DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Metal-organic frameworks with a high density of highly charged exposed metal cation sites

Abstract

The disclosure provides for Metal-Organic Frameworks comprising M.sub.2 (m-dobdc)-based cores, and methods of use thereof, including gas separation, gas storage, sensing, and other applications utilizing a high density of exposed metal cation sites.

Inventors:
; ;
Issue Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1464768
Patent Number(s):
10035127
Application Number:
15/033,748
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
DOE Contract Number:  
AC02-05CH11231; AR0000251
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Nov 04
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Long, Jeffrey R., Kapelewski, Matthew T., and Geier, Stephen J. Metal-organic frameworks with a high density of highly charged exposed metal cation sites. United States: N. p., 2018. Web.
Long, Jeffrey R., Kapelewski, Matthew T., & Geier, Stephen J. Metal-organic frameworks with a high density of highly charged exposed metal cation sites. United States.
Long, Jeffrey R., Kapelewski, Matthew T., and Geier, Stephen J. Tue . "Metal-organic frameworks with a high density of highly charged exposed metal cation sites". United States. https://www.osti.gov/servlets/purl/1464768.
@article{osti_1464768,
title = {Metal-organic frameworks with a high density of highly charged exposed metal cation sites},
author = {Long, Jeffrey R. and Kapelewski, Matthew T. and Geier, Stephen J.},
abstractNote = {The disclosure provides for Metal-Organic Frameworks comprising M.sub.2 (m-dobdc)-based cores, and methods of use thereof, including gas separation, gas storage, sensing, and other applications utilizing a high density of exposed metal cation sites.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 31 00:00:00 EDT 2018},
month = {Tue Jul 31 00:00:00 EDT 2018}
}

Works referenced in this record:

Adsorption process with on-line adsorbent removal
patent-application, November 2006


Crystallography of metal–organic frameworks
journal, October 2014


Process for preparing an organometallic framework material
patent-application, July 2005


Covalently linked organic frameworks and polyhedra
patent, September 2009


Fluorinated metal-organic frameworks for gas storage
patent, January 2013


Gas storage system
patent-application, December 2004


Process for preparing hydrogen peroxide from the elements
patent-application, March 2006


1,2,3-triazole based metal-organic framework as photo-active materials
patent-application, November 2011


Metal−Organic Frameworks As Templates for Nanoscale NaAlH4
journal, September 2009

  • Bhakta, Raghunandan K.; Herberg, Julie L.; Jacobs, Benjamin
  • Journal of the American Chemical Society, Vol. 131, Issue 37, p. 13198-13199
  • https://doi.org/10.1021/ja904431x

Donor-acceptor rotaxanes with tetracationic cyclophane ring
journal, September 2012


PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS
patent-application, August 2007


Bone graft composition
patent-application, October 2007


Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent, October 2007


Air Collector with Functionalized Ion Exchange Membrane for Capturing Ambient CO2
patent-application, September 2007


Gas storage system
patent, December 2007


Covalently linked organic frameworks and polyhedra
patent-application, July 2006


Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
journal, July 2009

  • Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin
  • Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786
  • https://doi.org/10.1021/ja903411w

Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide
journal, January 2009


Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
journal, October 2007

  • Côté, Adrien P.; El-Kaderi, Hani M.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 129, Issue 43, p. 12914-12915
  • https://doi.org/10.1021/ja0751781

Metal catalyzed reactions
patent, February 2004


CH4 storage and CO2 capture in highly porous zirconium oxide based metal–organic frameworks
journal, January 2012


Metal organic framework—polymer mixed matrix membranes
patent, December 2009


Polymerisation and oligomerisation catalysts
patent, June 2007


Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent-application, December 2004


Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method
journal, June 2012


Gas sensor incorporating a porous framework
patent, May 2014


Bleaching composition for dry cleaning containing transition metal bleach catalyst
patent, November 2002


Homogeneous and heterogenized Au(III) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids
journal, January 2005


A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008


Reversible ethylene oxide capture in porous frameworks
patent, April 2014


Adsorption of Harmful Organic Vapors by Flexible Hydrophobic Bis-pyrazolate Based MOFs
journal, March 2010


