High-density carbon nanotube-based monolith and related materials, methods, and devices

Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; Charnvanichborikarn, Supakit; Kucheyev, Sergei; Montalvo, Elizabeth; Shin, Swanee; Tylski, Elijah

Title: High-density carbon nanotube-based monolith and related materials, methods, and devices

Abstract

Disclosed here is a composition comprising at least one high-density carbon-nanotube-based monolith, said monolith comprising carbon nanotubes crosslinked by nanoparticles and having a density of at least 0.2 g/cm³. Also provided is a method for making the composition comprising: preparing a reaction mixture comprising a suspension and at least one catalyst, said suspension is a carbon nanotube suspension; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel, said drying step is substantially free of supercritical drying and freeze drying; and pyrolyzing the dry gel to produce the composition comprising a high-density carbon-nanotube-based monolith. Exceptional combinations of properties are achieved including high conductive and mechanical properties.

Inventors:: Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; Charnvanichborikarn, Supakit; Kucheyev, Sergei; Montalvo, Elizabeth; Shin, Swanee; Tylski, Elijah

Issue Date:: 2018-07-03

Research Org.:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1461503

Patent Number(s):: 10014090

Application Number:: 15/217,858

Assignee:: Lawrence Livermore National Security, LLC (Livermore, CA)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

Show more

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2006/40 - Electric properties

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2202/04 - Nanotubes with a specific amount of walls
C01B32/174 - Derivatisation
C01B2202/22 - Electronic properties
C01B32/166 - in liquid phase
C01B2202/02 - Single-walled nanotubes

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES
H01B1/04 - mainly consisting of carbon-silicon compounds, carbon or silicon

Show less

DOE Contract Number:: AC52-07NA27344

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Jul 22

Country of Publication:: United States

Language:: English

Citation Formats


                    Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Charnvanichborikarn, Supakit, Kucheyev, Sergei, Montalvo, Elizabeth, Shin, Swanee, and Tylski, Elijah. High-density carbon nanotube-based monolith and related materials, methods, and devices.  United States: N. p., 2018. 
        Web.

Copy to clipboard


                    Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Charnvanichborikarn, Supakit, Kucheyev, Sergei, Montalvo, Elizabeth, Shin, Swanee, & Tylski, Elijah. High-density carbon nanotube-based monolith and related materials, methods, and devices.  United States.

Copy to clipboard


                    Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Charnvanichborikarn, Supakit, Kucheyev, Sergei, Montalvo, Elizabeth, Shin, Swanee, and Tylski, Elijah. Tue .  
        "High-density carbon nanotube-based monolith and related materials, methods, and devices".  United States.  https://www.osti.gov/servlets/purl/1461503.

Copy to clipboard


                    
@article{osti_1461503,

  title        = {High-density carbon nanotube-based monolith and related materials, methods, and devices},

  author       = {Worsley, Marcus A. and Baumann, Theodore F. and Biener, Juergen and Charnvanichborikarn, Supakit and Kucheyev, Sergei and Montalvo, Elizabeth and Shin, Swanee and Tylski, Elijah},

  abstractNote = {Disclosed here is a composition comprising at least one high-density carbon-nanotube-based monolith, said monolith comprising carbon nanotubes crosslinked by nanoparticles and having a density of at least 0.2 g/cm3. Also provided is a method for making the composition comprising: preparing a reaction mixture comprising a suspension and at least one catalyst, said suspension is a carbon nanotube suspension; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel, said drying step is substantially free of supercritical drying and freeze drying; and pyrolyzing the dry gel to produce the composition comprising a high-density carbon-nanotube-based monolith. Exceptional combinations of properties are achieved including high conductive and mechanical properties.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {7}

}

Copy to clipboard

Patent:

View Patent

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process
journal, July 2010

Xu, Yuxi; Sheng, Kaixuan; Li, Chun
ACS Nano, Vol. 4, Issue 7, p. 4324-4330
https://doi.org/10.1021/nn101187z

Graphene-Wrapped Fe₃O₄ Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries
journal, September 2010

Zhou, Guangmin; Wang, Da-Wei; Li, Feng
Chemistry of Materials, Vol. 22, Issue 18, p. 5306-5313
https://doi.org/10.1021/cm101532x

Structural Studies of Lithium Intercalation in a Nanocrystalline α-Fe₂O₃Compound
journal, January 2006

Jain, Gaurav; Balasubramanian, Mahalingam; Xu, Jun John
Chemistry of Materials, Vol. 18, Issue 2, p. 423-434
https://doi.org/10.1021/cm052014f

Fabrication of Graphene-Polymer Nanocomposites With Higher-Order Three-Dimensional Architectures
journal, June 2009

Vickery, Jemma L.; Patil, Avinash J.; Mann, Stephen
Advanced Materials, Vol. 21, Issue 21, p. 2180-2184
https://doi.org/10.1002/adma.200803606

Assembly of Graphene Sheets into 3D Macroscopic Structures
journal, May 2012

Yin, Shengyan; Niu, Zhiqiang; Chen, Xiaodong
Small, Vol. 8, Issue 16, p. 2458-2463
https://doi.org/10.1002/smll.201102614

Comment on “Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene”
journal, March 2009

