Functionalized ionic liquid electrolytes for lithium ion batteries

Title: Functionalized ionic liquid electrolytes for lithium ion batteries

Abstract

An ionic liquid that is a salt has a Formula: ##STR00001## Such ionic liquids may be used in electrolytes and in electrochemical cells.

Inventors:: Zhang, Zhengcheng; Weng, Wei; Zhang, Lu; Amine, Khalil

Issue Date:: 2018-06-05

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1457033

Patent Number(s):: 9,991,559

Application Number:: 14/742,194

Assignee:: UChicago Argonne, LLC (Chicago, IL)

DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Jun 17

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Zhang, Zhengcheng, Weng, Wei, Zhang, Lu, and Amine, Khalil. Functionalized ionic liquid electrolytes for lithium ion batteries.  United States: N. p., 2018. 
        Web.

Copy to clipboard


                    Zhang, Zhengcheng, Weng, Wei, Zhang, Lu, & Amine, Khalil. Functionalized ionic liquid electrolytes for lithium ion batteries.  United States.

Copy to clipboard


                    Zhang, Zhengcheng, Weng, Wei, Zhang, Lu, and Amine, Khalil. Tue .  
        "Functionalized ionic liquid electrolytes for lithium ion batteries".  United States.  https://www.osti.gov/servlets/purl/1457033.

Copy to clipboard


                    
@article{osti_1457033,

  title        = {Functionalized ionic liquid electrolytes for lithium ion batteries},

  author       = {Zhang, Zhengcheng and Weng, Wei and Zhang, Lu and Amine, Khalil},

  abstractNote = {An ionic liquid that is a salt has a Formula: ##STR00001## Such ionic liquids may be used in electrolytes and in electrochemical cells.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {6}

}

Copy to clipboard

Patent:

View Patent

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

High cycle life secondary lithium battery
patent, October 1985

Yen, Shiao-Ping; Carter, Boyd; Shen, David
US Patent Document 4,550,064
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F4550064

Layer for stabilization of lithium anode
patent, January 1996

Koksbang, Rene
US Patent Document 5,487,959
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5487959

Solid polymer electrolyte-based oxygen batteries
patent, April 1996

Abraham, Kuzhikalail M.; Jiang, Zhiping
US Patent Document 5,510,209
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5510209

Semipermeable composite membrane and a method for the preparation of such a membrane
patent, November 1998

Zwijnenburg, Arie; De Rijk, Jan Willem; Rekers, Casper
US Patent Document 5,833,854
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5833854

Starburst conjugates
patent, January 2001

Tomalia, Donald; Kruper, William; Cheng, Roberta
US Patent Document 6,177,414
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6177414

Non-aqueous electrolyte solvents for secondary cells
patent, June 2001

Angell, Charles; Xu, Kang; Kovalev, Igor
US Patent Document 6,245,465
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6245465

Dendrimer monolayer films
patent, November 2001

Crooks, Richard; Ricco, Antonio; Wells, Mona
US Patent Document 6,312,809
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6312809

Electrolyte
patent, September 2004

Koike, Tsuneaki; Yumoto, Hiroyuki; Tsukamoto, Hisashi
US Patent Document 6,787,268
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6787268

High ionic conductivity gel polymer electrolyte for rechargeable polymer batteries
patent, January 2005

Park, Chi-Kyun; Zhang, Zhiwei; Sun, Lu Ying
US Patent Document 6,841,303
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6841303

Manufacturing method and apparatus of 4-fluoroethylene carbonate
patent, September 2007

Woo, Byung Won; Yoon, Seoung Woo; Lee, Jun Ho
US Patent Document 7,268,238
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7268238

Lithium/air batteries with LiPON as separator and protective barrier and method
patent, March 2008

Klaassen, Jody J.
US Patent Document 7,344,804
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7344804

Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes
patent, July 2013

Chen, Zonghai; Amine, Khalil
US Patent Document 8,475,688
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F8475688