Isoreticular synthesis and modification of frameworks with the UiO-66 topology
journal, January 2010


Evaluating metal–organic frameworks for natural gas storage
journal, January 2014


“Clickable” Metal−Organic Framework
journal, November 2008


Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials
patent-application, August 2009


Gas sensor incorporating a porous framework
patent, July 2013


Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012


Framework mobility in the metal–organic framework crystal IRMOF-3: Evidence for aromatic ring and amine rotation
journal, October 2011


Crystalline membranes
patent-application, January 2005


Synthesis of inorganic membranes on supports
patent, July 1998


Polymeric Foams with Nanocellular Morphology and Methods for Making Them
patent-application, October 2009


Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005


Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011


A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008


Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach
journal, July 2008


A zinc(ii) metal–organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers
journal, January 2011


Shaped bodies containing metal-organic frameworks
patent-application, December 2003


Highly porous and stable metal–organic frameworks for uranium extraction
journal, January 2013


Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure (Eur. J. Inorg. Chem. 10/2008)
journal, April 2008


Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
journal, September 2008


Magnesium Butylisophthalate as a Porous Metal Organic Framework
patent-application, February 2010


Organic Porous Materials Comprising Shape-Persistent Three-Dimensional Molecular Cage Building Blocks
patent-application, February 2013


Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition
journal, July 2012


Zeolite synthesis using an alcohol or like molecules
patent, November 1992


Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates
journal, June 2009


Metal-organic polyhedra
patent-application, June 2005


Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
journal, June 2014

  • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
  • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866
  • https://doi.org/10.1021/ja503296c

Shaped bodies containing metal-organic frameworks
patent, May 2005


Metal-organic framework materials for gaseous hydrocarbon storage
patent, March 2008


Metal-organic framework materials for gaseous hydrocarbon storage
patent-application, August 2006


Metal-organic frameworks with exceptionally large pore aperatures
patent, July 2015


Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent-application, April 2003


Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014


Process for preparing and organometallic framework material
patent, August 2008


Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air
journal, March 2009


A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination
journal, October 2011


Introduction to Metal–Organic Frameworks
journal, September 2011


Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
journal, July 2009


Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008


Isomers of Metal–Organic Complex Arrays
journal, June 2012


Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry
journal, September 2009

  • Gadzikwa, Tendai; Farha, Omar K.; Malliakas, Christos D.
  • Journal of the American Chemical Society, Vol. 131, Issue 38, p. 13613-13615
  • https://doi.org/10.1021/ja904189d

Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions
journal, September 2005


Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
journal, October 2010

  • Mendoza-Cortés, José L.; Han, Sang Soo; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry A, Vol. 114, Issue 40, p. 10824-10833
  • https://doi.org/10.1021/jp1044139

Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework
journal, October 2011

  • Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A.
  • Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315
  • https://doi.org/10.1021/ja206525x

Post-Synthetic Modification of Tagged Metal-Organic Frameworks
journal, October 2008


M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites
journal, August 2014

  • Kapelewski, Matthew T.; Geier, Stephen J.; Hudson, Matthew R.
  • Journal of the American Chemical Society, Vol. 136, Issue 34, p. 12119-12129
  • https://doi.org/10.1021/ja506230r

Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of CuII(1,4-C4H4N2)(C4O4)(OH2)4
journal, July 1995


Synthesis of a Zinc(II) Imidazolium Dicarboxylate Ligand Metal−Organic Framework (MOF): a Potential Precursor to MOF-Tethered N-Heterocyclic Carbene Compounds
journal, February 2010


SHAPED BODIES CONTAINING METAL-ORGANIC FRAMEWORKS
patent-application, June 2009


Covalent Organic Frameworks and Methods of Making Same
patent-application, May 2014


Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008


Gas Sensor Incorporating a Porous Framework
patent-application, February 2012


Hydrogen Storage in New Metal–Organic Frameworks
journal, June 2012

  • Tranchemontagne, David J.; Park, Kyo Sung; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry C, Vol. 116, Issue 24, p. 13143-13151
  • https://doi.org/10.1021/jp302356q

Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007


Substituted benzazoloporphyrazines for polymerization and surface attachment and articles formed therefrom
patent-application, January 2011