Jeong, H.-K.; Noh, H.-J.; Kim, J.-Y.
Physical Review Letters, Vol. 102, Issue 9, Article No. 099701
https://doi.org/10.1103/PhysRevLett.102.099701

In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode
journal, December 2010

Huang, J. Y.; Zhong, L.; Wang, C. M.
Science, Vol. 330, Issue 6010, p. 1515-1520
https://doi.org/10.1126/science.1195628

Advanced carbon aerogels for energy applications
journal, January 2011

Biener, Juergen; Stadermann, Michael; Suss, Matthew
Energy & Environmental Science, Vol. 4, Issue 3, p. 656-667
https://doi.org/10.1039/c0ee00627k

Epitaxial graphene on ruthenium
journal, April 2008

Sutter, Peter W.; Flege, Jan-Ingo; Sutter, Eli A.
Nature Materials, Vol. 7, Issue 5, p. 406-411
https://doi.org/10.1038/nmat2166

Carrier Transport in Two-Dimensional Graphene Layers
journal, May 2007

Hwang, E. H.; Adam, S.; Sarma, S. Das
Physical Review Letters, Vol. 98, Issue 18, Article No. 186806
https://doi.org/10.1103/PhysRevLett.98.186806

Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets
journal, November 2007

Gomez-Navarro, Cristina; Weitz, R. Thomas; Bittner, Alexander M.
Nano Letters, Vol. 7, Issue 11, p. 3499-3503
https://doi.org/10.1021/nl072090c

Large scale manufacturing of nanostructured material
patent-application, April 2010

Cooper, Christopher H.; Cummings, Alan G.; Starostin, Mikhail Y.
US Patent Application 11/514184; 20100098877
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220100098877%22.PGNR.&OS=DN/20100098877&RS=DN/20100098877

Strong Akaganeite Aerogel Monoliths Using Epoxides: Synthesis and Characterization
journal, August 2003

Gash, Alexander E.; Satcher, Joe H.; Simpson, Randall L.
Chemistry of Materials, Vol. 15, Issue 17, p. 3268-3275
https://doi.org/10.1021/cm034211p

Combined XRD, EXAFS, and Mossbauer Studies of the Reduction by Lithium of α-Fe₂O₃ with Various Particle Sizes
journal, January 2003

Larcher, D.; Bonnin, D.; Cortes, R.
Journal of The Electrochemical Society, Vol. 150, Issue 12, p. A1643-A1650
https://doi.org/10.1149/1.1622959

Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
journal, July 2008

Lee, C.; Wei, X.; Kysar, J. W.
Science, Vol. 321, Issue 5887, p. 385-388
https://doi.org/10.1126/science.1157996

Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide
journal, May 2010

Tang, Zhihong; Shen, Shuling; Zhuang, Jing
Angewandte Chemie, Vol. 122, Issue 27
https://doi.org/10.1002/ange.201000270

Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells
journal, January 2008

Wang, Xuan; Zhi, Linjie; Müllen, Klaus
Nano Letters, Vol. 8, Issue 1, p. 323-327
https://doi.org/10.1021/nl072838r

Graphene-based electrochemical supercapacitors
journal, January 2008

Vivekchand, S. R. C.; Rout, Chandra Sekhar; Subrahmanyam, K. S.
Journal of Chemical Sciences, Vol. 120, Issue 1, p. 9-13
https://doi.org/10.1007/s12039-008-0002-7

Properties of single-walled carbon nanotube-based aerogels as a function of nanotube loading
journal, October 2009

Worsley, Marcus A.; Pauzauskie, Peter J.; Kucheyev, Sergei O.
Acta Materialia, Vol. 57, Issue 17, p. 5131-5136
https://doi.org/10.1016/j.actamat.2009.07.012

Aqueous Dispersion of Graphene Sheets Stabilized by Pluronic Copolymers: Formation of Supramolecular Hydrogel
journal, August 2009

Zu, Sheng-Zhen; Han, Bao-Hang
The Journal of Physical Chemistry C, Vol. 113, Issue 31, p. 13651-13657
https://doi.org/10.1021/jp9035887

Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation
journal, February 2009

Wu, Zhong-Shuai; Ren, Wencai; Gao, Libo
ACS Nano, Vol. 3, Issue 2, p. 411-417
https://doi.org/10.1021/nn900020u

Synthesis and Characterization of Nanometric Iron and Iron-Titanium Oxides by Mechanical Milling: Electrochemical Properties as Anodic Materials in Lithium Cells
journal, January 2005

Morales, Julian; Sanchez, Luis; Martin, Francisco
Journal of The Electrochemical Society, Vol. 152, Issue 9, p. A1748-A1754
https://doi.org/10.1149/1.1972812

Graphene Aerogels
patent-application, February 2012

Pauzauskie, Peter; Worsley, Marcus; Baumann, Theodore
US Patent Application 13/204277; 20120034442
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220120034442%22.PGNR.&OS=DN/20120034442&RS=DN/20120034442

Graphene Based Electrochemical Sensors and Biosensors: A Review
journal, March 2010

Shao, Yuyan; Wang, Jun; Wu, Hong
Electroanalysis, Vol. 22, Issue 10, p. 1027-1036
https://doi.org/10.1002/elan.200900571

Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries
journal, January 1998

Arora, Pankaj; White, Ralph E.; Doyle, Marc
Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667
https://doi.org/10.1149/1.1838857

Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition
journal, April 2011

Chen, Zongping; Ren, Wencai; Gao, Libo
Nature Materials, Vol. 10, Issue 6, p. 424-428
https://doi.org/10.1038/nmat3001

Method of manufacturing aerogel composites
patent, March 1999

Cao, Wanqing; Hunt, Arlon Jason
US Patent Document 5,879,744
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5879744

Unitary graphene layer or graphene single crystal
patent-application, May 2014

Zhamu, Aruna; Wang, Mingchao; Xiong, Wei
US Patent Application 13/694356; 20140147648
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220140147648%22.PGNR.&OS=DN/20140147648&RS=DN/20140147648

Raman validity for crystallite size L_a determination on reticulated vitreous carbon with different graphitization index
journal, November 2007

Baldan, M. R.; Almeida, E. C.; Azevedo, A. F.
Applied Surface Science, Vol. 254, Issue 2, p. 600-603
https://doi.org/10.1016/j.apsusc.2007.06.038

Giant Intrinsic Carrier Mobilities in Graphene and Its Bilayer
journal, January 2008

Morozov, S. V.; Novoselov, K. S.; Katsnelson, M. I.
Physical Review Letters, Vol. 100, Issue 1, Article No. 016602
https://doi.org/10.1103/PhysRevLett.100.016602

Superior Thermal Conductivity of Single-Layer Graphene
journal, March 2008

Balandin, Alexander A.; Ghosh, Suchismita; Bao, Wenzhong
Nano Letters, Vol. 8, Issue 3, p. 902-907
https://doi.org/10.1021/nl0731872

Binder-Free and Carbon-Free Nanoparticle Batteries: A Method for Nanoparticle Electrodes without Polymeric Binders or Carbon Black
journal, September 2012

Ha, Don-Hyung; Islam, Mohammad A.; Robinson, Richard D.
Nano Letters, Vol. 12, Issue 10, p. 5122-5130
https://doi.org/10.1021/nl3019559

An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments
journal, June 1992

Oliver, W. C.; Pharr, G. M.
Journal of Materials Research, Vol. 7, Issue 06, p. 1564-1583
https://doi.org/10.1557/JMR.1992.1564

Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material
journal, April 2008

Eda, Goki; Fanchini, Giovanni; Chhowalla, Manish
Nature Nanotechnology, Vol. 3, Issue 5, p. 270-274
https://doi.org/10.1038/nnano.2008.83

Graphene Aerogels
conference, January 2009

Wang, Jian; Ellsworth, Mark
https://doi.org/10.1149/1.3119548

X-ray absorption spectroscopy of graphite oxide
journal, June 2008

Jeong, H.-K.; Noh, H.-J.; Kim, J.-Y.
EPL (Europhysics Letters), Vol. 82, Issue 6, Article No. 67004
https://doi.org/10.1209/0295-5075/82/67004

Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels
journal, January 2003

Al-Muhtaseb, S. A.; Ritter, J. A.
Advanced Materials, Vol. 15, Issue 2, p. 101-114
https://doi.org/10.1002/adma.200390020

Mechanically robust and electrically conductive carbon nanotube foams
journal, February 2009

Worsley, Marcus A.; Kucheyev, Sergei O.; Satcher, Joe H.
Applied Physics Letters, Vol. 94, Issue 7, Article No. 073115
https://doi.org/10.1063/1.3086293

Nanostructured Reduced Graphene Oxide/Fe₂O₃ Composite As a High-Performance Anode Material for Lithium Ion Batteries
journal, April 2011

Zhu, Xianjun; Zhu, Yanwu; Murali, Shanthi
ACS Nano, Vol. 5, Issue 4, p. 3333-3338
https://doi.org/10.1021/nn200493r

Functionalized graphene sheet filled silicone foam nanocomposites
journal, January 2008

Verdejo, Raquel; Barroso-Bujans, Fabienne; Rodriguez-Perez, Miguel Angel
Journal of Materials Chemistry, Vol. 18, Issue 19, p. 2221-2226
https://doi.org/10.1039/b718289a

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

Poizot, P.; Laruelle, S.; Grugeon, S.
Nature, Vol. 407, Issue 6803, p. 496-499
https://doi.org/10.1038/35035045

Aerogel and xerogel composites for use as carbon anodes
patent, October 2010

Cooper, John F.; Tillotson, Thomas M.; Hrubesh, Lawrence W.
US Patent Document 7,811,711
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7811711

Graphene Compositions
patent-application, August 2011

Scheffer, Dan; Lettow, JOhn; Varma, Vipin
US Patent Application 12/848152; 20110186786
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220110186786%22.PGNR.&OS=DN/20110186786&RS=DN/20110186786

Carbon Scaffolds for Stiff and Highly Conductive Monolithic Oxide–Carbon Nanotube Composites
journal, June 2011

Worsley, Marcus A.; Kucheyev, Sergei O.; Kuntz, Joshua D.
Chemistry of Materials, Vol. 23, Issue 12, p. 3054-3061
https://doi.org/10.1021/cm200426k

Graphene Tapes
patent-application, November 2011

Korkut, Sibel; Milius, David L.; Roy-Mayhew, Joseph D.
US Patent Application 12/949448; 20110287241
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220110287241%22.PGNR.&OS=DN/20110287241&RS=DN/20110287241

