High-density carbon nanotube-based monolith and related materials, methods, and devices

Title: High-density carbon nanotube-based monolith and related materials, methods, and devices

Abstract

Disclosed here is a composition comprising at least one high-density carbon-nanotube-based monolith, said monolith comprising carbon nanotubes crosslinked by nanoparticles and having a density of at least 0.2 g/cm³. Also provided is a method for making the composition comprising: preparing a reaction mixture comprising a suspension and at least one catalyst, said suspension is a carbon nanotube suspension; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel, said drying step is substantially free of supercritical drying and freeze drying; and pyrolyzing the dry gel to produce the composition comprising a high-density carbon-nanotube-based monolith. Exceptional combinations of properties are achieved including high conductive and mechanical properties.

Inventors:: Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; Charnvanichborikarn, Supakit; Kucheyev, Sergei; Montalvo, Elizabeth; Shin, Swanee; Tylski, Elijah

Issue Date:: 2018-07-03

Research Org.:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1461503

Patent Number(s):: 10014090

Application Number:: 15/217,858

Assignee:: Lawrence Livermore National Security, LLC (Livermore, CA)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2202/04 - Nanotubes with a specific amount of walls

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2006/40 - Electric properties

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/174 - Derivatisation
C01B2202/22 - Electronic properties
C01B32/166 - in liquid phase
C01B2202/02 - Single-walled nanotubes

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES
H01B1/04 - mainly consisting of carbon-silicon compounds, carbon or silicon

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DOE Contract Number:: AC52-07NA27344

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Jul 22

Country of Publication:: United States

Language:: English

Citation Formats


                    Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Charnvanichborikarn, Supakit, Kucheyev, Sergei, Montalvo, Elizabeth, Shin, Swanee, and Tylski, Elijah. High-density carbon nanotube-based monolith and related materials, methods, and devices.  United States: N. p., 2018. 
        Web.

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                    Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Charnvanichborikarn, Supakit, Kucheyev, Sergei, Montalvo, Elizabeth, Shin, Swanee, & Tylski, Elijah. High-density carbon nanotube-based monolith and related materials, methods, and devices.  United States.

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                    Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Charnvanichborikarn, Supakit, Kucheyev, Sergei, Montalvo, Elizabeth, Shin, Swanee, and Tylski, Elijah. Tue .  
        "High-density carbon nanotube-based monolith and related materials, methods, and devices".  United States.  https://www.osti.gov/servlets/purl/1461503.

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@article{osti_1461503,

  title        = {High-density carbon nanotube-based monolith and related materials, methods, and devices},

  author       = {Worsley, Marcus A. and Baumann, Theodore F. and Biener, Juergen and Charnvanichborikarn, Supakit and Kucheyev, Sergei and Montalvo, Elizabeth and Shin, Swanee and Tylski, Elijah},

  abstractNote = {Disclosed here is a composition comprising at least one high-density carbon-nanotube-based monolith, said monolith comprising carbon nanotubes crosslinked by nanoparticles and having a density of at least 0.2 g/cm3. Also provided is a method for making the composition comprising: preparing a reaction mixture comprising a suspension and at least one catalyst, said suspension is a carbon nanotube suspension; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel, said drying step is substantially free of supercritical drying and freeze drying; and pyrolyzing the dry gel to produce the composition comprising a high-density carbon-nanotube-based monolith. Exceptional combinations of properties are achieved including high conductive and mechanical properties.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {7}

}

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Worsley, Marcus A.; Kucheyev, Sergei O.; Kuntz, Joshua D.
Journal of Materials Chemistry, Vol. 19, Issue 21, p. 3370-3372
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Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
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McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H.
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A Controllable Self-Assembly Method for Large-Scale Synthesis of Graphene Sponges and Free-Standing Graphene Films
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Crosslinked Graphene and Graphite Oxide
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High surface area carbon nanotube-supported titanium carbonitride aerogels
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Journal of Materials Chemistry, Vol. 19, Issue 31, p. 5503-5506
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Mechanically robust 3D graphene macroassembly with high surface area
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Title: High-density carbon nanotube-based monolith and related materials, methods, and devices

