capacitor
patent, July 1996
- Otowa, Toshiro
- US Patent Document 5,538,611
A Facile Aqueous Route to Synthesize Highly Ordered Mesoporous Polymers and Carbon Frameworks with Ia 3̄ d Bicontinuous Cubic Structure
journal, October 2005
- Zhang, Fuqiang; Meng, Yan; Gu, Dong
- Journal of the American Chemical Society, Vol. 127, Issue 39, p. 13508-13509
Synthesis of a carbon monolith with trimodal pores
journal, January 2003
- Shi, Zhi-Guo; Feng, Yu-Qi; Xu, Li
- Carbon, Vol. 41, Issue 13, p. 2677-2679
Recent Progress in the Synthesis of Porous Carbon Materials
journal, August 2006
- Lee, J.; Kim, J.; Hyeon, T.
- Advanced Materials, Vol. 18, Issue 16, p. 2073-2094
Synthesis of Mesoporous Carbon Materials via Enhanced Hydrogen-Bonding Interaction
journal, April 2006
- Liang, Chengdu; Dai, Sheng
- Journal of the American Chemical Society, Vol. 128, Issue 16, p. 5316-5317
Treatment of brackish produced water using carbon aerogel-based capacitive deionization technology
journal, May 2008
- Xu, Pei; Drewes, Jörg E.; Heil, Dean
- Water Research, Vol. 42, Issue 10-11, p. 2605-2617
Method and apparatus for capacitive deionization and electrochemical purification and regeneration of electrodes
patent, October 2001
- Tran, Tri; Farmer, Joseph; Murguia, Laura
- US Patent Document 6,309,532
Method for the Synthesis of Porous Carbon Materials
patent-application, November 2007
- Foley, Henry C.; Rajagopalan, Ramakrishnan; Marencic, Andrew P.
- US Patent Application 11/740425; 20070253887
Method for making thin carbon foam electrodes
patent, August 1999
- Pekala, Richard; Mayer, Steven; Kaschmitter, James
- US Patent Document 5,932,185
Supercapacitor and electrochemical apparatus for water purification
patent, November 2010
- Kang, Hyo-rang; Yang, Ho-jung
- US Patent Document 7,835,137
Synthesis of ordered mesoporous carbons with channel structure from an organic–organic nanocomposite
journal, January 2005
- Tanaka, Shunsuke; Nishiyama, Norikazu; Egashira, Yasuyuki
- Chemical Communications, Vol. 0, Issue 16, p. 2125-2127
Meso/Macroporous Carbon Monoliths from Polymeric Foams
journal, November 2004
- Alvarez, S.; Esquena, J.; Solans, C.
- Advanced Engineering Materials, Vol. 6, Issue 11, p. 897-899
Ordered mesoporous carbons and method for manufacturing same
patent-application, June 2008
- Addiego, William P.; Baca, Andra S.; Dawes, Steven B.
- US Patent Application 11/899002; 20080152577
High surface area, electrically conductive nanocarbon-supported metal oxide
patent-application, July 2010
- Worsley, Marcus A.; Han, Thomas Yong-Jin; Kuntz, Joshua D.
- US Patent Application 12/694425; 20100190639
Molecular Waterwheel (Noria) from a Simple Condensation of Resorcinol and an Alkanedial
journal, December 2006
- Kudo, Hiroto; Hayashi, Rieko; Mitani, Kouji
- Angewandte Chemie International Edition, Vol. 45, Issue 47, p. 7948-7952
Preparation of activated mesoporous carbons for electrosorption of ions from aqueous solutions
journal, January 2010
- Wang, Xiqing; Lee, Je Seung; Tsouris, Costas
- Journal of Materials Chemistry, Vol. 20, Issue 22, p. 4602-4608
Facile Synthesis of Ordered Mesoporous Carbons with High Thermal Stability by Self-Assembly of Resorcinol−Formaldehyde and Block Copolymers under Highly Acidic Conditions
journal, July 2008
- Wang, Xiqing; Liang, Chengdu; Dai, Sheng
- Langmuir, Vol. 24, Issue 14, p. 7500-7505
Capacitive deionization characteristics of nanostructured carbon aerogel electrodes synthesized via ambient drying
journal, October 2007
- Jung, Hae-Hyun; Hwang, Sung-Woo; Hyun, Sang-Hoon
- Desalination, Vol. 216, Issue 1-3, p. 377-385
Composite Carbon Electrodes Useful In Electric Double Layer Capacitors And Capacitive Deionization Methods of Making The Same
patent-application, December 2009
- Baca, Adra Smith; Bourcier, Roy JOseph; St. Clair, Todd P.