In situ infrared observation of the pyrolysis process of carbon aerogels
journal, April 1998

Kuhn, J.; Brandt, R.; Mehling, H.
Journal of Non-Crystalline Solids, Vol. 225, p. 58-63
https://doi.org/10.1016/S0022-3093(98)00009-X

Functionalized graphene sheets for polymer nanocomposites
journal, May 2008

Ramanathan, T.; Abdala, A. A.; Stankovich, S.
Nature Nanotechnology, Vol. 3, Issue 6, p. 327-331
https://doi.org/10.1038/nnano.2008.96

Raman Spectrum of Graphene and Graphene Layers
journal, October 2006

Ferrari, A. C.; Meyer, J. C.; Scardaci, V.
Physical Review Letters, Vol. 97, Issue 18, Article No. 187401
https://doi.org/10.1103/PhysRevLett.97.187401

Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene
journal, August 2008

Pacile, D.; Papagno, M.; Rodríguez, A. Fraile
Physical Review Letters, Vol. 101, Issue 6, Article No. 066806
https://doi.org/10.1103/PhysRevLett.101.066806

Synthesis of Graphene Aerogel with High Electrical Conductivity
journal, October 2010

Worsley, Marcus A.; Pauzauskie, Peter J.; Olson, Tammy Y.
Journal of the American Chemical Society, Vol. 132, Issue 40, p. 14067-14069
https://doi.org/10.1021/ja1072299

Unitary graphene matrix composites containing carbon or graphite fillers
patent-application, June 2014

Zhamu, Aruna; Wang, Mingchoa; Xiong, Wei
US Patent Application 13/694468; 20140154941
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220140154941%22.PGNR.&OS=DN/20140154941&RS=DN/20140154941

The rise of graphene
journal, March 2007

Geim, A. K.; Novoselov, K. S.
Nature Materials, Vol. 6, Issue 3, p. 183-191
https://doi.org/10.1038/nmat1849

High Surface Area, sp²-Cross-Linked Three-Dimensional Graphene Monoliths
journal, April 2011

Worsley, Marcus A.; Olson, Tammy Y.; Lee, Jonathan R. I.
The Journal of Physical Chemistry Letters, Vol. 2, Issue 8, p. 921-925
https://doi.org/10.1021/jz200223x

Electronic and structural properties of graphene-based transparent and conductive thin film electrodes
journal, October 2008

Vollmer, A.; Feng, X. L.; Wang, X.
Applied Physics A, Vol. 94, Issue 1, p. 1-4
https://doi.org/10.1007/s00339-008-4931-2

Aerogel and xerogel composites for use as carbon anodes
patent, August 2008

Cooper, John F.; Tillotson, Thomas M.; Hrubesh, Lawrence W.
US Patent Document 7,410,718
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7410718

Chemical composition
patent, March 1999

Jadesjo, Gunilla; Jonsson, Gunnil
US Patent Document 5,885,953
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5885953

Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide
journal, May 2010

Tang, Zhihong; Shen, Shuling; Zhuang, Jing
Angewandte Chemie International Edition, Vol. 49, Issue 27, p. 4603-4607
https://doi.org/10.1002/anie.201000270

Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene
journal, February 2007

Graf, D.; Molitor, F.; Ensslin, K.
Nano Letters, Vol. 7, Issue 2, p. 238-242
https://doi.org/10.1021/nl061702a

Depth-sensing indentation of low-density brittle nanoporous solids
journal, July 2009

Kucheyev, S. O.; Hamza, A. V.; Satcher Jr., J. H.
Acta Materialia, Vol. 57, Issue 12, p. 3472-3480
https://doi.org/10.1016/j.actamat.2009.04.003

Carbon 1s near-edge-absorption fine structure in graphite
journal, July 1993

Batson, P. E.
Physical Review B, Vol. 48, Issue 4, p. 2608-2610
https://doi.org/10.1103/PhysRevB.48.2608

Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries
journal, August 2008

Yoo, EunJoo; Kim, Jedeok; Hosono, Eiji
Nano Letters, Vol. 8, Issue 8, p. 2277-2282
https://doi.org/10.1021/nl800957b

Detection of individual gas molecules adsorbed on graphene
journal, July 2007

Schedin, F.; Geim, A. K.; Morozov, S. V.
Nature Materials, Vol. 6, Issue 9, p. 652-655
https://doi.org/10.1038/nmat1967

Graphene and graphene oxide aerogels
patent-application, June 2010

Wang, Jian; Ellsworth, Mark W.
US Patent Application 12/315701; 20100144904
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220100144904%22.PGNR.&OS=DN/20100144904&RS=DN/20100144904

Graphene-based composite materials
journal, July 2006

Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B.
Nature, Vol. 442, Issue 7100, p. 282-286
https://doi.org/10.1038/nature04969

Structure and electronic properties of a nongraphitic disordered carbon system and its heat-treatment effects
journal, June 2003

Takai, Kazuyuki; Oga, Meigo; Sato, Hirohiko
Physical Review B, Vol. 67, Issue 21, Article No. 214202
https://doi.org/10.1103/PhysRevB.67.214202

