Polymers functionalized with bronsted acid groups
Abstract
Porous aromatic framework polymers functionalized with Bronsted acid moieties are prepared by polymerization of a three-dimensional organic aryl or heteroaryl monomer and its copolymerization with a second aryl or heteroaryl monomer functionalized with one or more Bronsted acid moiety. The polymers are characterized by a stable three-dimensional structure, which, in exemplary embodiments, includes interpenetrating subunits within one or more domain of the bulk polymer structure. The polymers are of use in methods of adsorbing ammonia and amines and in devices and systems configured for this purpose.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of California, Oakland, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1457025
- Patent Number(s):
- 9987583
- Application Number:
- 15/038,286
- Assignee:
- The Regents of the University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- SC0001015
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 May 28
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Van Humbeck, Jeffrey, Long, Jeffrey R., McDonald, Thomas M., and Barin, Gokhan. Polymers functionalized with bronsted acid groups. United States: N. p., 2018.
Web.
Van Humbeck, Jeffrey, Long, Jeffrey R., McDonald, Thomas M., & Barin, Gokhan. Polymers functionalized with bronsted acid groups. United States.
Van Humbeck, Jeffrey, Long, Jeffrey R., McDonald, Thomas M., and Barin, Gokhan. Tue .
"Polymers functionalized with bronsted acid groups". United States. https://www.osti.gov/servlets/purl/1457025.
@article{osti_1457025,
title = {Polymers functionalized with bronsted acid groups},
author = {Van Humbeck, Jeffrey and Long, Jeffrey R. and McDonald, Thomas M. and Barin, Gokhan},
abstractNote = {Porous aromatic framework polymers functionalized with Bronsted acid moieties are prepared by polymerization of a three-dimensional organic aryl or heteroaryl monomer and its copolymerization with a second aryl or heteroaryl monomer functionalized with one or more Bronsted acid moiety. The polymers are characterized by a stable three-dimensional structure, which, in exemplary embodiments, includes interpenetrating subunits within one or more domain of the bulk polymer structure. The polymers are of use in methods of adsorbing ammonia and amines and in devices and systems configured for this purpose.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 05 00:00:00 EDT 2018},
month = {Tue Jun 05 00:00:00 EDT 2018}
}
Works referenced in this record:
Porous Organo-Metallic Skeleton Material Containing an Additional Polymer
patent-application, September 2008
- Muller, Ulrich; Hesse, Michael; Schubert, Markus
- US Patent Application 12/093656; 20080227634
Film Formed from a Blend of Biodegradable Aliphatic-Aromatic Copolyesters
patent-application, June 2009
- Shi, Bo; Wang, James H.
- US Patent Application 11/956419; 20090157020
EDIBLE AND BIOCOMPATIBLE METAL-ORGANIC FRAMEWORKS
patent-application, November 2010
- Yaghi, Omar M.; El-Kadri, Oussama M.; Fang, Qianrong
- US Patent Application 12/680141; 20100286022
Shaped Body Containing Porous Aromatic Framework Material
patent-application, October 2012
- Gaab, Manuela; Maurer, Stefan; Krahnert, Wolf-Rudiger
- US Patent Application 13/451860; 20120270731
Tetraphenylethylene-based fluorescent porous organic polymers: preparation, gas sorption properties and photoluminescence properties
journal, January 2011
- Chen, Qi; Wang, Jin-Xiang; Yang, Fen
- Journal of Materials Chemistry, Vol. 21, Issue 35, p. 13554-13560
Sulfonate-Grafted Porous Polymer Networks for Preferential CO2 Adsorption at Low Pressure
journal, November 2011
- Lu, Weigang; Yuan, Daqiang; Sculley, Julian
- Journal of the American Chemical Society, Vol. 133, Issue 45, p. 18126-18129
Exceptional ammonia uptake by a covalent organic framework
journal, February 2010
- Doonan, Christian J.; Tranchemontagne, David J.; Glover, T. Grant
- Nature Chemistry, Vol. 2, Issue 3, p. 235-238
Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brønsted Acid Groups
journal, January 2014
- Van Humbeck, Jeffrey F.; McDonald, Thomas M.; Jing, Xiaofei
- Journal of the American Chemical Society, Vol. 136, Issue 6, p. 2432-2440
Spiro(fluorene-9,9′-xanthene)-Based Porous Organic Polymers: Preparation, Porosity, and Exceptional Hydrogen Uptake at Low Pressure
journal, October 2011
- Chen, Qi; Wang, Jin-Xiang; Wang, Qiu
- Macromolecules, Vol. 44, Issue 20, p. 7987-7993
Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area
journal, November 2009
- Ben, Teng; Ren, Hao; Ma, Shengqian
- Angewandte Chemie International Edition, Vol. 48, Issue 50, p. 9457-9460
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008
- Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
- Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
Application of the piperazine-grafted CuBTTri metal-organic framework in postcombustion carbon dioxide capture
journal, July 2013
- Das, Anita; Choucair, Mohammad; Southon, Peter D.