Polymer lithium battery with ionic electrolyte
patent-application, August 2003

Huang, Sui-Yang
US Patent Document 10/368926; 20030157409
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220030157409%22.PGNR.&OS=DN/20030157409&RS=DN/20030157409

Lithium based electrochemical cell systems
patent-application, August 2004

Hyung, Yoo-Eup; Vissers, Donald R.; Amine, Khalil
US Patent Application 10/738400; 20040151951
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220040151951%22.PGNR.&OS=DN/20040151951&RS=DN/20040151951

Electrolytic Solution
patent-application, April 2009

Koh, Meiten; Yamauchi, Akiyoshi
US Patent Application 11/887543; 20090086408
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220090086408%22.PGNR.&OS=DN/20090086408&RS=DN/20090086408

A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery
journal, January 1996

Abraham, K. M.; Jiang, Z.
Journal of The Electrochemical Society, Vol. 143, Issue 1, p. 1-5
DOI: 10.1149/1.1836378

Novel silane compounds as electrolyte solvents for Li-ion batteries
journal, March 2006

Amine, Khalil; Wang, Qingzheng; Vissers, Donald R.
Electrochemistry Communications, Vol. 8, Issue 3, p. 429-433
DOI: 10.1016/j.elecom.2005.12.017

Transient behavior of insertion reaction electrodes
journal, July 1996

Huggins, Robert A.
Solid State Ionics, Vol. 86-88, Issue Part 1, p. 41-48
DOI: 10.1016/0167-2738(96)00090-2

Can All the Lithium be Removed from T ₂ Li_2 / 3 [ Ni_1 / 3Mn_2 / 3 ] O ₂ ?
journal, January 2001

Lu, Zhonghua; Dahn, J. R.
Journal of The Electrochemical Society, Vol. 148, Issue 7, p. A710-A715
DOI: 10.1149/1.1376116

Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes
journal, September 1999

McMillan, Rod; Slegr, Helen; Shu, Z. X.
Journal of Power Sources, Vol. 81-82, p. 20-26
DOI: 10.1016/S0378-7753(98)00201-8

Understanding siloxane functionalised ionic liquids
journal, January 2010

Niedermeyer, Heiko; Ab Rani, Mohd Azri; Lickiss, Paul D.
Physical Chemistry Chemical Physics, Vol. 12, Issue 8, p. 2018-2029
DOI: 10.1039/B922011A

Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers
journal, December 2000

Rikukawa, M.; Sanui, K.
Progress in Polymer Science, Vol. 25, Issue 10, p. 1463-1502
DOI: 10.1016/S0079-6700(00)00032-0

Dendronized Polymers: Synthesis, Characterization, Assembly at Interfaces, and Manipulation
journal, March 2000

Schlüter, A. Dieter; Rabe, Jürgen P.
Angewandte Chemie International Edition, Vol. 39, Issue 5, p. 864-883
DOI: 10.1002/(SICI)1521-3773(20000303)39:5<864::AID-ANIE864>3.0.CO;2-E

Electrochemical Intercalation of PF ₆ into Graphite
journal, January 2000

Seel, J. A.; Dahn, J. R.
Journal of The Electrochemical Society, Vol. 147, Issue 3, p. 892-898
DOI: 10.1149/1.1393288

Doped sulfone electrolytes for high voltage Li-ion cell applications
journal, July 2009

Sun, Xiaoguang; Angell, C. Austen
Electrochemistry Communications, Vol. 11, Issue 7, p. 1418-1421
DOI: 10.1016/j.elecom.2009.05.020

New sulfone electrolytes for rechargeable lithium batteries.: Part I. Oligoether-containing sulfones
journal, March 2005

Sun, Xiao-Guang; Angell, C. Austen
Electrochemistry Communications, Vol. 7, Issue 3, p. 261-266
DOI: 10.1016/j.elecom.2005.01.010