Preparation of Graphitic Oxide
journal, March 1958

Hummers, William S.; Offeman, Richard E.
Journal of the American Chemical Society, Vol. 80, Issue 6, p. 1339-1339
https://doi.org/10.1021/ja01539a017

Graphene aerogels
patent, March 2015

Pauzauskie, Peter J.; Worsley, Marcus A.; Baumann, Theodore F.
US Patent Document 8,993,113
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F8993113

Graphene Anchored with Co₃O₄ Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance
journal, June 2010

Wu, Zhong-Shuai; Ren, Wencai; Wen, Lei
ACS Nano, Vol. 4, Issue 6, p. 3187-3194
https://doi.org/10.1021/nn100740x

Storage device and method for sorption and desorption of molecular gas contained by storage sites of nano-filament laded reticulated aerogel
patent, May 2008

Struthers, Ralph C.; Chang, David B.; Toossi, Reza
US Patent Document 7,378,188
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7378188

Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000

Ferrari, A. C.; Robertson, J.
Physical Review B, Vol. 61, Issue 20, p. 14095-14107
https://doi.org/10.1103/PhysRevB.61.14095

Specific surface area of carbon nanotubes and bundles of carbon nanotubes
journal, April 2001

Peigney, A.; Laurent, Ch.; Flahaut, E.
Carbon, Vol. 39, Issue 4, p. 507-514
https://doi.org/10.1016/S0008-6223(00)00155-X

Process for preparing monoliths of aerogels of metal oxides
patent, May 1993

Cogliati, Guido; Bezzi, Giovanni
US Patent Document 5,207,814
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5207814

Highly conducting graphene sheets and Langmuir–Blodgett films
journal, August 2008

Li, Xiaolin; Zhang, Guangyu; Bai, Xuedong
Nature Nanotechnology, Vol. 3, Issue 9, p. 538-542
https://doi.org/10.1038/nnano.2008.210

Mn₃O₄−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries
journal, October 2010

Wang, Hailiang; Cui, Li-Feng; Yang, Yuan
Journal of the American Chemical Society, Vol. 132, Issue 40, p. 13978-13980
https://doi.org/10.1021/ja105296a

Stiff and electrically conductive composites of carbon nanotube aerogels and polymers
journal, January 2009

Worsley, Marcus A.; Kucheyev, Sergei O.; Kuntz, Joshua D.
Journal of Materials Chemistry, Vol. 19, Issue 21, p. 3370-3372
https://doi.org/10.1039/b905735h

Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
journal, September 2007

McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H.
Chemistry of Materials, Vol. 19, Issue 18, p. 4396-4404
https://doi.org/10.1021/cm0630800

Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004

Novoselov, K. S.
Science, Vol. 306, Issue 5696, p. 666-669
https://doi.org/10.1126/science.1102896

On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential
journal, January 2002

Laruelle, S.; Grugeon, S.; Poizot, P.
Journal of The Electrochemical Society, Vol. 149, Issue 5, p. A627-A634
https://doi.org/10.1149/1.1467947

A Controllable Self-Assembly Method for Large-Scale Synthesis of Graphene Sponges and Free-Standing Graphene Films
journal, May 2010

Liu, Fei; Seo, Tae Seok
Advanced Functional Materials, Vol. 20, Issue 12, p. 1930-1936
https://doi.org/10.1002/adfm.201000287

Crosslinked Graphene and Graphite Oxide
patent-application, August 2011

Lettow, John; Scheffer, Dan; Varma, Vipin
US Patent Application 12/848148; 20110189452
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220110189452%22.PGNR.&OS=DN/20110189452&RS=DN/20110189452

Practical Chemical Sensors from Chemically Derived Graphene
journal, February 2009

Fowler, Jesse D.; Allen, Matthew J.; Tung, Vincent C.
ACS Nano, Vol. 3, Issue 2, p. 301-306
https://doi.org/10.1021/nn800593m

Mechanically robust 3D graphene macroassembly with high surface area
journal, January 2012

Worsley, Marcus A.; Kucheyev, Sergei O.; Mason, Harris E.
Chemical Communications, Vol. 48, Issue 67, p. 8428-8430
https://doi.org/10.1039/c2cc33979j

Thermal and electrical conductivity of monolithic carbon aerogels
journal, January 1993

Lu, Xianping; Nilsson, Ove; Fricke, Jochen
Journal of Applied Physics, Vol. 73, Issue 2, p. 581-584
https://doi.org/10.1063/1.353367

S. J. Gregg, K. S. W. Sing: Adsorption, Surface Area and Porosity. 2. Auflage, Academic Press, London 1982. 303 Seiten, Preis: $ 49.50
journal, October 1982

Haul, R.
Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 86, Issue 10, p. 957-957
https://doi.org/10.1002/bbpc.19820861019

Ternary Self-Assembly of Ordered Metal Oxide−Graphene Nanocomposites for Electrochemical Energy Storage
journal, March 2010

Wang, Donghai; Kou, Rong; Choi, Daiwon
ACS Nano, Vol. 4, Issue 3, p. 1587-1595
https://doi.org/10.1021/nn901819n

Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite
journal, August 2009

Cote, Laura J.; Cruz-Silva, Rodolfo; Huang, Jiaxing
Journal of the American Chemical Society, Vol. 131, Issue 31, p. 11027-11032
https://doi.org/10.1021/ja902348k

