Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks
Abstract
Organic charge-transfer (CT) co-crystals in a mixed stack system are disclosed, wherein a donor molecule (D) and an acceptor molecule (A) occupy alternating positions (DADADA) along the CT axis. A platform is provided which amplifies the molecular recognition of donors and acceptors and produces co-crystals at ambient conditions, wherein the platform comprises (i) a molecular design of the first constituent (.alpha.-complement), (ii) a molecular design of the second compound (.beta.-complement), and (iii) a solvent system that promotes co-crystallization.
- Inventors:
- Issue Date:
- Research Org.:
- Northwestern Univ., Evanston, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1457701
- Patent Number(s):
- 9997272
- Application Number:
- 15/252,852
- Assignee:
- Northwestern University (Evanston, IL)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES
- DOE Contract Number:
- SC0000989
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2016 Aug 31
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS
Citation Formats
Stupp, Samuel I., Stoddart, J. Fraser, Shveyd, Alexander K., Tayi, Alok S., Sue, Chi-Hau, and Narayanan, Ashwin. Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks. United States: N. p., 2018.
Web.
Stupp, Samuel I., Stoddart, J. Fraser, Shveyd, Alexander K., Tayi, Alok S., Sue, Chi-Hau, & Narayanan, Ashwin. Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks. United States.
Stupp, Samuel I., Stoddart, J. Fraser, Shveyd, Alexander K., Tayi, Alok S., Sue, Chi-Hau, and Narayanan, Ashwin. Tue .
"Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks". United States. https://www.osti.gov/servlets/purl/1457701.
@article{osti_1457701,
title = {Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks},
author = {Stupp, Samuel I. and Stoddart, J. Fraser and Shveyd, Alexander K. and Tayi, Alok S. and Sue, Chi-Hau and Narayanan, Ashwin},
abstractNote = {Organic charge-transfer (CT) co-crystals in a mixed stack system are disclosed, wherein a donor molecule (D) and an acceptor molecule (A) occupy alternating positions (DADADA) along the CT axis. A platform is provided which amplifies the molecular recognition of donors and acceptors and produces co-crystals at ambient conditions, wherein the platform comprises (i) a molecular design of the first constituent (.alpha.-complement), (ii) a molecular design of the second compound (.beta.-complement), and (iii) a solvent system that promotes co-crystallization.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 12 00:00:00 EDT 2018},
month = {Tue Jun 12 00:00:00 EDT 2018}
}
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