Salts for multivalent ion batteries
Abstract
Methods for preparing electrolyte salts for alkaline earth metal-ion batteries (e.g., calcium and magnesium ion batteries) are described. The electrolyte salts comprise alkaline earth metal (e.g., Mg or Ca) salts of bis(fluorosulfonyl)imide (FSI) and 3,4-dicyano-2-trifluoromethylimidazole (TDI). The methods comprise contacting FSI or TDI with an alkaline earth metal bis(trifluoroacetate) salt in trifluoroacetic acid.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1463702
- Patent Number(s):
- 10020538
- Application Number:
- 14/940,667
- Assignee:
- UCHICAGO ARGONNE, LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Nov 13
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Liao, Chen, Dzwiniel, Trevor L., Pan, Baofei, Han, Sang-Don, and Burrell, Anthony. Salts for multivalent ion batteries. United States: N. p., 2018.
Web.
Liao, Chen, Dzwiniel, Trevor L., Pan, Baofei, Han, Sang-Don, & Burrell, Anthony. Salts for multivalent ion batteries. United States.
Liao, Chen, Dzwiniel, Trevor L., Pan, Baofei, Han, Sang-Don, and Burrell, Anthony. Tue .
"Salts for multivalent ion batteries". United States. https://www.osti.gov/servlets/purl/1463702.
@article{osti_1463702,
title = {Salts for multivalent ion batteries},
author = {Liao, Chen and Dzwiniel, Trevor L. and Pan, Baofei and Han, Sang-Don and Burrell, Anthony},
abstractNote = {Methods for preparing electrolyte salts for alkaline earth metal-ion batteries (e.g., calcium and magnesium ion batteries) are described. The electrolyte salts comprise alkaline earth metal (e.g., Mg or Ca) salts of bis(fluorosulfonyl)imide (FSI) and 3,4-dicyano-2-trifluoromethylimidazole (TDI). The methods comprise contacting FSI or TDI with an alkaline earth metal bis(trifluoroacetate) salt in trifluoroacetic acid.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}
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Works referenced in this record:
Synthesis of bis(fluorosulfonyl)imide
patent, February 2013
- Singh, Rajendra; Martin, Jerry; Poshusta, Joseph
- US Patent Document 8,377,406
Synthesis of hydrogen bis(fluorosulfonyl)imide
patent, May 2014
- Poshusta, Joseph; Martin, Jerry; Singh, Rajendra
- US Patent Document 8,722,005
New type of imidazole based salts designed specifically for lithium ion batteries
journal, January 2010
- Niedzicki, L.; Żukowska, G. Z.; Bukowska, M.
- Electrochimica Acta, Vol. 55, Issue 4, p. 1450-1454