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Title: Synthesis and polymerization of vinyl triazolium ionic liquids

Abstract

Herein, we describe polymerized ionic liquids, demonstrate the synthesis of polymerized ionic liquids, and demonstrate the polymerization of triazolium monomers. One embodiment shows the polymeriazation of the triazolium monomers with bis(trifluoromethanesulfonyl)imide anions. In another embodiment we show the feasibility of copolymerizing with commodity monomers such as styrene using free radical polymerization techniques.

Inventors:
; ; ;
Issue Date:
Research Org.:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1438389
Patent Number(s):
9969823
Application Number:
14/951,210
Assignee:
The United States of America as represented by the Department of Energy (Washington, DC)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Nov 24
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Luebke, David, Nulwala, Hunaid, Matyjaszewski, Krzysztof, and Adzima, Brian. Synthesis and polymerization of vinyl triazolium ionic liquids. United States: N. p., 2018. Web.
Luebke, David, Nulwala, Hunaid, Matyjaszewski, Krzysztof, & Adzima, Brian. Synthesis and polymerization of vinyl triazolium ionic liquids. United States.
Luebke, David, Nulwala, Hunaid, Matyjaszewski, Krzysztof, and Adzima, Brian. Tue . "Synthesis and polymerization of vinyl triazolium ionic liquids". United States. https://www.osti.gov/servlets/purl/1438389.
@article{osti_1438389,
title = {Synthesis and polymerization of vinyl triazolium ionic liquids},
author = {Luebke, David and Nulwala, Hunaid and Matyjaszewski, Krzysztof and Adzima, Brian},
abstractNote = {Herein, we describe polymerized ionic liquids, demonstrate the synthesis of polymerized ionic liquids, and demonstrate the polymerization of triazolium monomers. One embodiment shows the polymeriazation of the triazolium monomers with bis(trifluoromethanesulfonyl)imide anions. In another embodiment we show the feasibility of copolymerizing with commodity monomers such as styrene using free radical polymerization techniques.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 15 00:00:00 EDT 2018},
month = {Tue May 15 00:00:00 EDT 2018}
}

Works referenced in this record:

Polymeric Ionic Liquids, Methods of Making and Methods of Use Thereof
patent-application, September 2011


Synthesis of CF3-containing β-hetaryl-substituted enones
journal, January 2003