Core excitons and vibronic coupling in diamond and graphite
journal, November 1993

Ma, Y.; Skytt, P.; Wassdahl, N.
Physical Review Letters, Vol. 71, Issue 22, p. 3725-3728
https://doi.org/10.1103/PhysRevLett.71.3725

Mechanically Robust, Electrically Conductive Ultralow-Density Carbon Nanotude-Based Aerogels
patent-application, July 2010

Worsley, Marcus A.; Kucheyev, Sergei O.; Baumann, Theodore F.
US Patent Application 12/652616; 20100187484
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220100187484%22.PGNR.&OS=DN/20100187484&RS=DN/20100187484

Facile Synthesis of a Crystalline, High-Surface-Area SnO₂ Aerogel
journal, June 2005

Baumann, T. F.; Kucheyev, S. O.; Gash, A. E.
Advanced Materials, Vol. 17, Issue 12, p. 1546-1548
https://doi.org/10.1002/adma.200500074

Extremely high thermal conductivity of graphene: Prospects for thermal management applications in nanoelectronic circuits
journal, April 2008

Ghosh, S.; Calizo, I.; Teweldebrhan, D.
Applied Physics Letters, Vol. 92, Issue 15, Article No. 151911
https://doi.org/10.1063/1.2907977

The Chemistry of Silica. Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry. VonR. K. Iler. John Wiley and Sons, Chichester 1979. XXIV, 886 S., geb. £ 39.50
journal, April 1980

Boehm, Hanns-Peter
Angewandte Chemie, Vol. 92, Issue 4
https://doi.org/10.1002/ange.19800920433

Similar Records in DOE Patents and OSTI.GOV collections:

High-density 3D graphene-based monolith and related materials, methods, and devices

Patent Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; ...

A composition comprising at least one high-density graphene-based monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds and having a density of at least 0.1 g/cm.sup.3. Also provided is a method comprising: preparing a reaction mixture comprising a suspension and at least one catalyst, said suspension selected from a graphene oxide (GO) suspension and a carbon nanotube suspension; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel, said drying step is substantially free of supercritical drying and freeze drying; and pyrolyzing the dry gel tomore »« less
Full Text Available
Method and device for secure, high-density tritium bonded with carbon

Patent Wertsching, Alan Kevin; Trantor, Troy Joseph; Ebner, Matthias Anthony; ...

A method and device for producing secure, high-density tritium bonded with carbon. A substrate comprising carbon is provided. A precursor is intercalated between carbon in the substrate. The precursor intercalated in the substrate is irradiated until at least a portion of the precursor, preferably a majority of the precursor, is transmutated into tritium and bonds with carbon of the substrate forming bonded tritium. The resulting bonded tritium, tritium bonded with carbon, produces electrons via beta decay. The substrate is preferably a substrate from the list of substrates consisting of highly-ordered pyrolytic graphite, carbon fibers, carbon nanotunes, buckministerfullerenes, and combinations thereof.more »« less
Full Text Available
Method and device to synthesize boron nitride nanotubes and related nanoparticles

Patent Zettl, Alexander K.

Methods and apparatus for producing chemical nanostructures having multiple elements, such as boron and nitride, e.g. boron nitride nanotubes, are disclosed. The method comprises creating a plasma jet, or plume, such as by an arc discharge. The plasma plume is elongated and has a temperature gradient along its length. It extends along its length into a port connector area having ports for introduction of feed materials. The feed materials include the multiple elements, which are introduced separately as fluids or powders at multiple ports along the length of the plasma plume, said ports entering the plasma plume at different temperatures.more »« less
Full Text Available
Method and device to synthesize boron nitride nanotubes and related nanoparticles

Patent Zettl, Alexander K.

Methods and apparatus for producing chemical nanostructures having multiple elements, such as boron and nitride, e.g. boron nitride nanotubes, are disclosed. The method comprises creating a plasma jet, or plume, such as by an arc discharge. The plasma plume is elongated and has a temperature gradient along its length. It extends along its length into a port connector area having ports for introduction of feed materials. The feed materials include the multiple elements, which are introduced separately as fluids or powders at multiple ports along the length of the plasma plume, said ports entering the plasma plume at different temperatures.more »« less
Full Text Available
Photovoltaic device using single wall carbon nanotubes and method of fabricating the same

Patent Biris, Alexandru S.; Li, Zhongrui

A photovoltaic device and methods for forming the same. In one embodiment, the photovoltaic device has a silicon substrate, and a film comprising a plurality of single wall carbon nanotubes disposed on the silicon substrate, wherein the plurality of single wall carbon nanotubes forms a plurality of heterojunctions with the silicon in the substrate.
Full Text Available

Similar Records

Title: High-density carbon nanotube-based monolith and related materials, methods, and devices

Abstract

Citation Formats

Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process journal, July 2010

Graphene-Wrapped Fe3O4 Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries journal, September 2010

Structural Studies of Lithium Intercalation in a Nanocrystalline α-Fe2O3Compound journal, January 2006

Fabrication of Graphene-Polymer Nanocomposites With Higher-Order Three-Dimensional Architectures journal, June 2009

Assembly of Graphene Sheets into 3D Macroscopic Structures journal, May 2012

Comment on “Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene” journal, March 2009

In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode journal, December 2010

