Membrane separation of olefin and paraffin mixtures

Title: Membrane separation of olefin and paraffin mixtures

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Abstract

A metal exchanged fluorinated ionomer is a copolymer minimally including repeating units of (i) a polymerized derivative of a perfluorinated cyclic or cyclizable monomer and (ii) a strong acid highly fluorinated vinylether compound in which the acid moiety is exchanged with a cation of a Group 11 metal. Metal exchanged fluorinated ionomers are readily soluble and can be formed into thin, selectively gas permeable membranes by solution deposition methods. These membranes are suitable for separating olefins from gas olefin/paraffin mixtures. Good selectivity and transmembrane flux can be obtained without humidifying the membrane feed gas mixture.

Inventors:: Feiring, Andrew Edward; Lazzeri, Jonathan; Majumdar, Sudipto; Shangguan, Ning

Issue Date:: 2018-07-24

Research Org.:: Compact Membrane Systems Inc., Newport, DE (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1464455

Patent Number(s):: 10029248

Application Number:: 14/334,605

Assignee:: Compact Membrane Systems Inc. (Newport, DE)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C11/04 - Ethylene

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D71/32 - containing fluorine atoms
B01D71/52 - Polyethers
B01D71/76 - Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C7/144 - using membranes, e.g. selective permeation

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J39/20 - obtained by reactions only involving unsaturated carbon-to-carbon bonds
B01J41/14 - obtained by reactions only involving unsaturated carbon-to-carbon bonds

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C11/06 - Propene
C07C11/08 - with four carbon atoms

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D53/228 - {characterised by specific membranes}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J47/12 - characterised by the use of ion-exchange material in the form of ribbons, filaments, fibres or sheets, e.g. membranes

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/50 - Improvements relating to the production of products other than chlorine, adipic acid, caprolactam, or chlorodifluoromethane, e.g. bulk or fine chemicals or pharmaceuticals

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D71/82 - characterised by the presence of specified groups, e.g. introduced by chemical after-treatment

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DOE Contract Number:: SC0004672; SC0007510

Resource Type:: Patent

Resource Relation:: Patent File Date: 2014 Jul 17

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Feiring, Andrew Edward, Lazzeri, Jonathan, Majumdar, Sudipto, and Shangguan, Ning. Membrane separation of olefin and paraffin mixtures.  United States: N. p., 2018. 
        Web.

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                    Feiring, Andrew Edward, Lazzeri, Jonathan, Majumdar, Sudipto, & Shangguan, Ning. Membrane separation of olefin and paraffin mixtures.  United States.

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                    Feiring, Andrew Edward, Lazzeri, Jonathan, Majumdar, Sudipto, and Shangguan, Ning. Tue .  
        "Membrane separation of olefin and paraffin mixtures".  United States.  https://www.osti.gov/servlets/purl/1464455.

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@article{osti_1464455,

  title        = {Membrane separation of olefin and paraffin mixtures},

  author       = {Feiring, Andrew Edward and Lazzeri, Jonathan and Majumdar, Sudipto and Shangguan, Ning},

  abstractNote = {A metal exchanged fluorinated ionomer is a copolymer minimally including repeating units of (i) a polymerized derivative of a perfluorinated cyclic or cyclizable monomer and (ii) a strong acid highly fluorinated vinylether compound in which the acid moiety is exchanged with a cation of a Group 11 metal. Metal exchanged fluorinated ionomers are readily soluble and can be formed into thin, selectively gas permeable membranes by solution deposition methods. These membranes are suitable for separating olefins from gas olefin/paraffin mixtures. Good selectivity and transmembrane flux can be obtained without humidifying the membrane feed gas mixture.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {7}

}

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