Process for the functionalization of heteroalkanes and arenes
Abstract
Provided are methods and materials for the functionalization of a heteroalkane or arene using an oxidizing electrophile as a stoichiometric agent or catalyst. The reaction involves the replacement of a hydrogen atom on an sp3-hybridized carbon atom of the heteroalkane or of a hydrogen atom on an sp2-hybridized carbon atom of the arene. A main group element organometallic intermediate is formed that undergoes further conversion to a functionalized heteroalkane or arene.
- Inventors:
- Issue Date:
- Research Org.:
- The Scripps Research Inst., La Jolla, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1462178
- Patent Number(s):
- 10011547
- Application Number:
- 15/506,583
- Assignee:
- The Scripps Research Institute (La Jolla, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Aug 25
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Periana, Roy A., Konnick, Michael M., and Hashiguchi, Brian G. Process for the functionalization of heteroalkanes and arenes. United States: N. p., 2018.
Web.
Periana, Roy A., Konnick, Michael M., & Hashiguchi, Brian G. Process for the functionalization of heteroalkanes and arenes. United States.
Periana, Roy A., Konnick, Michael M., and Hashiguchi, Brian G. Tue .
"Process for the functionalization of heteroalkanes and arenes". United States. https://www.osti.gov/servlets/purl/1462178.
@article{osti_1462178,
title = {Process for the functionalization of heteroalkanes and arenes},
author = {Periana, Roy A. and Konnick, Michael M. and Hashiguchi, Brian G.},
abstractNote = {Provided are methods and materials for the functionalization of a heteroalkane or arene using an oxidizing electrophile as a stoichiometric agent or catalyst. The reaction involves the replacement of a hydrogen atom on an sp3-hybridized carbon atom of the heteroalkane or of a hydrogen atom on an sp2-hybridized carbon atom of the arene. A main group element organometallic intermediate is formed that undergoes further conversion to a functionalized heteroalkane or arene.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Manufacture of vicinal glycol esters from synthesis gas
patent, May 1981
- Knifton, John F.
- US Patent Document 4,268,689
Main-Group Compounds Selectively Oxidize Mixtures of Methane, Ethane, and Propane to Alcohol Esters
journal, March 2014
- Hashiguchi, B. G.; Konnick, M. M.; Bischof, S. M.
- Science, Vol. 343, Issue 6176, p. 1232-1237
Selective CH Functionalization of Methane, Ethane, and Propane by a Perfluoroarene Iodine(III) Complex
journal, August 2014
- Konnick, Michael M.; Hashiguchi, Brian G.; Devarajan, Deepa
- Angewandte Chemie International Edition, Vol. 53, Issue 39, p. 10490-10494