- US Patent Application 11/848637; 20090305138
High Surface Area Graphitized Carbon and Processes for Making Same
patent-application, August 2009
- Sun, Yipeng; Shen, Jian-Ping; Rice, Gordon
- US Patent Application 12/033859; 20090208780
Electrode Stack For Capacitive Device
patent-application, December 2009
- Bourcier, Roy JOseph; St Clair, Todd P.; Nadjadi, Andrew
- US Patent Application 12/146668; 20090320253
Biobased composites from glyoxal–phenolic resins and sisal fibers
journal, March 2010
- Ramires, Elaine C.; Megiatto, Jackson D.; Gardrat, Christian
- Bioresource Technology, Vol. 101, Issue 6, p. 1998-2006
Robust carbon monolith having hierarchical porosity
patent-application, August 2005
- Dai, Sheng; Guiochon, Georges A.; Liang, Chengdu
- US Patent Application 10/770734; 20050169829
Highly microporous carbons and process of manufacture
patent, October 1999
- Baker, Frederick; Beckler, Robert; Miller, James
- US Patent Document 5,965,483
Capacitive Device
patent-application, June 2009
- Bourcier, Roy Joseph
- US Patent Application 11/947109; 20090141422
Carbon/carbon composite materials and use thereof in electrochemical cells
patent, July 1998
- Mrotek, Edward; Reichman, Benjamin; Yin, MengPing
- US Patent Document 5,776,633
Ion-removal from water using activated carbon electrodes
patent, April 2001
- Gadkaree, Kishor; Mach, Joseph; Stempin, John
- US Patent Document 6,214,204
Electrosorption capacitance of nanostructured carbon-based materials
journal, October 2006
- Hou, Chia-Hung; Liang, Chengdu; Yiacoumi, Sotira
- Journal of Colloid and Interface Science, Vol. 302, Issue 1, p. 54-61
Consolidated amorphous carbon materials, their manufacture and use
patent, February 2002
- Nesbitt, Carl; Sun, Xiaowei
- US Patent Document 6,350,520
Block-Copolymer assisted synthesis of hierarchical carbon monoliths suitable as supercapacitor electrodes
journal, January 2010
- Carriazo, Daniel; Picó, Fernando; Gutiérrez, María C.
- Journal of Materials Chemistry, Vol. 20, Issue 4, p. 773-780
Facile synthesis of ordered mesoporous carbons from F108/resorcinol–formaldehyde composites obtained in basic media
journal, January 2007
- Liu, Changyi; Li, Lixia; Song, Huaihe
- Chemical Communications, Vol. 0, Issue 7, p. 757-759
Hierarchical ordered mesoporous carbon from phloroglucinol-glyoxal and its application in capacitive deionization of brackish water
journal, January 2010
- Mayes, Richard T.; Tsouris, Costas; Kiggans Jr., James O.
- Journal of Materials Chemistry, Vol. 20, Issue 39, p. 8674-8678
Method and apparatus for capacitive deionization and electrochemical purification and regeneration of electrodes
patent, September 1999
- Farmer, Joseph
- US Patent Document 5,954,937
Generation of Hierarchical Meso- and Macroporous Carbon from Mesophase Pitch by Spinodal Decomposition using Polymer Templates
journal, November 2007
- Adelhelm, P.; Hu, Y.-S.; Chuenchom, L.
- Advanced Materials, Vol. 19, Issue 22, p. 4012-4017
Electrode stack for capacitive device
patent, August 2010
- Bourcier, Roy; St. Clair, Todd; Nadjadi, Andrew
- US Patent Document 7,766,981
Mesoporous Carbon Materials: Synthesis and Modification
journal, May 2008
- Liang, Chengdu; Li, Zuojiang; Dai, Sheng
- Angewandte Chemie International Edition, Vol. 47, Issue 20, p. 3696-3717
Mesoporous carbons
patent, March 1984
- Everett, Douglas; Bligh, Stephen; Rojas, Fernando
- US Patent Document 4,439,349
Ordered Mesoporous Polymers and Homologous Carbon Frameworks: Amphiphilic Surfactant Templating and Direct Transformation
journal, November 2005
- Meng, Yan; Gu, Dong; Zhang, Fuqiang
- Angewandte Chemie International Edition, Vol. 44, Issue 43, p. 7053-7059
Dual Phase Separation for Synthesis of Bimodal Meso-/Macroporous Carbon Monoliths
journal, May 2009
- Liang, Chengdu; Dai, Sheng
- Chemistry of Materials, Vol. 21, Issue 10, p. 2115-2124
Non-woven cover for containing and abating odiferous organic emanations
patent, March 2012
- Wenstrup, David; Raghavendran, Venkatkrishna
- US Patent Document 8,137,957