High voltage redox shuttles, method for making high voltage redox shuttles
Abstract
The invention provides a method for producing a molecule capable of undergoing reduction-oxidation when subjected to a voltage potential, the method comprising phosphorylating hydroquinone to create a first intermediate; rearranging the first intermediate to an aryl-bis-(phosphonate) thereby creating a second intermediate comprising phosphorous alkoxy groups; alkylating (e.g., methylating) the second intermediate; converting the alkoxy groups to halides; and substituting the halides to alkyl or aryl groups. Also provided is a system for preventing overcharge in a Lithium-ion battery, the method comprising a mixture of a redox shuttle with electrolyte in the battery such that the shuttle comprises between about 10 and about 20 weight percent of the mixture.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1459568
- Patent Number(s):
- 10008743
- Application Number:
- 14/171,556
- Assignee:
- UCHICAGO ARGONNE, LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Feb 03
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Krumdick, Gregory K., Dzwiniel, Trevor L., and Pupek, Krzysztof. High voltage redox shuttles, method for making high voltage redox shuttles. United States: N. p., 2018.
Web.
Krumdick, Gregory K., Dzwiniel, Trevor L., & Pupek, Krzysztof. High voltage redox shuttles, method for making high voltage redox shuttles. United States.
Krumdick, Gregory K., Dzwiniel, Trevor L., and Pupek, Krzysztof. Tue .
"High voltage redox shuttles, method for making high voltage redox shuttles". United States. https://www.osti.gov/servlets/purl/1459568.
@article{osti_1459568,
title = {High voltage redox shuttles, method for making high voltage redox shuttles},
author = {Krumdick, Gregory K. and Dzwiniel, Trevor L. and Pupek, Krzysztof},
abstractNote = {The invention provides a method for producing a molecule capable of undergoing reduction-oxidation when subjected to a voltage potential, the method comprising phosphorylating hydroquinone to create a first intermediate; rearranging the first intermediate to an aryl-bis-(phosphonate) thereby creating a second intermediate comprising phosphorous alkoxy groups; alkylating (e.g., methylating) the second intermediate; converting the alkoxy groups to halides; and substituting the halides to alkyl or aryl groups. Also provided is a system for preventing overcharge in a Lithium-ion battery, the method comprising a mixture of a redox shuttle with electrolyte in the battery such that the shuttle comprises between about 10 and about 20 weight percent of the mixture.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {6}
}
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