- Microporous and Mesoporous Materials, Vol. 174, p. 74-80
FTIR Study of CO2 Adsorption on Amine-Grafted SBA-15: Elucidation of Adsorbed Species
journal, May 2011
- Danon, Alon; Stair, Peter C.; Weitz, Eric
- The Journal of Physical Chemistry C, Vol. 115, Issue 23, p. 11540-11549
Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
journal, July 2009
- Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin
- Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786
Role of Amine Structure on Carbon Dioxide Adsorption from Ultradilute Gas Streams such as Ambient Air
journal, July 2012
- Didas, Stephanie A.; Kulkarni, Ambarish R.; Sholl, David S.
- ChemSusChem, Vol. 5, Issue 10, p. 2058-2064
Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010
- Furukawa, H.; Ko, N.; Go, Y. B.
- Science, Vol. 329, Issue 5990, p. 424-428
Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal–Organic Frameworks
journal, September 2011
- Getman, Rachel B.; Bae, Youn-Sang; Wilmer, Christopher E.
- Chemical Reviews, Vol. 112, Issue 2, p. 703-723
MOF-74 building unit has a direct impact on toxic gas adsorption
journal, January 2011
- Grant Glover, T.; Peterson, Gregory W.; Schindler, Bryan J.
- Chemical Engineering Science, Vol. 66, Issue 2, p. 163-170
Carbon Dioxide Capture from the Air Using a Polyamine Based Regenerable Solid Adsorbent
journal, December 2011
- Goeppert, Alain; Czaun, Miklos; May, Robert B.
- Journal of the American Chemical Society, Vol. 133, Issue 50, p. 20164-20167
Adsorption Equilibria of Ammonia Gas on Inorganic and Organic Sorbents at 298.15 K
February 2001
- Helminen, Jarkko; Helenius, Joni; Paatero, Erkki
- Journal of Chemical & Engineering Data, Vol. 46, Issue 2, p. 391-399
Palladium(0)-Catalyzed Cross-Coupling Reaction of Alkoxydiboron with Haloarenes: A Direct Procedure for Arylboronic Esters
journal, November 1995
- Ishiyama, Tatsuo; Murata, Miki; Miyaura, Norio
- The Journal of Organic Chemistry, Vol. 60, Issue 23, p. 7508-7510
Targeted synthesis of micro–mesoporous hybrid material derived from octaphenylsilsesquioxane building units
journal, January 2013
- Jing, Xiaofei; Sun, Fuxing; Ren, Hao
- Microporous and Mesoporous Materials, Vol. 165, p. 92-98
Requirements for contamination control in the gigabit era
journal, May 1997
- Kitajima, H.; Shiramizu, Y.
- IEEE Transactions on Semiconductor Manufacturing, Vol. 10, Issue 2, p. 267-272
A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids
journal, October 2010
- Kinzel, Tom; Zhang, Yong; Buchwald, Stephen L.
- Journal of the American Chemical Society, Vol. 132, Issue 40, p. 14073-14075
Imine-Bridged Planar Poly(p-phenylene) Derivatives for Maximization of Extended π-Conjugation. The Common Intermediate Approach
journal, December 1994
- Lamba, Jaydeep J. S.; Tour, James M.
- Journal of the American Chemical Society, Vol. 116, Issue 26, p. 11723-11736
Metal–Organic Frameworks for Separations
journal, September 2011
- Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
- Chemical Reviews, Vol. 112, Issue 2, p. 869-932
Analysis of Relationship between Inorganic Gases and Fine Particles in Cleanroom Environment
journal, January 2010
- Lin, I-Kai; Bai, Hsunling; Wu, Bi-Jun
- Aerosol and Air Quality Research, Vol. 10, Issue 3, p. 245-254
Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage/Separation
journal, November 2010
- Lu, Weigang; Yuan, Daqiang; Zhao, Dan
- Chemistry of Materials, Vol. 22, Issue 21, p. 5964-5972
Airborne contamination of a chemically amplified resist. 1. Identification of problem
journal, March 1993
- MacDonald, Scott A.; Hinsberg, William D.; Wendt, H. Russell
- Chemistry of Materials, Vol. 5, Issue 3, p. 348-356
Enhanced carbon dioxide capture upon incorporation of N,N′-dimethylethylenediamine in the metal–organic framework CuBTTri
journal, January 2011
- McDonald, Thomas M.; D'Alessandro, Deanna M.; Krishna, Rajamani
- Chemical Science, Vol. 2, Issue 10, p. 2022-2028
Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012
- McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.
- Journal of the American Chemical Society, Vol. 134, Issue 16, p. 7056-7065
Synthesis of Structured Porous Polymers with Acid and Basic Sites and Their Catalytic Application in Cascade-Type Reactions
journal, March 2013
- Merino, Estíbaliz; Verde-Sesto, Ester; Maya, Eva M.
- Chemistry of Materials, Vol. 25, Issue 6, p. 981-988
Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake
journal, August 2011
- Morris, William; Doonan, Christian J.; Yaghi, Omar M.