Advanced carbon aerogels for energy applications journal, January 2011

Epitaxial graphene on ruthenium journal, April 2008

Carrier Transport in Two-Dimensional Graphene Layers journal, May 2007

Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets journal, November 2007

Large scale manufacturing of nanostructured material patent-application, April 2010

Strong Akaganeite Aerogel Monoliths Using Epoxides: Synthesis and Characterization journal, August 2003

Combined XRD, EXAFS, and Mossbauer Studies of the Reduction by Lithium of α-Fe2O3 with Various Particle Sizes journal, January 2003

Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene journal, July 2008

Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide journal, May 2010

Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells journal, January 2008

Graphene-based electrochemical supercapacitors journal, January 2008

Properties of single-walled carbon nanotube-based aerogels as a function of nanotube loading journal, October 2009

Aqueous Dispersion of Graphene Sheets Stabilized by Pluronic Copolymers: Formation of Supramolecular Hydrogel journal, August 2009

Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation journal, February 2009

Synthesis and Characterization of Nanometric Iron and Iron-Titanium Oxides by Mechanical Milling: Electrochemical Properties as Anodic Materials in Lithium Cells journal, January 2005

Graphene Aerogels patent-application, February 2012

Graphene Based Electrochemical Sensors and Biosensors: A Review journal, March 2010

Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries journal, January 1998

Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition journal, April 2011

Method of manufacturing aerogel composites patent, March 1999

Unitary graphene layer or graphene single crystal patent-application, May 2014

Raman validity for crystallite size La determination on reticulated vitreous carbon with different graphitization index journal, November 2007

Giant Intrinsic Carrier Mobilities in Graphene and Its Bilayer journal, January 2008

Superior Thermal Conductivity of Single-Layer Graphene journal, March 2008

Binder-Free and Carbon-Free Nanoparticle Batteries: A Method for Nanoparticle Electrodes without Polymeric Binders or Carbon Black journal, September 2012

An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments journal, June 1992

Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material journal, April 2008

Graphene Aerogels conference, January 2009

X-ray absorption spectroscopy of graphite oxide journal, June 2008

Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels journal, January 2003

Mechanically robust and electrically conductive carbon nanotube foams journal, February 2009

Nanostructured Reduced Graphene Oxide/Fe2O3 Composite As a High-Performance Anode Material for Lithium Ion Batteries journal, April 2011

Functionalized graphene sheet filled silicone foam nanocomposites journal, January 2008

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries journal, September 2000

Aerogel and xerogel composites for use as carbon anodes patent, October 2010

Graphene Compositions patent-application, August 2011

Carbon Scaffolds for Stiff and Highly Conductive Monolithic Oxide–Carbon Nanotube Composites journal, June 2011

Graphene Tapes patent-application, November 2011

In situ infrared observation of the pyrolysis process of carbon aerogels journal, April 1998

Functionalized graphene sheets for polymer nanocomposites journal, May 2008

Raman Spectrum of Graphene and Graphene Layers journal, October 2006

Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene journal, August 2008

Synthesis of Graphene Aerogel with High Electrical Conductivity journal, October 2010

Unitary graphene matrix composites containing carbon or graphite fillers patent-application, June 2014

The rise of graphene journal, March 2007

High Surface Area, sp2-Cross-Linked Three-Dimensional Graphene Monoliths journal, April 2011

Electronic and structural properties of graphene-based transparent and conductive thin film electrodes journal, October 2008

Aerogel and xerogel composites for use as carbon anodes patent, August 2008

Chemical composition patent, March 1999

Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide journal, May 2010

Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene journal, February 2007

Depth-sensing indentation of low-density brittle nanoporous solids journal, July 2009

Carbon 1s near-edge-absorption fine structure in graphite journal, July 1993

Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries journal, August 2008

Detection of individual gas molecules adsorbed on graphene journal, July 2007

Graphene and graphene oxide aerogels patent-application, June 2010

Graphene-based composite materials journal, July 2006

Structure and electronic properties of a nongraphitic disordered carbon system and its heat-treatment effects journal, June 2003

Preparation of Graphitic Oxide journal, March 1958

Graphene aerogels patent, March 2015

Graphene Anchored with Co3O4 Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance journal, June 2010

Storage device and method for sorption and desorption of molecular gas contained by storage sites of nano-filament laded reticulated aerogel patent, May 2008

Interpretation of Raman spectra of disordered and amorphous carbon journal, May 2000

Specific surface area of carbon nanotubes and bundles of carbon nanotubes journal, April 2001

Process for preparing monoliths of aerogels of metal oxides patent, May 1993

Highly conducting graphene sheets and Langmuir–Blodgett films journal, August 2008

Mn3O4−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries journal, October 2010

Stiff and electrically conductive composites of carbon nanotube aerogels and polymers journal, January 2009

Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite journal, September 2007

Electric Field Effect in Atomically Thin Carbon Films journal, October 2004

Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process
journal, July 2010

Graphene-Wrapped Fe₃O₄ Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries
journal, September 2010

Structural Studies of Lithium Intercalation in a Nanocrystalline α-Fe₂O₃Compound
journal, January 2006

Fabrication of Graphene-Polymer Nanocomposites With Higher-Order Three-Dimensional Architectures
journal, June 2009

