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Title: Process for the functionalization of heteroalkanes and arenes

Provided are methods and materials for the functionalization of a heteroalkane or arene using an oxidizing electrophile as a stoichiometric agent or catalyst. The reaction involves the replacement of a hydrogen atom on an sp3-hybridized carbon atom of the heteroalkane or of a hydrogen atom on an sp2-hybridized carbon atom of the arene. A main group element organometallic intermediate is formed that undergoes further conversion to a functionalized heteroalkane or arene.
Inventors:
; ;
Issue Date:
OSTI Identifier:
1462178
Assignee:
The Scripps Research Institute (La Jolla, CA) OSTI
Patent Number(s):
10,011,547
Application Number:
15/506,583
Resource Relation:
Patent File Date: 2015 Aug 25
Research Org:
The Scripps Research Inst., La Jolla, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

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