- Inorganic Chemistry, Vol. 50, Issue 15, p. 6853-6855
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011
- O’Keeffe, Michael; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 675-702
Safe and Convenient Procedure for Solvent Purification
journal, January 1996
- Pangborn, Amy B.; Giardello, Michael A.; Grubbs, Robert H.
- Organometallics, Vol. 15, Issue 5, p. 1518-1520
Evaluation of a robust, diimide-based, porous organic polymer (POP) as a high-capacity sorbent for representative chemical threats
journal, March 2011
- Peterson, Gregory W.; Farha, Omar K.; Schindler, Bryan
- Journal of Porous Materials, Vol. 19, Issue 2, p. 261-266
Enhanced Adsorption of Ammonia on Metal-Organic Framework/Graphite Oxide Composites: Analysis of Surface Interactions
journal, January 2010
- Petit, Camille; Bandosz, Teresa J.
- Advanced Functional Materials, Vol. 20, Issue 1, p. 111-118
Graphite Oxide/Polyoxometalate Nanocomposites as Adsorbents of Ammonia
journal, February 2009
- Petit, Camille; Bandosz, Teresa J.
- The Journal of Physical Chemistry C, Vol. 113, Issue 9, p. 3800-3809
The role of sulfur-containing groups in ammonia retention on activated carbons
journal, March 2010
- Petit, Camille; Kante, Karifala; Bandosz, Teresa J.
- Carbon, Vol. 48, Issue 3, p. 654-667
Activated carbons modified with aluminium–zirconium polycations as adsorbents for ammonia
journal, September 2008
- Petit, Camille; Bandosz, Teresa J.
- Microporous and Mesoporous Materials, Vol. 114, Issue 1-3, p. 137-147
The Mechanism of Carbon Dioxide Adsorption in an Alkylamine-Functionalized Metal–Organic Framework
journal, April 2013
- Planas, Nora; Dzubak, Allison L.; Poloni, Roberta
- Journal of the American Chemical Society, Vol. 135, Issue 20, p. 7402-7405
Element–organic frameworks with high permanent porosity
journal, January 2008
- Rose, Marcus; Böhlmann, Winfried; Sabo, Michal
- Chemical Communications, Vol. 0, Issue 21, p. 2462-2464
New element organic frameworks viaSuzuki coupling with high adsorption capacity for hydrophobic molecules
journal, January 2010
- Rose, Marcus; Klein, Nicole; Böhlmann, Winfried
- Soft Matter, Vol. 6, Issue 16, p. 3918-3923
Ammonia adsorption and its effects on framework stability of MOF-5 and MOF-177
journal, August 2010
- Saha, Dipendu; Deng, Shuguang
- Journal of Colloid and Interface Science, Vol. 348, Issue 2, p. 615-620
High surface area amorphous microporous poly(aryleneethynylene) networks using tetrahedral carbon- and silicon-centred monomers
journal, January 2009
- Stöckel, Ev; Wu, Xiaofeng; Trewin, Abbie
- Chemical Communications, Vol. 0, Issue 2, p. 212-214
Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011
- Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri
- Chemical Reviews, Vol. 112, Issue 2, p. 782-835
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Chalcogenation in Multiphase Superbase Systems
journal, April 1992
- Trofimov, Boris A.
- Sulfur Reports, Vol. 11, Issue 2, p. 207-227
Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis
journal, August 2011
- Wang, Cheng; Xie, Zhigang; deKrafft, Kathryn E.
- Journal of the American Chemical Society, Vol. 133, Issue 34, p. 13445-13454
Removal of airborne toxic chemicals by porous organic polymers containing metal–catecholates
journal, January 2013
- Weston, Mitchell H.; Peterson, Gregory W.; Browe, Matthew A.
- Chemical Communications, Vol. 49, Issue 29, p. 2995-2997
Synthesis of Imine-Bridged Phenylenepyridine Ladder Polymers. Optical Band Gap Widening through Intramolecular Charge Transfer in Planar Polymers
journal, April 1999
- Yao, Yuxing; Tour, James M.
- Macromolecules, Vol. 32, Issue 8, p. 2455-2461
Gas detection by structural variations of fluorescent guest molecules in a flexible porous coordination polymer
journal, September 2011
- Yanai, Nobuhiro; Kitayama, Koji; Hijikata, Yuh
- Nature Materials, Vol. 10, Issue 10, p. 787-793
Surface Area Control and Photocatalytic Activity of Conjugated Microporous Poly(benzothiadiazole) Networks
journal, December 2012
- Zhang, Kai; Kopetzki, Daniel; Seeberger, Peter H.
- Angewandte Chemie International Edition, Vol. 52, Issue 5, p. 1432-1436
Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide Capture from Flue Gas
journal, June 2012
- Lu, Weigang; Sculley, Julian P.; Yuan, Daqiang
- Angewandte Chemie International Edition, Vol. 51, Issue 30, p. 7480-7484