Assembly of Graphene Sheets into 3D Macroscopic Structures
journal, May 2012

Comment on “Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene”
journal, March 2009

In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode
journal, December 2010

Advanced carbon aerogels for energy applications
journal, January 2011

Epitaxial graphene on ruthenium
journal, April 2008

Carrier Transport in Two-Dimensional Graphene Layers
journal, May 2007

Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets
journal, November 2007

Large scale manufacturing of nanostructured material
patent-application, April 2010

Strong Akaganeite Aerogel Monoliths Using Epoxides: Synthesis and Characterization
journal, August 2003

Combined XRD, EXAFS, and Mossbauer Studies of the Reduction by Lithium of α-Fe₂O₃ with Various Particle Sizes
journal, January 2003

Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
journal, July 2008

Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide
journal, May 2010

Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells
journal, January 2008

Graphene-based electrochemical supercapacitors
journal, January 2008

Properties of single-walled carbon nanotube-based aerogels as a function of nanotube loading
journal, October 2009

Aqueous Dispersion of Graphene Sheets Stabilized by Pluronic Copolymers: Formation of Supramolecular Hydrogel
journal, August 2009

Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation
journal, February 2009

Synthesis and Characterization of Nanometric Iron and Iron-Titanium Oxides by Mechanical Milling: Electrochemical Properties as Anodic Materials in Lithium Cells
journal, January 2005

Graphene Aerogels
patent-application, February 2012

Graphene Based Electrochemical Sensors and Biosensors: A Review
journal, March 2010

Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries
journal, January 1998

Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition
journal, April 2011

Method of manufacturing aerogel composites
patent, March 1999

Unitary graphene layer or graphene single crystal
patent-application, May 2014

Raman validity for crystallite size L_a determination on reticulated vitreous carbon with different graphitization index
journal, November 2007

Giant Intrinsic Carrier Mobilities in Graphene and Its Bilayer
journal, January 2008

Superior Thermal Conductivity of Single-Layer Graphene
journal, March 2008

Binder-Free and Carbon-Free Nanoparticle Batteries: A Method for Nanoparticle Electrodes without Polymeric Binders or Carbon Black
journal, September 2012

An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments
journal, June 1992

Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material
journal, April 2008

Graphene Aerogels
conference, January 2009

X-ray absorption spectroscopy of graphite oxide
journal, June 2008

Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels
journal, January 2003

Mechanically robust and electrically conductive carbon nanotube foams
journal, February 2009

Nanostructured Reduced Graphene Oxide/Fe₂O₃ Composite As a High-Performance Anode Material for Lithium Ion Batteries
journal, April 2011

Functionalized graphene sheet filled silicone foam nanocomposites
journal, January 2008

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

Aerogel and xerogel composites for use as carbon anodes
patent, October 2010

Graphene Compositions
patent-application, August 2011

Carbon Scaffolds for Stiff and Highly Conductive Monolithic Oxide–Carbon Nanotube Composites
journal, June 2011

Graphene Tapes
patent-application, November 2011

In situ infrared observation of the pyrolysis process of carbon aerogels
journal, April 1998

Functionalized graphene sheets for polymer nanocomposites
journal, May 2008

Raman Spectrum of Graphene and Graphene Layers
journal, October 2006

Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene
journal, August 2008

Synthesis of Graphene Aerogel with High Electrical Conductivity
journal, October 2010

Unitary graphene matrix composites containing carbon or graphite fillers
patent-application, June 2014

The rise of graphene
journal, March 2007

High Surface Area, sp²-Cross-Linked Three-Dimensional Graphene Monoliths
journal, April 2011

Electronic and structural properties of graphene-based transparent and conductive thin film electrodes
journal, October 2008

Aerogel and xerogel composites for use as carbon anodes
patent, August 2008

Chemical composition
patent, March 1999

Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide
journal, May 2010

Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene
journal, February 2007

Depth-sensing indentation of low-density brittle nanoporous solids
journal, July 2009

Carbon 1s near-edge-absorption fine structure in graphite
journal, July 1993

Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries
journal, August 2008

Detection of individual gas molecules adsorbed on graphene
journal, July 2007

Graphene and graphene oxide aerogels
patent-application, June 2010

Graphene-based composite materials
journal, July 2006

Structure and electronic properties of a nongraphitic disordered carbon system and its heat-treatment effects
journal, June 2003

Preparation of Graphitic Oxide
journal, March 1958

Graphene aerogels
patent, March 2015

Graphene Anchored with Co₃O₄ Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance
journal, June 2010

Storage device and method for sorption and desorption of molecular gas contained by storage sites of nano-filament laded reticulated aerogel
patent, May 2008

Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000

Specific surface area of carbon nanotubes and bundles of carbon nanotubes
journal, April 2001

Process for preparing monoliths of aerogels of metal oxides
patent, May 1993

Highly conducting graphene sheets and Langmuir–Blodgett films
journal, August 2008

Mn₃O₄−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries
journal, October 2010

Stiff and electrically conductive composites of carbon nanotube aerogels and polymers
journal, January 2009

Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
journal, September 2007

Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004

On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential
journal, January 2002

A Controllable Self-Assembly Method for Large-Scale Synthesis of Graphene Sponges and Free-Standing Graphene Films
journal, May 2010

Crosslinked Graphene and Graphite Oxide
patent-application, August 2011