Title: Composition for fuel cell electrode

Abstract

In some examples, a fuel cell including an anode; electrolyte; and cathode separated from the anode by the electrolyte, wherein the cathode includes a Pr-nickelate based material with (Pr.sub.1-xA_x)_n+1(Ni_1-yB_y)_nO₃n+1+.delta. as a general formula, where n is 1 as an integer, A is an A-site dopant including of a metal of a group formed by one or more lanthanides, and B is a B-site dopant including of a metal of a group formed by one or more transition metals, wherein the A and B-site dopants are provided such that there is an increase in phase-stability and reduction in degradation of the Pr-nickelate based material, and A is at least one metal cation of lanthanides, La, Nd, Sm, or Gd, B is at least one metal cation of transition metals, Cu, Co, Mn, Zn, or Cr, where: 0<1, and 0

Inventors:

Jung, Hwa Young; Xing, Zhengliang; Liu, Zhien; Goettler, Richard W.; Zhou, Xiao-Dong; Dogdibegovic, Emir

Issue Date:

2018-06-19

Research Org.:

LG Fuel Cell Systems, Inc., North Canton, OH (United States); Univ. of South Carolina, Columbia, SC (United States)

Sponsoring Org.:

USDOE

OSTI Identifier:

1458518

Patent Number(s):

10003083

Application Number:

14/805,279

Assignee:

LG Fuel Cell Systems, Inc. (North Canton, OH); University of South Carolina (Columbia, SC)

Patent Classifications (CPCs):

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

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C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C04B2235/3284 - Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M8/1246 - the electrolyte consisting of oxides
H01M4/9033 - {Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites}
H01M8/1231 - with both reactants being gaseous or vaporised

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C04B2235/80 - Phases present in the sintered or melt-cast ceramic products other than the main phase
C04B2235/3213 - Strontium oxides or oxide-forming salts thereof

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

Y02P70/50 - Manufacturing or production processes characterised by the final manufactured product

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C04B2235/3274 - Ferrites
C04B2235/3275 - Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Y02E60/50 - Fuel cells

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M2008/1293 - {Fuel cells with solid oxide electrolytes}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C04B2235/3281 - Copper oxides, cuprates or oxide-forming salts thereof, e.g. CuO or Cu2O
C04B35/01 - based on oxide ceramics
C04B2235/3279 - Nickel oxides, nickalates, or oxide-forming salts thereof

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M8/004 - {Cylindrical, tubular or wound}
H01M2300/0071 - Oxides
H01M8/0217 - Complex oxides, optionally doped, of the type AMO3, A being an alkaline earth metal or rare earth metal and M being a metal, e.g. perovskites
H01M2300/0074 - Ion conductive at high temperature

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C04B2235/3262 - Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
C04B2235/3227 - Lanthanum oxide or oxide-forming salts thereof
C04B2235/768 - Perovskite structure ABO3

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M8/006 - {Flat}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C04B2235/76 - Crystal structural characteristics, e.g. symmetry

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M8/0236 - Glass

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

C04B2235/3241 - Chromium oxides, chromates, or oxide-forming salts thereof
C04B2235/3224 - Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide

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DOE Contract Number:  

FE0000303

Resource Type:

Patent

Resource Relation:

Patent File Date: 2015 Jul 21

Country of Publication:

United States

Language:

English

Subject:

25 ENERGY STORAGE