Oxyphosphorus-containing polymers as binders for battery cathodes

Title: Oxyphosphorus-containing polymers as binders for battery cathodes

Abstract

A class of polymeric phosphorous esters can be used as binders for battery cathodes. Metal salts can be added to the polymers to provide ionic conductivity. The polymeric phosphorous esters can be formulated with other polymers either as mixtures or as copolymers to provide additional desirable properties. Examples of such properties include even higher ionic conductivity and improved mechanical properties. Furthermore, cathodes that include the polymeric phosphorous esters can be assembled with a polymeric electrolyte separator and an anode to form a complete battery.

Inventors:: Pratt, Russell Clayton; Mullin, Scott Allen; Eitouni, Hany Basam

Issue Date:: 2018-05-29

Research Org.:: Seeo, Inc., Hayward, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1452919

Patent Number(s):: 9985292

Application Number:: 14/089,617

Assignee:: Seeo, Inc. (Hayward, CA)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/622 - {being polymers}
H01M2300/0082 - Organic polymers
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx

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DOE Contract Number:: EE0005449

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Nov 25

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE

Citation Formats


                    Pratt, Russell Clayton, Mullin, Scott Allen, and Eitouni, Hany Basam. Oxyphosphorus-containing polymers as binders for battery cathodes.  United States: N. p., 2018. 
        Web.

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                    Pratt, Russell Clayton, Mullin, Scott Allen, & Eitouni, Hany Basam. Oxyphosphorus-containing polymers as binders for battery cathodes.  United States.

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                    Pratt, Russell Clayton, Mullin, Scott Allen, and Eitouni, Hany Basam. Tue .  
        "Oxyphosphorus-containing polymers as binders for battery cathodes".  United States.  https://www.osti.gov/servlets/purl/1452919.

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@article{osti_1452919,

  title        = {Oxyphosphorus-containing polymers as binders for battery cathodes},

  author       = {Pratt, Russell Clayton and Mullin, Scott Allen and Eitouni, Hany Basam},

  abstractNote = {A class of polymeric phosphorous esters can be used as binders for battery cathodes. Metal salts can be added to the polymers to provide ionic conductivity. The polymeric phosphorous esters can be formulated with other polymers either as mixtures or as copolymers to provide additional desirable properties. Examples of such properties include even higher ionic conductivity and improved mechanical properties. Furthermore, cathodes that include the polymeric phosphorous esters can be assembled with a polymeric electrolyte separator and an anode to form a complete battery.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {5}

}

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Works referenced in this record:

Glycol Esters of Phenylphosphonic Acid
patent, August 1945

Toy, Arthur Dock Fon
US Patent Document 2,382,622
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F2382622

Polymeric electrolytes
patent, April 1988

Knight, John; Booth, Colin; Mobbs, Richard H.
US Patent Document 4,737,422
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F4737422

Separator for lithium batteries and lithium batteries including the separator
patent, March 1989

Foster, Donald L.
US Patent Document 4,812,375
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F4812375

Electrochemical cell
patent, November 1989

Lundsgaard, Jorgen S.
US Patent Document 4,879,190
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F4879190

High power solid state electrochemical laminar cell
patent, May 1990

Shackle, Dale R.; Fauteux, Denis G.; Lundsgaard, Jorgen S.
US Patent Document 4,925,751
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F4925751

Method for making a polymeric electrolyte
patent, May 1991

Cook, John; Park, Geroge; McLoughlin, Robert
US Patent Document 5,013,619
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5013619

Enhanced lithium surface
patent, October 1994

Chaloner-Gill, Benjamin; Chang, On; Golovin, Neal
US Patent Document 5,354,631
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5354631

Fire-resistant solid polymer electrolytes
patent, February 1995

Chaloner-Gill, Benjamin
US Patent Document 5,393,621
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5393621

Lithium containing solid electrochemical cells
patent, July 1997

Saidi, Eileen
US Patent Document 5,643,665
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5643665