New sulfone electrolytes: Part II. Cyclo alkyl group containing sulfones
journal, November 2004

Sun, Xiao-Guang; Austen Angell, C.
Solid State Ionics, Vol. 175, Issue 1-4, p. 257-260
DOI: 10.1016/j.ssi.2003.11.035

High Anodic Stability of a New Electrolyte Solvent: Unsymmetric Noncyclic Aliphatic Sulfone
journal, January 1998

Xu, K.; Angell, C. A.
Journal of The Electrochemical Society, Vol. 145, Issue 4, p. L70-L72
DOI: 10.1149/1.1838419

Sulfone-Based Electrolytes for Lithium-Ion Batteries
journal, January 2002

Xu, Kang; Angell, C. Austen
Journal of The Electrochemical Society, Vol. 149, Issue 7, p. A920-A926
DOI: 10.1149/1.1483866

Similar Records in DOE Patents and OSTI.GOV collections:

Functionalized ionic liquid electrolytes for lithium ion batteries

Patent Zhang, Zhengcheng; Weng, Wei; Zhang, Lu; ...

An ionic liquid that is a salt has a Formula: ##STR00001## Such ionic liquids may be used in electrolytes and in electrochemical cells.
Full Text Available
Functional electrolyte for lithium-ion batteries

Patent Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil

Functional electrolyte solvents include compounds having at least one aromatic ring with 2, 3, 4 or 5 substituents, at least one of which is a substituted or unsubstituted methoxy group, at least one of which is a tert-butyl group and at least one of which is a substituted or unsubstituted polyether or poly(ethylene oxide) (PEO) group bonded through oxygen to the aromatic ring, are provided.
Full Text Available
Ionic liquids, electrolyte solutions including the ionic liquids, and energy storage devices including the ionic liquids

Patent Gering, Kevin L.; Harrup, Mason K.; Rollins, Harry W.

An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.
Full Text Available
Heteroaromatic-based electrolytes for lithium and lithium-ion batteries

Patent Cheng, Gang; Abraham, Daniel P.

The present invention provides an electrolyte for lithium and/or lithium-ion batteries comprising a lithium salt in a liquid carrier comprising heteroaromatic compound including a five-membered or six-membered heteroaromatic ring moiety selected from the group consisting of a furan, a pyrazine, a triazine, a pyrrole, and a thiophene, the heteroaromatic ring moiety bearing least one carboxylic ester or carboxylic anhydride substituent bound to at least one carbon atom of the heteroaromatic ring. Preferred heteroaromatic ring moieties include pyridine compounds, pyrazine compounds, pyrrole compounds, furan compounds, and thiophene compounds.
Full Text Available
Electrolyte compositions for lithium and lithium-ion batteries

Patent Abraham, Daniel P.; Cheng, Gang

"The present invention provides an electrolyte composition for a lithium or lithium-ion battery comprising a lithium salt in a liquid carrier comprising (a) a linear alkyl carbonate solvent, a cyclic alkyl carbonate solvent, or a combination thereof, and (b) a glycerol carbonate derivative compound of Formula (I):wherein X is selected from O, O(CO)O, S, N, P, P(═O), B, and Si; n is 1 when X is O, O(CO)O, or S; n is 2 when x is N, P, P(═O), or B; n is 3 when X is Si; and each R independently is selected from alkyl, alkenyl, alkynyl, aryl, acyl,more »« less
Full Text Available

Similar Records

Title: Functionalized ionic liquid electrolytes for lithium ion batteries

Abstract

Citation Formats

High cycle life secondary lithium battery patent, October 1985

Layer for stabilization of lithium anode patent, January 1996

Solid polymer electrolyte-based oxygen batteries patent, April 1996

Semipermeable composite membrane and a method for the preparation of such a membrane patent, November 1998

