Salts for multivalent ion batteries

Liao, Chen; Dzwiniel, Trevor L.; Pan, Baofei; Han, Sang-Don; Burrell, Anthony

Title: Salts for multivalent ion batteries

Abstract

Methods for preparing electrolyte salts for alkaline earth metal-ion batteries (e.g., calcium and magnesium ion batteries) are described. The electrolyte salts comprise alkaline earth metal (e.g., Mg or Ca) salts of bis(fluorosulfonyl)imide (FSI) and 3,4-dicyano-2-trifluoromethylimidazole (TDI). The methods comprise contacting FSI or TDI with an alkaline earth metal bis(trifluoroacetate) salt in trifluoroacetic acid.

Inventors:: Liao, Chen; Dzwiniel, Trevor L.; Pan, Baofei; Han, Sang-Don; Burrell, Anthony

Issue Date:: 2018-07-10

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1463702

Patent Number(s):: 10020538

Application Number:: 14/940,667

Assignee:: UCHICAGO ARGONNE, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0568 - characterised by the solutes

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0569 - characterised by the solvents

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D233/90 - Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0563 - Liquid materials, e.g. for Li-SOCl2 cells

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B21/084 - containing also one or more oxygen atoms, e.g. nitrosyl halides

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B21/086 - containing one or more sulfur atoms

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D233/93 - with hydrocarbon radicals, substituted by halogen atoms, attached to other ring members

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Nov 13

Country of Publication:: United States

Language:: English

Citation Formats


                    Liao, Chen, Dzwiniel, Trevor L., Pan, Baofei, Han, Sang-Don, and Burrell, Anthony. Salts for multivalent ion batteries.  United States: N. p., 2018. 
        Web.

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                    Liao, Chen, Dzwiniel, Trevor L., Pan, Baofei, Han, Sang-Don, & Burrell, Anthony. Salts for multivalent ion batteries.  United States.

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                    Liao, Chen, Dzwiniel, Trevor L., Pan, Baofei, Han, Sang-Don, and Burrell, Anthony. Tue .  
        "Salts for multivalent ion batteries".  United States.  https://www.osti.gov/servlets/purl/1463702.

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@article{osti_1463702,

  title        = {Salts for multivalent ion batteries},

  author       = {Liao, Chen and Dzwiniel, Trevor L. and Pan, Baofei and Han, Sang-Don and Burrell, Anthony},

  abstractNote = {Methods for preparing electrolyte salts for alkaline earth metal-ion batteries (e.g., calcium and magnesium ion batteries) are described. The electrolyte salts comprise alkaline earth metal (e.g., Mg or Ca) salts of bis(fluorosulfonyl)imide (FSI) and 3,4-dicyano-2-trifluoromethylimidazole (TDI). The methods comprise contacting FSI or TDI with an alkaline earth metal bis(trifluoroacetate) salt in trifluoroacetic acid.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {7}

}

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Works referenced in this record:

Synthesis of bis(fluorosulfonyl)imide
patent, February 2013

Singh, Rajendra; Martin, Jerry; Poshusta, Joseph
US Patent Document 8,377,406
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F8377406

Synthesis of hydrogen bis(fluorosulfonyl)imide
patent, May 2014

Poshusta, Joseph; Martin, Jerry; Singh, Rajendra
US Patent Document 8,722,005
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F8722005

New type of imidazole based salts designed specifically for lithium ion batteries
journal, January 2010

Niedzicki, L.; Żukowska, G. Z.; Bukowska, M.
Electrochimica Acta, Vol. 55, Issue 4, p. 1450-1454
https://doi.org/10.1016/j.electacta.2009.05.008

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Title: Salts for multivalent ion batteries

Abstract

Citation Formats

Synthesis of bis(fluorosulfonyl)imide patent, February 2013

Synthesis of hydrogen bis(fluorosulfonyl)imide patent, May 2014

New type of imidazole based salts designed specifically for lithium ion batteries journal, January 2010

Synthesis of bis(fluorosulfonyl)imide
patent, February 2013

Synthesis of hydrogen bis(fluorosulfonyl)imide
patent, May 2014

New type of imidazole based salts designed specifically for lithium ion batteries
journal, January 2010