Stabilized anode for lithium-polymer batteries
patent, July 1997

Skotheim, Terje Absjorn
US Patent Document 5,648,187
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5648187

Protective coatings for negative electrodes
patent, February 2000

Visco, Steven J.; Chu, May-Ying
US Patent Document 6,025,094
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6025094

Double current collector cathode design using chemically similar active materials for alkali metal electrochemical
patent, June 2004

Gan, Hong; Takeuchi, Esther
US Patent Document 6,743,550
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6743550

Non-crosslinked, amorphous, block copolymer electrolyte for batteries
patent, April 2006

Mayes, Anne; Ceder, Gerbrand; Chiang, Yet-Ming
US Patent Document 7,026,071
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7026071

Ionically conductive composites for protection of active metal anodes
patent, October 2007

Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
US Patent Document 7,282,302
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7282302

Polymer composition for encapsulation of electrode particles
patent, January 2008

Gozdz, Antoni; Loxley, Andrew; Pullen, Anthony
US Patent Document 7,318,982
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7318982

Fluorinated comb-shaped polymers
patent-application, November 2006

Norsten, Tyler B.; Ding, Jianfu; Guiver, Michael D.
US Patent Document 11/441003; 20060270822
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220060270822%22.PGNR.&OS=DN/20060270822&RS=DN/20060270822

Binder for Electrode of Non-Aqueous Electrolyte Secondary Battery, Electrode, and Non-Aqueous Electrolyte Secondary Battery
patent-application, February 2009

Hoshiba, Koji; Nakamura, Eitaro
US Patent Document 11/886773; 20090053603
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220090053603%22.PGNR.&OS=DN/20090053603&RS=DN/20090053603

Protection of Anodes for Electrochemical Cells
patent-application, April 2010

Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
US Patent Document 12/180379; 20100104948
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220100104948%22.PGNR.&OS=DN/20100104948&RS=DN/20100104948

Binder for Secondary Battery Electrode, Secondary Battery Electrode, and Secondary Battery
patent-application, May 2010

Fukumine, Mayumi; Wakizaka, Yasuhiro
US Patent Document 12/594133; 20100112441
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220100112441%22.PGNR.&OS=DN/20100112441&RS=DN/20100112441

Electrodes With Solid Polymer Electrolytes
patent-application, January 2011

Hudson, William; Eitouni;, Hany Basam; Singh, Mohit
US Patent Application 12/867665; 20110003211
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220110003211%22.PGNR.&OS=DN/20110003211&RS=DN/20110003211

Inorganic Binders For Battery Electrodes And Aqueous Processing Thereof
patent-application, May 2011

Kay, Andreas
US Patent Application 13/003063; 20110117432
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220110117432%22.PGNR.&OS=DN/20110117432&RS=DN/20110117432

Non-flammable polyphosphonate electrolytes
journal, November 2004

Dixon, Brian G.; Morris, R. Scott; Dallek, Steven
Journal of Power Sources, Vol. 138, Issue 1-2, p. 274-276
https://doi.org/10.1016/j.jpowsour.2004.06.016

Computational chemistry: design and experimental verification of pre-designed heteropolymer electrolytes for rechargeable lithium batteries
journal, June 2003

Dixon, Brian G.; Scott Morris, R.
Journal of Power Sources, Vol. 119-121, p. 856-858
https://doi.org/10.1016/S0378-7753(03)00286-6

Synthetic analogues of phosphorus containing biopolymers
journal, January 1984

Penczek, S.; Lapienis, G.; Klosinski, P.
Pure and Applied Chemistry, Vol. 56, Issue 10, p. 1309-1322
https://doi.org/10.1351/pac198456101309

Synthesis of Well-Defined Thermoresponsive Polyphosphoester Macroinitiators Using Organocatalysts
journal, March 2010

Iwasaki, Yasuhiko; Yamaguchi, Etsuko
Macromolecules, Vol. 43, Issue 6, p. 2664-2666
https://doi.org/10.1021/ma100242s

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Title: Oxyphosphorus-containing polymers as binders for battery cathodes