Abstract

Citation Formats

Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process journal, July 2010

Graphene-Wrapped Fe3O4 Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries journal, September 2010

Structural Studies of Lithium Intercalation in a Nanocrystalline α-Fe2O3Compound journal, January 2006

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In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode journal, December 2010

Advanced carbon aerogels for energy applications journal, January 2011

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Synthesis and Characterization of Nanometric Iron and Iron-Titanium Oxides by Mechanical Milling: Electrochemical Properties as Anodic Materials in Lithium Cells journal, January 2005

Graphene Aerogels patent-application, February 2012

Graphene Based Electrochemical Sensors and Biosensors: A Review journal, March 2010

Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries journal, January 1998

Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition journal, April 2011

In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures journal, January 2011

Method of manufacturing aerogel composites patent, March 1999

Unitary graphene layer or graphene single crystal patent-application, May 2014

Raman validity for crystallite size La determination on reticulated vitreous carbon with different graphitization index journal, November 2007

Giant Intrinsic Carrier Mobilities in Graphene and Its Bilayer journal, January 2008

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Binder-Free and Carbon-Free Nanoparticle Batteries: A Method for Nanoparticle Electrodes without Polymeric Binders or Carbon Black journal, September 2012

An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments journal, June 1992

Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material journal, April 2008

Graphene Aerogels conference, January 2009

X-ray absorption spectroscopy of graphite oxide journal, June 2008

Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels journal, January 2003

Mechanically robust and electrically conductive carbon nanotube foams journal, February 2009

Nanostructured Reduced Graphene Oxide/Fe2O3 Composite As a High-Performance Anode Material for Lithium Ion Batteries journal, April 2011

Functionalized graphene sheet filled silicone foam nanocomposites journal, January 2008

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries journal, September 2000

Aerogel and xerogel composites for use as carbon anodes patent, October 2010

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In situ infrared observation of the pyrolysis process of carbon aerogels journal, April 1998

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Raman Spectrum of Graphene and Graphene Layers journal, October 2006

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Synthesis of Graphene Aerogel with High Electrical Conductivity journal, October 2010

The rise of graphene journal, March 2007

High Surface Area, sp2-Cross-Linked Three-Dimensional Graphene Monoliths journal, April 2011

Electronic and structural properties of graphene-based transparent and conductive thin film electrodes journal, October 2008

Aerogel and xerogel composites for use as carbon anodes patent, August 2008

Chemical composition patent, March 1999

Mechanically robust 3D graphene macroassembly with high surface area journal, January 2012

Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide journal, May 2010

Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene journal, February 2007

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Detection of individual gas molecules adsorbed on graphene journal, July 2007

Graphene-based composite materials journal, July 2006

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Graphene aerogels patent, March 2015

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Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite journal, September 2007

Electric Field Effect in Atomically Thin Carbon Films journal, October 2004

On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential journal, January 2002

A Controllable Self-Assembly Method for Large-Scale Synthesis of Graphene Sponges and Free-Standing Graphene Films journal, May 2010

Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process
journal, July 2010

Graphene-Wrapped Fe₃O₄ Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries
journal, September 2010

Structural Studies of Lithium Intercalation in a Nanocrystalline α-Fe₂O₃Compound
journal, January 2006

Fabrication of Graphene-Polymer Nanocomposites With Higher-Order Three-Dimensional Architectures
journal, June 2009

Assembly of Graphene Sheets into 3D Macroscopic Structures
journal, May 2012

Comment on “Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene”
journal, March 2009

In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode
journal, December 2010

Advanced carbon aerogels for energy applications
journal, January 2011

Epitaxial graphene on ruthenium
journal, April 2008

Carrier Transport in Two-Dimensional Graphene Layers
journal, May 2007

Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets
journal, November 2007

Large scale manufacturing of nanostructured material
patent-application, April 2010

Strong Akaganeite Aerogel Monoliths Using Epoxides: Synthesis and Characterization
journal, August 2003

Combined XRD, EXAFS, and Mossbauer Studies of the Reduction by Lithium of α-Fe₂O₃ with Various Particle Sizes
journal, January 2003

Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
journal, July 2008

Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide
journal, May 2010

Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells
journal, January 2008

Graphene-based electrochemical supercapacitors
journal, January 2008

Properties of single-walled carbon nanotube-based aerogels as a function of nanotube loading
journal, October 2009

Aqueous Dispersion of Graphene Sheets Stabilized by Pluronic Copolymers: Formation of Supramolecular Hydrogel
journal, August 2009

Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation
journal, February 2009

Synthesis and Characterization of Nanometric Iron and Iron-Titanium Oxides by Mechanical Milling: Electrochemical Properties as Anodic Materials in Lithium Cells
journal, January 2005

Graphene Aerogels
patent-application, February 2012

Graphene Based Electrochemical Sensors and Biosensors: A Review
journal, March 2010

Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries
journal, January 1998

Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition
journal, April 2011

In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures
journal, January 2011

Method of manufacturing aerogel composites
patent, March 1999

Unitary graphene layer or graphene single crystal
patent-application, May 2014

Raman validity for crystallite size L_a determination on reticulated vitreous carbon with different graphitization index
journal, November 2007

Giant Intrinsic Carrier Mobilities in Graphene and Its Bilayer
journal, January 2008

Superior Thermal Conductivity of Single-Layer Graphene
journal, March 2008

Binder-Free and Carbon-Free Nanoparticle Batteries: A Method for Nanoparticle Electrodes without Polymeric Binders or Carbon Black
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An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments
journal, June 1992

Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material
journal, April 2008

Graphene Aerogels
conference, January 2009

X-ray absorption spectroscopy of graphite oxide
journal, June 2008

Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels
journal, January 2003

Mechanically robust and electrically conductive carbon nanotube foams
journal, February 2009

Nanostructured Reduced Graphene Oxide/Fe₂O₃ Composite As a High-Performance Anode Material for Lithium Ion Batteries
journal, April 2011

Functionalized graphene sheet filled silicone foam nanocomposites
journal, January 2008

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

Aerogel and xerogel composites for use as carbon anodes
patent, October 2010

Carbon Scaffolds for Stiff and Highly Conductive Monolithic Oxide–Carbon Nanotube Composites
journal, June 2011

In situ infrared observation of the pyrolysis process of carbon aerogels
journal, April 1998

Functionalized graphene sheets for polymer nanocomposites
journal, May 2008

Raman Spectrum of Graphene and Graphene Layers
journal, October 2006

Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene
journal, August 2008

Synthesis of Graphene Aerogel with High Electrical Conductivity
journal, October 2010

The rise of graphene
journal, March 2007

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journal, April 2011

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journal, October 2008

Aerogel and xerogel composites for use as carbon anodes
patent, August 2008

Chemical composition
patent, March 1999

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journal, January 2012

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journal, July 2009

Carbon 1s near-edge-absorption fine structure in graphite
journal, July 1993

Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries
journal, August 2008

Detection of individual gas molecules adsorbed on graphene
journal, July 2007

Graphene-based composite materials
journal, July 2006

Structure and electronic properties of a nongraphitic disordered carbon system and its heat-treatment effects
journal, June 2003

Preparation of Graphitic Oxide
journal, March 1958

Graphene aerogels
patent, March 2015

Graphene Anchored with Co₃O₄ Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance
journal, June 2010

Storage device and method for sorption and desorption of molecular gas contained by storage sites of nano-filament laded reticulated aerogel
patent, May 2008

Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000

Specific surface area of carbon nanotubes and bundles of carbon nanotubes
journal, April 2001

Process for preparing monoliths of aerogels of metal oxides
patent, May 1993

Highly conducting graphene sheets and Langmuir–Blodgett films
journal, August 2008

Mn₃O₄−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries
journal, October 2010

Stiff and electrically conductive composites of carbon nanotube aerogels and polymers
journal, January 2009

Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
journal, September 2007

Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004

On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential
journal, January 2002

A Controllable Self-Assembly Method for Large-Scale Synthesis of Graphene Sponges and Free-Standing Graphene Films
journal, May 2010

Crosslinked Graphene and Graphite Oxide
patent-application, August 2011

Practical Chemical Sensors from Chemically Derived Graphene
journal, February 2009

High surface area carbon nanotube-supported titanium carbonitride aerogels
journal, January 2009