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Title: Process for the functionalization of heteroalkanes and arenes

Abstract

Provided are methods and materials for the functionalization of a heteroalkane or arene using an oxidizing electrophile as a stoichiometric agent or catalyst. The reaction involves the replacement of a hydrogen atom on an sp3-hybridized carbon atom of the heteroalkane or of a hydrogen atom on an sp2-hybridized carbon atom of the arene. A main group element organometallic intermediate is formed that undergoes further conversion to a functionalized heteroalkane or arene.

Inventors:
; ;
Issue Date:
Research Org.:
The Scripps Research Inst., La Jolla, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1462178
Patent Number(s):
10,011,547
Application Number:
15/506,583
Assignee:
The Scripps Research Institute (La Jolla, CA) OSTI
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Aug 25
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Periana, Roy A., Konnick, Michael M., and Hashiguchi, Brian G. Process for the functionalization of heteroalkanes and arenes. United States: N. p., 2018. Web.
Periana, Roy A., Konnick, Michael M., & Hashiguchi, Brian G. Process for the functionalization of heteroalkanes and arenes. United States.
Periana, Roy A., Konnick, Michael M., and Hashiguchi, Brian G. Tue . "Process for the functionalization of heteroalkanes and arenes". United States. https://www.osti.gov/servlets/purl/1462178.
@article{osti_1462178,
title = {Process for the functionalization of heteroalkanes and arenes},
author = {Periana, Roy A. and Konnick, Michael M. and Hashiguchi, Brian G.},
abstractNote = {Provided are methods and materials for the functionalization of a heteroalkane or arene using an oxidizing electrophile as a stoichiometric agent or catalyst. The reaction involves the replacement of a hydrogen atom on an sp3-hybridized carbon atom of the heteroalkane or of a hydrogen atom on an sp2-hybridized carbon atom of the arene. A main group element organometallic intermediate is formed that undergoes further conversion to a functionalized heteroalkane or arene.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}

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