Abstract

Citation Formats

Glycol Esters of Phenylphosphonic Acid patent, August 1945

Polymeric electrolytes patent, April 1988

Separator for lithium batteries and lithium batteries including the separator patent, March 1989

Electrochemical cell patent, November 1989

High power solid state electrochemical laminar cell patent, May 1990

Method for making a polymeric electrolyte patent, May 1991

Enhanced lithium surface patent, October 1994

Fire-resistant solid polymer electrolytes patent, February 1995

Lithium containing solid electrochemical cells patent, July 1997

Stabilized anode for lithium-polymer batteries patent, July 1997

Protective coatings for negative electrodes patent, February 2000

Double current collector cathode design using chemically similar active materials for alkali metal electrochemical patent, June 2004

Non-crosslinked, amorphous, block copolymer electrolyte for batteries patent, April 2006

Ionically conductive composites for protection of active metal anodes patent, October 2007

Polymer composition for encapsulation of electrode particles patent, January 2008

Fluorinated comb-shaped polymers patent-application, November 2006

Binder for Electrode of Non-Aqueous Electrolyte Secondary Battery, Electrode, and Non-Aqueous Electrolyte Secondary Battery patent-application, February 2009

Protection of Anodes for Electrochemical Cells patent-application, April 2010

Binder for Secondary Battery Electrode, Secondary Battery Electrode, and Secondary Battery patent-application, May 2010

Electrodes With Solid Polymer Electrolytes patent-application, January 2011

Inorganic Binders For Battery Electrodes And Aqueous Processing Thereof patent-application, May 2011

Non-flammable polyphosphonate electrolytes journal, November 2004

Computational chemistry: design and experimental verification of pre-designed heteropolymer electrolytes for rechargeable lithium batteries journal, June 2003

Synthetic analogues of phosphorus containing biopolymers journal, January 1984

Synthesis of Well-Defined Thermoresponsive Polyphosphoester Macroinitiators Using Organocatalysts journal, March 2010

Glycol Esters of Phenylphosphonic Acid
patent, August 1945

Polymeric electrolytes
patent, April 1988

Separator for lithium batteries and lithium batteries including the separator
patent, March 1989

Electrochemical cell
patent, November 1989

High power solid state electrochemical laminar cell
patent, May 1990

Method for making a polymeric electrolyte
patent, May 1991

Enhanced lithium surface
patent, October 1994

Fire-resistant solid polymer electrolytes
patent, February 1995

Lithium containing solid electrochemical cells
patent, July 1997

Stabilized anode for lithium-polymer batteries
patent, July 1997

Protective coatings for negative electrodes
patent, February 2000

Double current collector cathode design using chemically similar active materials for alkali metal electrochemical
patent, June 2004

Non-crosslinked, amorphous, block copolymer electrolyte for batteries
patent, April 2006

Ionically conductive composites for protection of active metal anodes
patent, October 2007

Polymer composition for encapsulation of electrode particles
patent, January 2008

Fluorinated comb-shaped polymers
patent-application, November 2006

Binder for Electrode of Non-Aqueous Electrolyte Secondary Battery, Electrode, and Non-Aqueous Electrolyte Secondary Battery
patent-application, February 2009

Protection of Anodes for Electrochemical Cells
patent-application, April 2010

Binder for Secondary Battery Electrode, Secondary Battery Electrode, and Secondary Battery
patent-application, May 2010

Electrodes With Solid Polymer Electrolytes
patent-application, January 2011

Inorganic Binders For Battery Electrodes And Aqueous Processing Thereof
patent-application, May 2011

Non-flammable polyphosphonate electrolytes
journal, November 2004

Computational chemistry: design and experimental verification of pre-designed heteropolymer electrolytes for rechargeable lithium batteries
journal, June 2003

Synthetic analogues of phosphorus containing biopolymers
journal, January 1984

Synthesis of Well-Defined Thermoresponsive Polyphosphoester Macroinitiators Using Organocatalysts
journal, March 2010