Membrane separation of olefin and paraffin mixtures
Abstract
A metal exchanged fluorinated ionomer is a copolymer minimally including repeating units of (i) a polymerized derivative of a perfluorinated cyclic or cyclizable monomer and (ii) a strong acid highly fluorinated vinylether compound in which the acid moiety is exchanged with a cation of a Group 11 metal. Metal exchanged fluorinated ionomers are readily soluble and can be formed into thin, selectively gas permeable membranes by solution deposition methods. These membranes are suitable for separating olefins from gas olefin/paraffin mixtures. Good selectivity and transmembrane flux can be obtained without humidifying the membrane feed gas mixture.
- Inventors:
- Issue Date:
- Research Org.:
- Compact Membrane Systems Inc., Newport, DE (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1464455
- Patent Number(s):
- 10029248
- Application Number:
- 14/334,605
- Assignee:
- Compact Membrane Systems Inc. (Newport, DE)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
- DOE Contract Number:
- SC0004672; SC0007510
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Jul 17
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Feiring, Andrew Edward, Lazzeri, Jonathan, Majumdar, Sudipto, and Shangguan, Ning. Membrane separation of olefin and paraffin mixtures. United States: N. p., 2018.
Web.
Feiring, Andrew Edward, Lazzeri, Jonathan, Majumdar, Sudipto, & Shangguan, Ning. Membrane separation of olefin and paraffin mixtures. United States.
Feiring, Andrew Edward, Lazzeri, Jonathan, Majumdar, Sudipto, and Shangguan, Ning. Tue .
"Membrane separation of olefin and paraffin mixtures". United States. https://www.osti.gov/servlets/purl/1464455.
@article{osti_1464455,
title = {Membrane separation of olefin and paraffin mixtures},
author = {Feiring, Andrew Edward and Lazzeri, Jonathan and Majumdar, Sudipto and Shangguan, Ning},
abstractNote = {A metal exchanged fluorinated ionomer is a copolymer minimally including repeating units of (i) a polymerized derivative of a perfluorinated cyclic or cyclizable monomer and (ii) a strong acid highly fluorinated vinylether compound in which the acid moiety is exchanged with a cation of a Group 11 metal. Metal exchanged fluorinated ionomers are readily soluble and can be formed into thin, selectively gas permeable membranes by solution deposition methods. These membranes are suitable for separating olefins from gas olefin/paraffin mixtures. Good selectivity and transmembrane flux can be obtained without humidifying the membrane feed gas mixture.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}