Starburst conjugates patent, January 2001

Non-aqueous electrolyte solvents for secondary cells patent, June 2001

Dendrimer monolayer films patent, November 2001

Electrolyte patent, September 2004

High ionic conductivity gel polymer electrolyte for rechargeable polymer batteries patent, January 2005

Manufacturing method and apparatus of 4-fluoroethylene carbonate patent, September 2007

Lithium/air batteries with LiPON as separator and protective barrier and method patent, March 2008

Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes patent, July 2013

Polymer lithium battery with ionic electrolyte patent-application, August 2003

Lithium based electrochemical cell systems patent-application, August 2004

Electrolytic Solution patent-application, April 2009

A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery journal, January 1996

Novel silane compounds as electrolyte solvents for Li-ion batteries journal, March 2006

Transient behavior of insertion reaction electrodes journal, July 1996

Can All the Lithium be Removed from T 2 ­ Li2 / 3 [ Ni1 / 3Mn2 / 3 ] O 2 ? journal, January 2001

Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes journal, September 1999

Understanding siloxane functionalised ionic liquids journal, January 2010

Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers journal, December 2000

Dendronized Polymers: Synthesis, Characterization, Assembly at Interfaces, and Manipulation journal, March 2000

Electrochemical Intercalation of PF 6 into Graphite journal, January 2000

Doped sulfone electrolytes for high voltage Li-ion cell applications journal, July 2009

New sulfone electrolytes for rechargeable lithium batteries.: Part I. Oligoether-containing sulfones journal, March 2005

New sulfone electrolytes: Part II. Cyclo alkyl group containing sulfones journal, November 2004

High Anodic Stability of a New Electrolyte Solvent: Unsymmetric Noncyclic Aliphatic Sulfone journal, January 1998

Sulfone-Based Electrolytes for Lithium-Ion Batteries journal, January 2002

High cycle life secondary lithium battery
patent, October 1985

Layer for stabilization of lithium anode
patent, January 1996

Solid polymer electrolyte-based oxygen batteries
patent, April 1996

Semipermeable composite membrane and a method for the preparation of such a membrane
patent, November 1998

Starburst conjugates
patent, January 2001

Non-aqueous electrolyte solvents for secondary cells
patent, June 2001

Dendrimer monolayer films
patent, November 2001

Electrolyte
patent, September 2004

High ionic conductivity gel polymer electrolyte for rechargeable polymer batteries
patent, January 2005

Manufacturing method and apparatus of 4-fluoroethylene carbonate
patent, September 2007

Lithium/air batteries with LiPON as separator and protective barrier and method
patent, March 2008

Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes
patent, July 2013

Polymer lithium battery with ionic electrolyte
patent-application, August 2003

Lithium based electrochemical cell systems
patent-application, August 2004

Electrolytic Solution
patent-application, April 2009

A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery
journal, January 1996

Novel silane compounds as electrolyte solvents for Li-ion batteries
journal, March 2006

Transient behavior of insertion reaction electrodes
journal, July 1996

Can All the Lithium be Removed from T ₂ Li_2 / 3 [ Ni_1 / 3Mn_2 / 3 ] O ₂ ?
journal, January 2001

Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes
journal, September 1999

Understanding siloxane functionalised ionic liquids
journal, January 2010

Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers
journal, December 2000

Dendronized Polymers: Synthesis, Characterization, Assembly at Interfaces, and Manipulation
journal, March 2000

Electrochemical Intercalation of PF ₆ into Graphite
journal, January 2000

Doped sulfone electrolytes for high voltage Li-ion cell applications
journal, July 2009

New sulfone electrolytes for rechargeable lithium batteries.: Part I. Oligoether-containing sulfones
journal, March 2005

New sulfone electrolytes: Part II. Cyclo alkyl group containing sulfones
journal, November 2004

High Anodic Stability of a New Electrolyte Solvent: Unsymmetric Noncyclic Aliphatic Sulfone
journal, January 1998

Sulfone-Based Electrolytes for Lithium-Ion Batteries
journal, January 2002