Metal oxides from metal-organic framework materials
patent, August 2013


Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals
journal, September 2011


A Thermally Stable Pt/Y-Based Metal−Organic Framework:  Exploring the Accessibility of the Metal Centers with Spectroscopic Methods Using H2O, CH3OH, and CH3CN as Probes
journal, November 2006


Adsorbing Agent, Dust Collection Chamber And Method For Adsorbing Odours
patent-application, January 2008


Microporous Coordination Polymers as Novel Sorbents for Gas Separation
patent-application, October 2010


Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002


Reversible oxygen sorbent compositions
patent, May 1993


Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012


A Metal−Organic Framework with Covalently Bound Organometallic Complexes
journal, July 2010


Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013


Porous Metal Organic Framework Based On Pyrroles And Pyridinones
patent-application, July 2009


Mixed metal framework compositions for monoalkylene glycol production
patent, November 1991


Metal–organic frameworks as heterogeneous catalysts for oxidation reactions
journal, January 2011


Gas Odorous Substance Separation
patent-application, August 2008


Gas Adsorption on Metal-Organic Frameworks
patent-application, March 2010


Porous organo-metallic skeleton material containing an additional polymer
patent, October 2010


Photoluminescent Metal−Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates
journal, February 2003


Covalent modification of a metal–organic framework with isocyanates: probing substrate scope and reactivity
journal, January 2008


High Methane Storage Capacity in Aluminum Metal–Organic Frameworks
journal, February 2014


In Situ Hydrothermal Growth of Metal−Organic Framework 199 Films on Stainless Steel Fibers for Solid-Phase Microextraction of Gaseous Benzene Homologues
journal, December 2009


Method of storing, uptaking, releasing of gases by novel framework materials
patent-application, August 2003


Metal-Organic Framework Adsorbents for Composite Gas Separation
patent-application, March 2014


Process for preparing porous metal-organic frameworks based on aluminum fumarate
patent, September 2013


Method of using a metal organic frameworks based on aluminum fumarate
patent, August 2013


Role of Copper Species in the Oxidative Dimerization of Arylboronic Acids: Synthesis of Symmetrical Biaryls
journal, December 2003


Late transition metal catalyst complexes and oligomers therefrom
patent, December 2002


Shaped bodies containing metal-organic frameworks
patent, April 2009


Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene
patent-application, November 2011


Reversible Ethylene Oxide Capture in Porous Frameworks
patent-application, February 2012


Carbon Dioxide Capture and Storage Using Open Frameworks
patent-application, May 2012


Process for the alkoxylation of monools in the presence of metallo-organic framework materials
patent-application, January 2005


Non-regenerating carbon monoxide sensor
patent, March 1998


Preparation of metal-catecholate frameworks
patent, June 2014


Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012


Role of Exposed Metal Sites in Hydrogen Storage in MOFs
journal, July 2008


A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials
journal, November 2005


Process for preparing hydrogen peroxide from the elements
patent-application, April 2004


From MOFs to zeolites: zirconium sites for epoxide rearrangement
journal, January 2013


Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals
patent-application, November 2004


An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids
journal, January 2002


A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst
journal, August 2002


Enhanced H2 Adsorption in Isostructural Metal−Organic Frameworks with Open Metal Sites: Strong Dependence of the Binding Strength on Metal Ions
journal, November 2008


High gas adsorption in a microporous metal-organic framework with open-metal sites
patent-application, November 2006


Process for producing polyalkylene carbonates
patent, September 2003


Process for the alkoxylation of monools in the presence of metallo-organic framework materials
patent-application, June 2006


Covalent Organic Framework Films, and Methods of Making and Uses of Same
patent-application, February 2014


Metal-Organic Frameworks with Exceptionally Large Pore Aperatures
patent-application, April 2013


Metal-Organic Frameworks for Aromatic Hydrocarbon Separations
patent-application, June 2016


Metal-Organic Frameworks Incorporating Copper-Complexed Rotaxanes
journal, January 2012


Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014


Facile Synthesis of a Highly Crystalline, Covalently Linked Porous Boronate Network
journal, October 2006


Method of storing, uptaking, releasing of gases by novel framework materials
patent, August 2005