skip to main content
DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Metal-organic frameworks with a high density of highly charged exposed metal cation sites

Abstract

The disclosure provides for Metal-Organic Frameworks comprising M.sub.2 (m-dobdc)-based cores, and methods of use thereof, including gas separation, gas storage, sensing, and other applications utilizing a high density of exposed metal cation sites.

Inventors:
; ;
Issue Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1464768
Patent Number(s):
10,035,127
Application Number:
15/033,748
Assignee:
The Regents of the University of California (Oakland, CA)
DOE Contract Number:  
AC02-05CH11231; AR0000251
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Nov 04
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Long, Jeffrey R., Kapelewski, Matthew T., and Geier, Stephen J. Metal-organic frameworks with a high density of highly charged exposed metal cation sites. United States: N. p., 2018. Web.
Long, Jeffrey R., Kapelewski, Matthew T., & Geier, Stephen J. Metal-organic frameworks with a high density of highly charged exposed metal cation sites. United States.
Long, Jeffrey R., Kapelewski, Matthew T., and Geier, Stephen J. Tue . "Metal-organic frameworks with a high density of highly charged exposed metal cation sites". United States. https://www.osti.gov/servlets/purl/1464768.
@article{osti_1464768,
title = {Metal-organic frameworks with a high density of highly charged exposed metal cation sites},
author = {Long, Jeffrey R. and Kapelewski, Matthew T. and Geier, Stephen J.},
abstractNote = {The disclosure provides for Metal-Organic Frameworks comprising M.sub.2 (m-dobdc)-based cores, and methods of use thereof, including gas separation, gas storage, sensing, and other applications utilizing a high density of exposed metal cation sites.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}

Patent:

Save / Share:

Works referenced in this record:

M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites
journal, August 2014

  • Kapelewski, Matthew T.; Geier, Stephen J.; Hudson, Matthew R.
  • Journal of the American Chemical Society, Vol. 136, Issue 34, p. 12119-12129
  • DOI: 10.1021/ja506230r

Enhanced H2 Adsorption in Isostructural Metal−Organic Frameworks with Open Metal Sites: Strong Dependence of the Binding Strength on Metal Ions
journal, November 2008

  • Zhou, Wei; Wu, Hui; Yildirim, Taner
  • Journal of the American Chemical Society, Vol. 130, Issue 46, p. 15268-15269
  • DOI: 10.1021/ja807023q

Combinatorial Approach to the Hydrothermal Synthesis of Zeolites
journal, March 1998


Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal–linker complexes
journal, January 2011

  • Barman, Samir; Furukawa, Hiroyasu; Blacque, Olivier
  • Chemical Communications, Vol. 47, Issue 43, p. 11882-11884
  • DOI: 10.1039/c1cc14387e

Metal−Organic Frameworks As Templates for Nanoscale NaAlH4
journal, September 2009

  • Bhakta, Raghunandan K.; Herberg, Julie L.; Jacobs, Benjamin
  • Journal of the American Chemical Society, Vol. 131, Issue 37, p. 13198-13199
  • DOI: 10.1021/ja904431x

Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008

  • Britt, D.; Tranchemontagne, D.; Yaghi, O. M.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 33, p. 11623-11627
  • DOI: 10.1073/pnas.0804900105

Post-Synthetic Modification of Tagged Metal-Organic Frameworks
journal, October 2008

  • Burrows, Andrew D.; Frost, Christopher G.; Mahon, Mary F.
  • Angewandte Chemie International Edition, Vol. 47, Issue 44, p. 8482-8486
  • DOI: 10.1002/anie.200802908

Highly porous and stable metal–organic frameworks for uranium extraction
journal, January 2013

  • Carboni, Michaël; Abney, Carter W.; Liu, Shubin
  • Chemical Science, Vol. 4, Issue 6, p. 2396-2402
  • DOI: 10.1039/c3sc50230a

Photoluminescent Metal−Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates
journal, February 2003

  • Chen, Wei; Wang, Jia-Yu; Chen, Cheng
  • Inorganic Chemistry, Vol. 42, Issue 4, p. 944-946
  • DOI: 10.1021/ic025871j

Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates
journal, June 2009

  • Chen, Long; Kim, Jangbae; Ishizuka, Tomoya
  • Journal of the American Chemical Society, Vol. 131, Issue 21, p. 7287-7292
  • DOI: 10.1021/ja901357h

Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014

  • Chen, Binling; Yang, Zhuxian; Zhu, Yanqiu
  • Journal of Materials Chemistry A, Vol. 2, Issue 40, p. 16811-16831
  • DOI: 10.1039/C4TA02984D

Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition
journal, July 2012

  • Choi, Sang Beom; Furukawa, Hiroyasu; Nam, Hye Jin
  • Angewandte Chemie International Edition, Vol. 51, Issue 35, p. 8791-8795
  • DOI: 10.1002/anie.201202925

Concomitant Formation of N-Heterocyclic Carbene−Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions
journal, July 2009

  • Chun, Jiseul; Jung, Il Gu; Kim, Hae Jin
  • Inorganic Chemistry, Vol. 48, Issue 14, p. 6353-6355
  • DOI: 10.1021/ic900846s

Cu2O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species
journal, April 2010

  • Chun, Jiseul; Lee, Han Sol; Jung, Il Gu
  • Organometallics, Vol. 29, Issue 7, p. 1518-1521
  • DOI: 10.1021/om900768w

A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst
journal, August 2002

  • Corma, Avelino; Díaz-Cabañas, María J.; Martínez-Triguero, Joaquín
  • Nature, Vol. 418, Issue 6897, p. 514-517
  • DOI: 10.1038/nature00924

From MOFs to zeolites: zirconium sites for epoxide rearrangement
journal, January 2013

  • Corma, Avelino; Orozco, Lina M.; Renz, Michael
  • New Journal of Chemistry, Vol. 37, Issue 11, p. 3496-3502
  • DOI: 10.1039/c3nj00551h

Metal-Organic Frameworks Incorporating Copper-Complexed Rotaxanes
journal, January 2012

  • Coskun, Ali; Hmadeh, Mohamad; Barin, Gokhan
  • Angewandte Chemie International Edition, Vol. 51, Issue 9, p. 2160-2163
  • DOI: 10.1002/anie.201107873

Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure (Eur. J. Inorg. Chem. 10/2008)
journal, April 2008

  • Costa, José Sánchez; Gamez, Patrick; Black, Cory A.
  • European Journal of Inorganic Chemistry, Vol. 2008, Issue 10, p. 1539-1539
  • DOI: 10.1002/ejic.200890023

Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005

  • Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
  • Science, Vol. 310, Issue 5751, p. 1166-1170
  • DOI: 10.1126/science.1120411

Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
journal, October 2007

  • Côté, Adrien P.; El-Kaderi, Hani M.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 129, Issue 43, p. 12914-12915
  • DOI: 10.1021/ja0751781

Synthesis of a Zinc(II) Imidazolium Dicarboxylate Ligand Metal−Organic Framework (MOF): a Potential Precursor to MOF-Tethered N-Heterocyclic Carbene Compounds
journal, February 2010

  • Crees, Rachel S.; Cole, Marcus L.; Hanton, Lyall R.
  • Inorganic Chemistry, Vol. 49, Issue 4, p. 1712-1719
  • DOI: 10.1021/ic9021118

In Situ Hydrothermal Growth of Metal−Organic Framework 199 Films on Stainless Steel Fibers for Solid-Phase Microextraction of Gaseous Benzene Homologues
journal, December 2009

  • Cui, Xiao-Yan; Gu, Zhi-Yuan; Jiang, Dong-Qing
  • Analytical Chemistry, Vol. 81, Issue 23, p. 9771-9777
  • DOI: 10.1021/ac901663x

Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
journal, July 2009

  • Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin
  • Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786
  • DOI: 10.1021/ja903411w

Role of Copper Species in the Oxidative Dimerization of Arylboronic Acids: Synthesis of Symmetrical Biaryls
journal, December 2003

  • Demir, Ayhan S.; Reis, Ömer; Emrullahoglu, Mustafa
  • The Journal of Organic Chemistry, Vol. 68, Issue 26, p. 10130-10134
  • DOI: 10.1021/jo034680a

Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012


Metal–organic frameworks as heterogeneous catalysts for oxidation reactions
journal, January 2011

  • Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes; Garcia, Hermenegildo
  • Catalysis Science & Technology, Vol. 1, Issue 6, p. 856-867
  • DOI: 10.1039/c1cy00068c

Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide
journal, January 2009

  • Dietzel, Pascal D. C.; Besikiotis, Vasileios; Blom, Richard
  • Journal of Materials Chemistry, Vol. 19, Issue 39, p. 7362-7370
  • DOI: 10.1039/b911242a

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008

  • Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
  • Angewandte Chemie International Edition, Vol. 47, Issue 4, p. 677-680
  • DOI: 10.1002/anie.200705020

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008

  • Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
  • Angewandte Chemie, Vol. 120, Issue 4, p. 689-692
  • DOI: 10.1002/ange.200705020

Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013


An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids
journal, January 2002

  • Koza, Darrell J.; Carita, Eric
  • Synthesis, Vol. 2002, Issue 15, p. 2183-2186
  • DOI: 10.1055/s-2002-34855

Evaluating metal–organic frameworks for natural gas storage
journal, January 2014

  • Mason, Jarad A.; Veenstra, Mike; Long, Jeffrey R.
  • Chemical Science, Vol. 5, Issue 1, p. 32-51
  • DOI: 10.1039/C3SC52633J

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012

  • McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.
  • Journal of the American Chemical Society, Vol. 134, Issue 16, p. 7056-7065
  • DOI: 10.1021/ja300034j

Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
journal, October 2010

  • Mendoza-Cortés, José L.; Han, Sang Soo; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry A, Vol. 114, Issue 40, p. 10824-10833
  • DOI: 10.1021/jp1044139

Framework mobility in the metal–organic framework crystal IRMOF-3: Evidence for aromatic ring and amine rotation
journal, October 2011


Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012

  • Morris, William; Volosskiy, Boris; Demir, Selcuk
  • Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
  • DOI: 10.1021/ic300825s

Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011

  • O’Keeffe, Michael; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 675-702
  • DOI: 10.1021/cr200205j

A Metal−Organic Framework with Covalently Bound Organometallic Complexes
journal, July 2010

  • Oisaki, Kounosuke; Li, Qiaowei; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 132, Issue 27, p. 9262-9264
  • DOI: 10.1021/ja103016y

A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination
journal, October 2011

  • Song, Jie; Luo, Zhen; Britt, David K.
  • Journal of the American Chemical Society, Vol. 133, Issue 42, p. 16839-16846
  • DOI: 10.1021/ja203695h

A Thermally Stable Pt/Y-Based Metal−Organic Framework:  Exploring the Accessibility of the Metal Centers with Spectroscopic Methods Using H2O, CH3OH, and CH3CN as Probes
journal, November 2006

  • Szeto, Kai Chung; Lillerud, Karl Petter; Tilset, Mats
  • The Journal of Physical Chemistry B, Vol. 110, Issue 43, p. 21509-21520
  • DOI: 10.1021/jp0634611

Characterization of a New Porous Pt-Containing Metal-Organic Framework Containing Potentially Catalytically Active Sites:  Local Electronic Structure at the Metal Centers
journal, January 2007

  • Szeto, Kai Chung; Prestipino, Carmelo; Lamberti, Carlo
  • Chemistry of Materials, Vol. 19, Issue 2, p. 211-220
  • DOI: 10.1021/cm0616432

Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach
journal, July 2008

  • Tanabe, Kristine K.; Wang, Zhenqiang; Cohen, Seth M.
  • Journal of the American Chemical Society, Vol. 130, Issue 26, p. 8508-8517
  • DOI: 10.1021/ja801848j

Facile Synthesis of a Highly Crystalline, Covalently Linked Porous Boronate Network
journal, October 2006

  • Tilford, R. William; Gemmill, William R.; zur Loye, Hans-Conrad
  • Chemistry of Materials, Vol. 18, Issue 22, p. 5296-5301
  • DOI: 10.1021/cm061177g

Hydrogen Storage in New Metal–Organic Frameworks
journal, June 2012

  • Tranchemontagne, David J.; Park, Kyo Sung; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry C, Vol. 116, Issue 24, p. 13143-13151
  • DOI: 10.1021/jp302356q

Role of Exposed Metal Sites in Hydrogen Storage in MOFs
journal, July 2008

  • Vitillo, Jenny G.; Regli, Laura; Chavan, Sachin
  • Journal of the American Chemical Society, Vol. 130, Issue 26, p. 8386-8396
  • DOI: 10.1021/ja8007159

Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007

  • Wang, Zhenqiang; Cohen, Seth M.
  • Journal of the American Chemical Society, Vol. 129, Issue 41, p. 12368-12369
  • DOI: 10.1021/ja074366o

Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions
journal, September 2005


Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of CuII(1,4-C4H4N2)(C4O4)(OH2)4
journal, July 1995

  • Yaghi, O. M.; Li, Guangming; Groy, T. L.
  • Journal of Solid State Chemistry, Vol. 117, Issue 2, p. 256-260
  • DOI: 10.1006/jssc.1995.1271

CH4 storage and CO2 capture in highly porous zirconium oxide based metal–organic frameworks
journal, January 2012

  • Yang, Qingyuan; Guillerm, Vincent; Ragon, Florence
  • Chemical Communications, Vol. 48, Issue 79, p. 9831-9833
  • DOI: 10.1039/c2cc34714h

Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008

  • Wang, Zhenqiang; Cohen, Seth M.
  • Angewandte Chemie International Edition, Vol. 47, Issue 25, p. 4699-4702
  • DOI: 10.1002/anie.200800686

Introduction to Metal–Organic Frameworks
journal, September 2011

  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

Covalent modification of a metal–organic framework with isocyanates: probing substrate scope and reactivity
journal, January 2008

  • Dugan, Emily; Wang, Zhenqiang; Okamura, Marilyn
  • Chemical Communications, Vol. 0, Issue 29, p. 3366-3368
  • DOI: 10.1039/B806150E

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

  • Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
  • Science, Vol. 295, Issue 5554, p. 469-472
  • DOI: 10.1126/science.1067208

A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials
journal, November 2005

  • Forster, Paul M.; Stock, Norbert; Cheetham, Anthony K.
  • Angewandte Chemie International Edition, Vol. 44, Issue 46, p. 7608-7611
  • DOI: 10.1002/anie.200501766

Isomers of Metal–Organic Complex Arrays
journal, June 2012

  • Fracaroli, Alejandro M.; Tashiro, Kentaro; Yaghi, Omar M.
  • Inorganic Chemistry, Vol. 51, Issue 12, p. 6437-6439
  • DOI: 10.1021/ic300744x

Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
journal, June 2014

  • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
  • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866
  • DOI: 10.1021/ja503296c

Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals
journal, September 2011

  • Furukawa, Hiroyasu; Go, Yong Bok; Ko, Nakeun
  • Inorganic Chemistry, Vol. 50, Issue 18, p. 9147-9152
  • DOI: 10.1021/ic201376t

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
journal, July 2009

  • Furukawa, Hiroyasu; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8875-8883
  • DOI: 10.1021/ja9015765

Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014

  • Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao
  • Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
  • DOI: 10.1021/ja500330a

Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry
journal, September 2009

  • Gadzikwa, Tendai; Farha, Omar K.; Malliakas, Christos D.
  • Journal of the American Chemical Society, Vol. 131, Issue 38, p. 13613-13615
  • DOI: 10.1021/ja904189d

Adsorption of Harmful Organic Vapors by Flexible Hydrophobic Bis-pyrazolate Based MOFs
journal, March 2010

  • Galli, S.; Masciocchi, N.; Colombo, V.
  • Chemistry of Materials, Vol. 22, Issue 5, p. 1664-1672
  • DOI: 10.1021/cm902899t

High Methane Storage Capacity in Aluminum Metal–Organic Frameworks
journal, February 2014

  • Gándara, Felipe; Furukawa, Hiroyasu; Lee, Seungkyu
  • Journal of the American Chemical Society, Vol. 136, Issue 14, p. 5271-5274
  • DOI: 10.1021/ja501606h

Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method
journal, June 2012

  • Gándara, Felipe; Uribe-Romo, Fernando J.; Britt, David K.
  • Chemistry - A European Journal, Vol. 18, Issue 34, p. 10595-10601
  • DOI: 10.1002/chem.201103433

Crystallography of metal–organic frameworks
journal, October 2014


Isoreticular synthesis and modification of frameworks with the UiO-66 topology
journal, January 2010

  • Garibay, Sergio J.; Cohen, Seth M.
  • Chemical Communications, Vol. 46, Issue 41, p. 7700-7702
  • DOI: 10.1039/c0cc02990d

Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework
journal, October 2011

  • Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A.
  • Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315
  • DOI: 10.1021/ja206525x

Homogeneous and heterogenized Au(III) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids
journal, January 2005

  • González-Arellano, C.; Corma, A.; Iglesias, M.
  • Chemical Communications, Vol. 0, Issue 15, p. 1990-1992
  • DOI: 10.1039/B418897G

“Clickable” Metal−Organic Framework
journal, November 2008

  • Goto, Yuta; Sato, Hiroki; Shinkai, Seiji
  • Journal of the American Chemical Society, Vol. 130, Issue 44, p. 14354-14355
  • DOI: 10.1021/ja7114053

Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
journal, September 2008

  • Han, Sang Soo; Furukawa, Hiroyasu; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 130, Issue 35, p. 11580-11581
  • DOI: 10.1021/ja803247y

Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air
journal, March 2009

  • Kirai, Naohiro; Yamamoto, Yoshihiko
  • European Journal of Organic Chemistry, Vol. 2009, Issue 12, p. 1864-1867
  • DOI: 10.1002/ejoc.200900173